Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-24T07:19:44.684Z Has data issue: false hasContentIssue false
  • English
  • Français

Cerium modified MnTiOx/attapulgite catalyst for low-temperature selective catalytic reduction of NOx with NH3

Published online by Cambridge University Press:  27 July 2018

Xiaoyan Huang ,
Aijuan Xie ,
Jiayi Wu ,
Linjing Xu ,
Shiping Luo ,
Jianwen Xia ,
Chao Yao  and
Xiazhang Li
Xiaoyan Huang
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Aijuan Xie*
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Jiayi Wu
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Linjing Xu
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Shiping Luo*
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Jianwen Xia
Affiliation:
Jiangsu Huayuan Mining Co., Ltd., Changzhou University, Changzhou 213164, People’s Republic of China
Chao Yao
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Xiazhang Li
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
Get access

Abstract

Novel cerium-loaded MnTiOx/attapulgite (Ce/MnTiOx/ATP) and cerium-doped MnTiOx/attapulgite (Ce–MnTiOx/ATP) catalysts for low-temperature selective catalytic reduction of nitrogen oxides (NOx) with ammonia (NH3-SCR) were synthesized by co-precipitation methods. The results of catalytic activity testing for the as-prepared Ce–MnTiOx/ATP and Ce/MnTiOx/ATP indicated that the Ce–MnTiOx/ATP catalyst exhibited better catalytic performance with over 80% NOx conversion within a wide temperature window between 170 and 350°, and the highest NOx conversion attained for the Ce–MnTiOx/ATP catalyst was 97.5%. A series of characterization illustrated that the Ce–MnTiOx/ATP catalyst exhibited a higher specific surface area, oxygen vacancy, redox ability, and acid site as compared to that of the Ce/MnTiOx/ATP catalyst. The performance tests showed that the Ce–MnTiOx/ATP catalyst exhibited not only better SO2 & H2O resistance but also higher N2 selectivity and good stability. Therefore, the Ce–MnTiOx/ATP catalyst was testified to be a promising catalyst for NH3-SCR.

Keywords

catalyticCeenvironmentally protective
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 21: Focus Issue: Catalytic Engineered Materials for Commercial and Industrial Energy Applications , 14 November 2018 , pp. 3559 - 3569
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

c)

These authors contributed equally to this work.

