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Application of self-assembling photosynthetic dye for organic photovoltaics

Published online by Cambridge University Press:  17 January 2011

Ryu Tange ,
Koji Inai ,
Takashi Sagawa  and
Susumu Yoshikawa
Ryu Tange
Affiliation:
Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
Koji Inai
Affiliation:
Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
Takashi Sagawa*
Affiliation:
Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
Susumu Yoshikawa*
Affiliation:
Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan; and Core Research of Evolutional Science & Technology (CREST), Japan Science Technology Agency (JST), Gokasho, Uji, Kyoto 611-0011, Japan
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
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Abstract

We have developed novel photovoltaic systems composed of the fullerene derivative (6,6)-phenyl C61 butyric acid methyl ester as electron acceptor with a second functional organic molecule, in this case bacteriochlorophyll c, as the light-harvesting and photosensitizing part. It was found that heat treatment of a thin film of bacteriochlorophyll c altered the morphological states of the aggregates and conductivity of the thin film could be regulated through the annealing process. Blended fullerene derivative and bacteriochlorophyll c thin films were fabricated on the surface of an indium-tin oxide/poly(ethylene dioxythiophene) doped with polystyrene sulfonic acid substrate layer and their photovoltaic properties were characterized and evaluated. Formation of fullerene-coordinated bacteriochlorophyll c complex was confirmed by changes in the visible absorption spectra and by FTIR. Such complexation promoted generation of photocurrent in the region of the Qyband and the current density of the thin film increased. A maximum incident photon-to-current conversion efficiency of 5.1% was attained at 745 nm.

Type
Reviews
Information
Journal of Materials Research , Volume 26 , Issue 2: Focus Issue: Self-Assembly and Directed Assembly of Advanced Materials , 28 January 2011 , pp. 306 - 310
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1.Jochum, T., Reddy, C.M., Eichhöfer, A., Buth, G., Szmytkowski, J., Kalt, H., Moss, D., and Balaban, T.S.: The supromolecular organization of self-assembling chlorosomal bacteriochlorophyll c, d, or e mimics. PNAS 105, 12736 (2008).CrossRefGoogle ScholarPubMed
2.Brabec, C.J. and Durrant, J.R.: Solution-processed organic solar cells. MRS Bull. 33, 670 (2008).Google Scholar
3.Yoshikawa, O., Sonobe, T., Sagawa, T., and Yoshikawa, S.: Single mode microwave irradiation to improve the efficiency of polymer solar cell based on poly(3-hexylthiophene) and fullerene derivative. Appl. Phys. Lett. 94, 083301 (2009).CrossRefGoogle Scholar
4.Chen, H-Y., Hou, J., Zhang, S., Liang, Y., Yang, G., Yang, Y., Yu, L., Wu, Y., and Li, G.: Polymer solar cells with enhanced open-circuit voltage and efficiency. Nat. Photonics 3, 649 (2009).CrossRefGoogle Scholar
5.Matsuo, Y., Sato, Y., Niinomi, T., Soga, I., Tanaka, H., and Nakamura, E.: Columnar structure in bulk heterojunction in solution-processable three-layered p-i-n organic photovoltaic devices using tetrabenzoporphyrin precursor and silylmethyl[60]fullerene. J. Am. Chem. Soc. 131, 16048 (2009).CrossRefGoogle ScholarPubMed
6.Yun, J-J., Jung, H-S., Kim, S-H., and Han, E-M.: Chlorophyll-layer-inserted poly(3-hexyl-thiophene) solar cell having a high light-to-current conversion efficiency up to 1.2%. Appl. Phys. Lett. 87, 123102 (2005).CrossRefGoogle Scholar
7.Linke-Schaetzel, M., Bhise, A.D., Gliemann, H., Koch, T., Schimmel, T., and Balaban, T.S.: Self-assembled chromophores for hybrid solar cells. Thin Solid Films 451–452, 16 (2004).Google Scholar
8.Saga, Y., Kim, T-Y., Hisai, T., and Tamiaki, H.: Assembly of extramembranous light-harvesting complexes of green sulfur photosynthetic bacterium Chlorobium tepidum on glass surface by electrostatic layer-by-layer adsorption. Thin Solid Films 500, 278 (2006).CrossRefGoogle Scholar
9.Huijser, A., Marek, P.L., Savenije, T.J., Siebbeles, L.D.A., Schere, T., Haschild, R., Szmytkowski, J., Kalt, H., Hahn, H., and Balaban, T.S.: Photosensitization of TiO2 and SnO2 by artificial self-assembling mimics of the natural chlorosomal bacteriochlorophylls. J. Phys. Chem. C 111, 11726 (2007).CrossRefGoogle Scholar
10.Nozawa, T., Ohtomo, K., Suzuki, M., Morishita, Y., and Madigan, M.T.: Structures and organization of bacteriochlorophyll c’s in chlorosomes from a new thermophilic bacterium Chlorobium tepidum. Bull. Chem. Soc. Jpn. 66, 231 (1993).CrossRefGoogle Scholar
11.Ishii, T., Uehara, K., Ozaki, Y., and Mimuro, M.: The effects of pH and strength on the aggregation of bacteriochlorophyll c in aqueous organic media: The possibility of two kinds of aggregates. Photochem. Photobiol. 70, 760 (1999).CrossRefGoogle Scholar
12.Egawa, A., Fujiwara, T., Mizoguchi, T., Kakitani, Y., Koyama, Y., and Akutsu, H.: Structure of the light-harvesting bacteriochlorophyll c assembly in chlorosomes from Chlorobium limicola determined by solid-state NMR. PNAS 104, 790 (2007).CrossRefGoogle ScholarPubMed
13.Brabec, C.J., Cravino, A., Meissner, D., Sariciftci, N.S., Fromherz, T., Rispens, M.T., Sanchez, L., and Hummelen, J.C.: Origin of the open circuit voltage of plastic solar cells. Adv. Funct. Mater. 11, 374 (2001).3.0.CO;2-W>CrossRefGoogle Scholar
14.Scharber, M.C., Mühlbacher, D., Koppe, M., Denk, P., Waldauf, C., Heeger, A.J., and Brabec, C.J.: Design rules for donors in bulk-heterojunction solar cells—Towards 10% energy-conversion efficiency. Adv. Mater. 18, 789 (2006).CrossRefGoogle Scholar