Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-28T14:16:19.135Z Has data issue: false hasContentIssue false

The characterization of corrosion resistance in the Ti-6Al-4V alloy fusion zone using a gas tungsten arc welding process

Published online by Cambridge University Press:  31 January 2011

L.M. Wang*
Affiliation:
Department of Power Vehicle and System Engineering, Graduate School of Defense Science, Chung Cheng Institute of Technology, National Defense University, Tao-Yuan 33509, Taiwan, Republic of China
H.C. Lin
Affiliation:
Department of Power Vehicle and System Engineering, Graduate School of Defense Science, Chung Cheng Institute of Technology, National Defense University, Tao-Yuan 33509, Taiwan, Republic of China
*
a) Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

The Ti-6Al-4V sheet alloys were welded by using a common gas tungsten arc welding process. In this work, we study the correlation of corrosion resistance and oxide layer structure produced after commonly used industrial heat treatments. We also study the oxide scales that were formed as a result of the heat-related treatment/aging process. The results indicate that better corrosion resistance of the Ti-6Al-4V alloy weldment can be obtained and significantly improved by a solution treatment plus an artificial aging (ST+AA) treatment, owing to the enhanced intensity of TiO2, V2O5, and Al2O3 oxides that compacted and grew on the surface of fusion zone. The newly found γ-TiAl and α2-Ti3Al particles that nucleated in the fusion zone due to different heat treatments do affect the composition of the oxide layer. The possible mechanism for this oxide layer formation in the fusion zone is discussed.

Type
Articles
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Fergus, W.J.: Review of the effect of alloy composition on the growth rates of scales formed during oxidation of gamma titanium aluminide alloys. Mater. Sci. Eng., A 338, 108 (2002).CrossRefGoogle Scholar
2.Delgado-Alvarado, C. and Sundaram, P.A.: Corrosion evaluation of Ti-48Al-2Cr-2Nb (at.%) in Ringer's solution. Acta Biomater. 2, 701 (2006).CrossRefGoogle ScholarPubMed
3.Metals Handbook, 9th ed. (ASM International, USA, 1990), pp. 2064.Google Scholar
4.Han, Z., Zhao, H., Chen, X.F., and Lin, H.C.: Corrosion behavior of Ti-6Al-4V alloy welded by scanning electron beam. Mater. Sci. Eng., A 277, 38 (2000).CrossRefGoogle Scholar
5.Heidarbeigy, M., Karimzadeh, F., and Saatchi, A.: Corrosion and galvanic coupling of heat treated Ti-6Al-4V alloy weldment. Mater. Lett. 62, 1575 (2008).CrossRefGoogle Scholar
6.Lewandowska, M., Pisarek, M., Rożniatowski, K., Gra¸dzka-Dahlke, M., Janik-Czachor, M., and Kurzydłowski, K.J.: Nanoscale characterization of anodic oxide films on Ti-6Al-4V alloy. Thin Solid Films 515, 6460 (2007).CrossRefGoogle Scholar
7.Anuwar, Mahesh, Jayaganthan, R., Tewari, V.K., and Arivazhagan, N.: A study on the hot corrosion behavior of Ti-6Al-4V alloy. Mater. Lett. 61, 1483 (2007).CrossRefGoogle Scholar
8.Garbacz, H. and Lewandowska, M.: Microstructural changes during oxidation of titanium alloys. Mater. Chem. Phys. 81, 542 (2003).CrossRefGoogle Scholar
9.Raja, V.S., Angal, R.D., and Suresh, M.: Effect of widmanstatten structure on protection potential of Ti-6Al-2Sn-4Zr-2Mo (0.1Si) alloy in 1 M NaBr solution. Corrosion 49, 2 (1993).CrossRefGoogle Scholar
10.Codaroa, E.N., Nakazatoa, R.Z., Horovistizb, A.L., Ribeiro, L.M.F., Ribeirob, R.B., and Hein, L.R.O.: An image analysis study of pit formation on Ti–6A1–4V. Mater. Sci. Eng., A 341, 202 (2003).CrossRefGoogle Scholar
11.Sastry, S.M.L. and Lipsitt, H.A.: Ordering transformations and mechanical properties of Ti3Al and Ti3Al-Nb alloys. Metall. Trans. A 8, 1543 (1977).CrossRefGoogle Scholar
12.Mishin, Y. and Herzig, Chr.: Diffusion in the Ti–Al system. Acta Mater. 48, 589 (2000).CrossRefGoogle Scholar
13.Mauricea, V., Desperta, G., Zannaa, S., Jossob, P., Bacosb, M-P., and Marcusa, P.: XPS study of the initial stages of oxidation of α2-Ti3Al and γ-TiAl intermetallic alloys. Acta Mater. 55, 3315 (2007).CrossRefGoogle Scholar
14.Elmer, J.W., Palmer, T.A., Babu, S.S., and Specht, E.D.: In situ observations of lattice expansion and transformation rates of α and β phases in Ti–6A1–4V. Mater. Sci. Eng., A 391, 104 (2005).CrossRefGoogle Scholar
15.Yoshikazu, R.O., Hidehiro, O., Katsumi, O., Toshihiro, A., Isao, T., and Michio, Y.: The effect of volume fraction of α and β phase in Ti-Al-V alloys on the superplastic behavior. Trans. ISIJ 26, 322 (1986).Google Scholar