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Cadmium selenide: Surface and nanoparticle energetics

Published online by Cambridge University Press:  09 March 2011

Fen Xu ,
Wei Zhou  and
Alexandra Navrotsky
Fen Xu
Affiliation:
Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California at Davis, Davis, California 95616
Wei Zhou
Affiliation:
Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California at Davis, Davis, California 95616
Alexandra Navrotsky*
Affiliation:
Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California at Davis, Davis, California 95616
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Cadmium selenide (CdSe) belongs to a class of important II–VI semiconductors widely used in optical, sensor, and laser materials and quantum-dot light-emitting diodes. Here we present the first direct calorimetric measurement of the surface energy of wurtzite CdSe. CdSe nanoparticles with particle size between 20 and 60 nm were prepared by a hydrothermal method without additives to control morphology, and the surface energy was derived from the drop solution enthalpies in molten sodium molybdate and from water adsorption calorimetry. The surface energy of the hydrated surface is 1.31 ± 0.26 J/m2, whereas that of the anhydrous surface is 1.65 ± 0.27 J/m2. These values are significantly lower than those for ZnO and many other oxides.

Keywords

CdSeNanoscale
Type
Articles
Information
Journal of Materials Research , Volume 26 , Issue 5 , 14 March 2011 , pp. 720 - 725
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1.Csik, I., Russo, S.P., and Mulvaney, P.: Density functional study of surface passivation of nonpolar wurtzite CdSe surfaces. J. Phys. Chem. C 112, 20413 (2008).CrossRefGoogle Scholar
2.Zakharov, O., Rubio, A., and Cohen, M.L.: Calculated structural and electronic properties of CdSe under pressure. Phys. Rev. B 51, 4926 (1995).CrossRefGoogle ScholarPubMed
3.Wang, W.Z., Geng, Y., Yan, P., Liu, F.Y., Xie, Y., and Qian, Y.T.: A novel mild route to nanocrystalline selenides at room temperature. J. Am. Chem. Soc. 121, 4062 (1999).CrossRefGoogle Scholar
4.Klimov, V.I., Mikhailovsky, A.A., Xu, S., Malko, A., Hollingsworth, J.A., Leatherdale, C.A., Eisler, H.J., and Bawendi, M.G.: Optical gain and stimulated emission in nanocrystal quantum dots. Science 290, 314 (2000).CrossRefGoogle ScholarPubMed
5.Coe, S., Woo, W.K., Bawendi, M., and Bulovic, V.: Electroluminescence from single monolayers of nanocrystals in molecular organic devices. Nature 420, 800 (2002).CrossRefGoogle ScholarPubMed
6.Bawendi, M.G., Steigerwald, M.L., and Brus, L.E.: The quantum mechanics of larger semiconductor clusters (quantum dots). Annu. Rev. Phys. Chem. 41, 477 (1990).CrossRefGoogle Scholar
7.Chen, C.C., Herhold, A.B., Johnson, C.S., and Alivisatos, A.P.: Size dependence of structural metastability in semiconductor nanocrystals. Science 276, 398 (1997).CrossRefGoogle ScholarPubMed
8.Herron, N., Wang, Y., and Eckert, H.: Synthesis and characterization of surface-capped, size-quantized CdS clusters. Chemical control of cluster size. J. Am. Chem. Soc. 112, 1322 (1990).CrossRefGoogle Scholar
9.Li, Y.D., Liao, H.W., Ding, Y., Fan, Y., Zhang, Y., and Qian, Y.T.: Solvothermal elemental direct reaction to CdE (E = S, Se, Te) semiconductor nanorod. Inorg. Chem. 38, 1382 (1999).CrossRefGoogle Scholar
10.Yi, H.C. and Moore, J.J.: Self-propagating high-temperature (combustion) synthesis (SHS) of powder-compacted materials. J. Mater. Sci. 25, 1159 (1990).CrossRefGoogle Scholar
11.Bandaranayake, R.J., Wen, G.W., Lin, J.Y., Jiang, H.X., and Sorensen, C.M.: Structural phase behavior in II-VI semiconductor nanoparticles. Appl. Phys. Lett. 67, 831 (1995).CrossRefGoogle Scholar