References

REFERENCES

Blanco, J., Avila, P., Suárez, S., Yates, M., Martin, J.A., Marzo, L., and Knapp, C.: CuO/NiO monolithic catalysts for NOx removal from nitric acid plant flue gas. Chem. Eng. J. 97, 1–9 (2004).CrossRefGoogle Scholar
Li, J., Chang, H., Ma, L., Hao, J., and Yang, R.: Low-temperature selective catalyticreduction of NOx with NH3 over metal oxide and zeolite catalysts—A review. Catal. Today 175, 147–156 (2011).CrossRefGoogle Scholar
Forzatti, P., Nova, I., and Tronconi, E.: Enhanced NH3 selective catalytic reduction for NOx abatement. Angew. Chem. 121, 8516–8518 (2009).CrossRefGoogle Scholar
Xiong, S-C., Liao, Y., Xiao, X., Dang, H., and Yang, S-J.: The mechanism of the effect of H2O on the low temperature selective catalytic reduction of NO with NH3 over Mn–Fe spinel. Catal. Sci. Technol. 5, 2132–2140 (2015).CrossRefGoogle Scholar
Zhang, L-Y., Shi, L., Huang, L., Zhang, J-P., Gao, R-H., and Zhang, D-S.: Rational design of high-performance deNOx catalysts based on MnxCo3−xO4 nanocages derived from metal-organic frameworks. ACS Catal. 4, 1753–1763 (2014).CrossRefGoogle Scholar
Dahlin, S., Nilsson, M., Bäckström, D., and Bergman, S.L.: Multivariate analysis of the effect of biodiesel-derived contaminants on V2O5–WO3/TiO2 SCR catalysts. Appl. Catal., B 183, 377–385 (2016).CrossRefGoogle Scholar
Song, L-Y., Chao, J-D., Fang, Y-J., and He, H.: Promotion of ceria for decomposition of ammonia bisulfate over V2O5–MoO3/TiO2 catalyst for selective catalytic reduction. Chem. Eng. J. 303, 275–281 (2016).CrossRefGoogle Scholar
Yang, R., Huang, H-F., Chen, Y-J., Zhang, X-X., and Lu, H-F.: Performance of Cr-doped vanadia/titania catalysts for low-temperature selective catalytic reduction of NOx with NH3. Chin. J. Catal. 36, 1256–1262 (2015).CrossRefGoogle Scholar
Zhang, S-G., Zhang, B-L., Liu, B., and Sun, S-L.: A review of Mn-containing oxide catalysts for low temperature selective catalytic reduction of NOx with NH3: Reaction mechanism and catalyst deactivation. RSC Adv. 7, 26226–26242 (2017).CrossRefGoogle Scholar
Deng, S-C., Zhuang, K., Xu, B-L., Ding, Y-H., and Yu, L.: Promotional effect of iron oxide on the catalytic properties of Fe–MnOx/TiO2 (anatase) catalysts for the SCR reaction at low temperatures. Catal. Sci. Technol. 6, 1772–1778 (2016).CrossRefGoogle Scholar
Jiang, B-Q., Wu, Z-B., Liu, Y., and Lee, S.C.: DRIFT study of the SO2 effect on lowtemperature SCR reaction over Fe–Mn/TiO2. J. Phys. Chem. C 114, 4961–4965 (2010).CrossRefGoogle Scholar
Liu, F-D., Shan, W-P., Lian, Z-H., and Xie, L-J.: Novel MnWOx catalyst with remarkable performance for low temperature NH3-SCR of NOx. Catal. Sci. Technol. 3, 2699–2707 (2013).CrossRefGoogle Scholar
Wan, Y-P., Zhao, W-R., Tang, Y., and Li, L.: Ni–Mn bi-metal oxide catalysts for the low temperature SCR removal of NO with NH3. Appl. Catal., B 148, 114–122 (2014).CrossRefGoogle Scholar
Chang, H-Z., Li, J-H., Chen, X-Y., and Ma, L.: Effect of Sn on MnOx–CeO2 catalyst for SCR of NOx by ammonia: Enhancement of activity and remarkable resistance to SO2. Catal. Commun. 27, 54–57 (2012).CrossRefGoogle Scholar
Putluru, S.S.R., Schill, L., Jensen, A.D., and Siret, B.: Mn/TiO2 and Mn–Fe/TiO2 catalysts synthesized by deposition precipitation-promising for selective catalytic reduction of NO with NH3 at low temperatures. Appl. Catal., B 165, 628–635 (2015).CrossRefGoogle Scholar
Li, X-Z., Yan, X-Y., Zuo, S-X., and Lu, X-W.: Construction of LaFe1−xMnxO3/attapulgite nanocomposite for photo-SCR of NOx at low temperature. Chem. Eng. J. 320, 211–221 (2017).CrossRefGoogle Scholar
France, L.J., Yang, Q., Li, W., and Chen, Z-H.: Ceria modified FeMnOx—Enhanced performance and sulphur resistance for low-temperature SCR of NOx. Appl. Catal., B 206, 203–215 (2017).CrossRefGoogle Scholar
Zhang, D-S., Du, X-J., Shi, L-Y., and Gao, R.H.: Shape-controlled synthesis and catalytic application of ceria nanomaterials. Dalton Trans. 41, 14455–14475 (2012).CrossRefGoogle ScholarPubMed
Zhao, X., Huang, L., Li, H-R., and Hu, H.: Promotional effects of zirconium doped CeVO4 for the low-temperature selective catalytic reduction of NOx with NH3. Appl. Catal., B 183, 269–281 (2016).CrossRefGoogle Scholar
Wang, P., Sun, H., Quan, X., and Chen, S.: Enhanced catalytic activity over MIL-100(Fe) loaded ceria catalysts for the selective catalytic reduction of NOx with NH3 at low temperature. J. Hazard. Mater. 301, 512–521 (2016).CrossRefGoogle Scholar
Wang, S-X., Guo, R-T., Pan, W-G., and Chen, Q-L.: The deactivation of Ce/TiO2 catalyst for NH3-SCR reaction by alkali metals: TPD and DRIFT studies. Catal. Commun. 89, 143–147 (2017).CrossRefGoogle Scholar
Xie, A-J., Zhou, X-M., Huang, X-Y., and Ji, L.: Cerium-loaded MnOx/attapulgite catalyst for the low-temperature NH3-selective catalytic reduction. J. Ind. Eng. Chem. 49, 230–241 (2017).CrossRefGoogle Scholar
Zhou, X-M., Huang, X-Y., Xie, A-J., and Luo, S-P.: V2O5-decorated Mn-Fe/attapulgite catalyst with high SO2 tolerance for SCR of NOx with NH3 at low temperature. Chem. Eng. J. 326, 1074–1085 (2017).CrossRefGoogle Scholar
Das, K., Sharma, S.N., Kumar, M., and De, S.K.: Morphology dependent luminescence properties of Co doped TiO2 nanostructures. J. Phys. Chem. C 113, 14783–14792 (2009).CrossRefGoogle Scholar
Andersen, N.I., Serov, A., and Atanassov, P.: Metal oxides/CNT nano-composite catalysts for oxygen reduction/oxygen evolution in alkaline media. Appl. Catal., B 163, 623–627 (2015).CrossRefGoogle Scholar
Cai, S-X., Hu, H., Li, H-R., and Shi, L-Y.: Design of multi-shell Fe2O3@MnOx@CNTs for the selective catalytic reduction of NO with NH3: Improvement of catalytic activity and SO2 tolerance. Nanoscale 8, 3588–3598 (2016).CrossRefGoogle ScholarPubMed
Boningari, T., Ettireddy, P.R., Somogyvari, A., and Liu, Y.: Influence of elevated surface texture hydrated titania on Ce-doped Mn/TiO2 catalysts for the low-temperature SCR of NOx under oxygen-rich conditions. J. Catal. 325, 145–155 (2015).CrossRefGoogle Scholar
Machida, M., Uto, M., and Daisuke Kurogi, A.: MnOx–CeO2 binary oxides for catalytic NOx sorption at low temperatures. Sorptive removal of NOx. Chem. Mater. 12, 3158–3164 (2000).CrossRefGoogle Scholar
Chen, X-B., Wang, P-L., Fang, P-F., and Ren, T-Y.: Tuning the property of Mn–Ce composite oxides by titanate nanotubes to improve the activity, selectivity and SO2/H2O tolerance in middle temperature NH3-SCR reaction. Fuel Process. Technol. 167, 221–228 (2017).CrossRefGoogle Scholar
Liu, X-W., Zhou, K-B., Wang, L., and Wang, B-Y.: Oxygen vacancy clusters promoting reducibility and activity of ceria nanorods. J. Am. Chem. Soc. 131, 3140–3141 (2009).CrossRefGoogle ScholarPubMed
Liu, F-D., He, H., Ding, Y., and Zhang, C-B.: Effect of manganese substitution on the structure and activity of iron titanate catalyst for the selective catalytic reduction of NO with NH3. Appl. Catal., B 93, 194–204 (2009).CrossRefGoogle Scholar
Wu, Y-S., Lu, Y., Song, C-J., Ma, Z-C., and Xing, S-T.: A novel redox-precipitation method for the preparation of α-MnO2 with a high surface Mn4+ concentration and its activity toward complete catalytic oxidation of o-xylene. Catal. Today 201, 32–39 (2013).CrossRefGoogle Scholar
Zhu, L., Zeng, Y-Q., Zhang, S., Deng, J-L., and Zhong, Q.: Effects of synthesis methods on catalytic activities of CoOx–TiO2 for low-temperature NH3-SCR of NO. J. Environ. Sci. 54, 277–287 (2017).CrossRefGoogle Scholar
Yang, S-X., Zhu, W-P., Jiang, Z-P., Chen, Z-X., and Wang, J-B.: The surface properties and the activities in catalytic wet air oxidation over CeO2–TiO2 catalysts. Appl. Surf. Sci. 252, 8499–8505 (2006).CrossRefGoogle Scholar
Lian, Z-H., Liu, F-D., He, H., Shi, X-Y., and Mo, J-S.: Manganese-niobium mixed oxide catalyst for the selective catalytic reduction of NOx with NH3 at low temperatures. Chem. Eng. J. 250, 390–398 (2014).CrossRefGoogle Scholar
Zhang, D-S., Zhang, L-Z., Shi, L-Y., Fang, C-F., and Zhang, J.: In situ supported MnOx–CeOx on carbon nanotubes for the low-temperature selective catalytic reduction of NO with NH3. Nanoscale 5, 1127–1136 (2013).CrossRefGoogle Scholar
Sultana, A., Sasaki, M., and Hamada, H.: Influence of support on the activity of Mn supported catalysts for SCR of NO with ammonia. Catal. Today 185, 284–289 (2012).CrossRefGoogle Scholar
Liu, Z-M., Yi, Y., Zhang, S-X., Zhu, T-L., Zhu, J-Z., and Wang, J-G.: Selective catalytic reduction of NOx with NH3 over Mn–Ce mixed oxide catalyst at low temperatures. Catal. Today 216, 76–81 (2013).CrossRefGoogle Scholar
Cai, S-X., Liu, J-L., Zha, K-W., and Li, H-R.: A general strategy for the in situ decoration of porous Mn–Co bi-metal oxides on metal mesh/foam for high performance de-NOx monolith catalysts. Nanoscale 9, 5648–5657 (2017).CrossRefGoogle ScholarPubMed
Li, Y., Li, Y-P., Wang, P-F., Hu, W-P., and Zhan, S-H.: Low-temperature selective catalytic reduction of NOx with NH3 over MnFeOx nanorods. Chem. Eng. J. 330, 213–222 (2017).CrossRefGoogle Scholar
Tang, X-L., Li, C-L., Yi, H-H., and Zhang, R-C.: Facile and fast synthesis of novel Mn2CoO4@rGO catalysts for the NH3-SCR of NOx at low temperature. Chem. Eng. J. 333, 467–476 (2018).CrossRefGoogle Scholar
Zhang, R-D., Yang, W., Luo, N., Li, P-X., Lei, Z-G., and Chen, B-H.: Low-temperature NH3-SCR of NO by lanthanum manganite perovskites: Effect of A-/B-site substitution and TiO2/CeO2 support. Appl. Catal., B 146, 94–104 (2014).CrossRefGoogle Scholar
Supplementary material: File

Huang et al. supplementary material

Figures S1-S3 and Tables S1-S2

Download Huang et al. supplementary material(File)
File 842.2 KB