12.Wang, Y. and Herron, N.: Nanometer-sized semiconductor clusters: Materials synthesis, quantum-size effects, and photophysical properties. J. Phys. Chem. 95, 525 (1991).CrossRefGoogle Scholar
13.Borade, R.B.: Synthesis and characterization of ferrisilicate zeolite of pentasil group. Zeolites 7, 398 (1987).CrossRefGoogle Scholar
14.Zhu, J.J., Koltypin, Y., and Gedanken, A.: General sonochemical method for the preparation of nanophasic selenides: Synthesis of ZnSe nanoparticles. Chem. Mater. 12, 73 (2000).CrossRefGoogle Scholar
15.Peng, X.G., Manna, L., Yang, W.D., Wickham, J., Scher, E., Kadavanich, A., and Alivisatos, A.P.: Shape control of CdSe nanocrystals. Nature 404, 59 (2000).CrossRefGoogle ScholarPubMed
16.Rajh, T., Micic, O.I., and Nozik, A.J.: Synthesis and characterization of surface-modified colloidal CdTe quantum dots. J. Phys. Chem. 97, 11999 (1993).CrossRefGoogle Scholar
17.Qiao, Z.P., Xie, Y., Xu, J.G., Zhu, Y.J., and Qian, Y.T.: Gamma-radiation synthesis of the nanocrystalline semiconductors PbS and CuS. J. Colloid Interface Sci. 214, 459 (1999).CrossRefGoogle ScholarPubMed
18.McHale, J.M., Auroux, A., Perrotta, A.J., and Navrotsky, A.: Surface energies and thermodynamic phase stability in nanocrystalline aluminas. Science 277, 788 (1997).CrossRefGoogle Scholar
19.Levchenko, A.A., Li, G.S., Boerio-Goates, J., Woodfield, B.F., and Navrotsky, A.: TiO2 stability landscape: Polymorphism, surface energy, and bound water energetics. Chem. Mater. 18, 6324 (2006).CrossRefGoogle Scholar
20.Mazeina, L. and Navrotsky, A.: Enthalpy of water adsorption and surface enthalpy of goethite (alpha-FeOOH) and hematite (alpha-Fe2O3). Chem. Mater. 19, 825 (2007).CrossRefGoogle Scholar
21.Zhang, P., Xu, F., Navrotsky, A., Lee, J.S., Kim, S.T., and Liu, J.: Surface enthalpies of nanophase ZnO with different morphologies. Chem. Mater. 19, 5687 (2007).CrossRefGoogle Scholar
22.Radha, A.V., Bomati-Miguel, O., Ushakov, S.V., Navrotsky, A., and Tartaj, P.: Surface enthalpy, enthalpy of water adsorption, and phase stability in nanocrystalline monoclinic zirconia. J. Am. Ceram. Soc. 92, 133 (2009).CrossRefGoogle Scholar
23.Deore, S., Xu, F., and Navrotsky, A.: Oxide-melt solution calorimetry of selenides: Enthalpy of formation of zinc, cadmium, and lead selenide. Am. Mineral. 93, 779 (2008).CrossRefGoogle Scholar
24.Pramanik, P. and Bhattacharya, R.N.: Chemical methods for the deposition of thin-films of Sb2Se3. J. Solid State Chem. 44, 425 (1982).CrossRefGoogle Scholar
25.Navrotsky, A.: Progress and new directions in high-temperature calorimetry. Phys. Chem. Miner. 2, 89 (1977).CrossRefGoogle Scholar
26.Navrotsky, A.: Progress and new directions in high temperature calorimetry revisited. Phys. Chem. Miner. 24, 222 (1997).CrossRefGoogle Scholar
27.Chen, S.S., Avila-Paredes, H.J., Kim, S., Zhao, J.F., Munir, Z.A., and Navrotsky, A.: Direct calorimetric measurement of grain boundary and surface enthalpies in yttria-stabilized zirconia. Phys. Chem. Chem. Phys. 11, 3039 (2009).CrossRefGoogle ScholarPubMed
28.McHale, J.M., Navrotsky, A., and Perrotta, A.J.: Effects of increased surface area and chemisorbed H2O on the relative stability of nanocrystalline gamma-Al2O3 and alpha-Al2O3. J. Phys. Chem. B 101, 603 (1997).CrossRefGoogle Scholar
29.Zhou, W., Ushakov, S.V., Wang, T., Ekerdt, J.G., Demkov, A.A., and Navrotsky, A.: Hafnia: Energetics of thin films and nanoparticles. J. Appl. Phys. 107, 123514 (2010).CrossRefGoogle Scholar
30.Manna, L., Wang, L.W., Cingolani, R., and Alivisatos, A.P.: First-principles modeling of unpassivated and surfactant-passivated bulk facets of wurtzite CdSe: A model system for studying the anisotropic growth of CdSe nanocrystals. J. Phys. Chem. B 109, 6183 (2005).CrossRefGoogle Scholar
31.Csik, I., Russo, S.P., and Mulvaney, P.: Density functional study of non-polar surfaces of wurtzite CdSe. Chem. Phys. Lett. 414, (2005).CrossRefGoogle Scholar