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Apatite-forming ability on titanium surface modified by hydrothermal treatment and ultraviolet irradiation

Published online by Cambridge University Press:  31 January 2011

Akiko Obata ,
Tianshu Zhai  and
Toshihiro Kasuga
Akiko Obata*
Affiliation:
Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan
Tianshu Zhai
Affiliation:
Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan
Toshihiro Kasuga
Affiliation:
Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Titania coatings with various morphologies were formed on titanium surfaces by hydrothermal treatment using a dilute alkaline solution and evaluated in their hydroxyapatite (HA)-forming abilities in simulated body fluid (1.5SBF) under ultraviolet (UV) irradiation. The HA formation on the titania coating in 1.5SBF was enhanced by UV irradiation. The amount of phosphate groups adsorbed on the titania, after soaking in 1.5SBF for 24 h under UV irradiation, was estimated to be larger than that of calcium ions, whereas that of calcium ions on the titania, after soaking without UV irradiation, was larger than that of phosphate groups. It was suggested that the titania generated much basic Ti–OH groups at its surface by UV irradiation and subsequently adsorbed phosphate groups, such as H2PO4−, resulting in the formation of a new surface rich in the amount of the groups, which eventually enhanced the HA formation in 1.5SBF.

Keywords

Biomimetic (assembly)Surface reactionTi
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 12: Biomimetic and Bio-enabled Materials Science and Engineering , December 2008 , pp. 3169 - 3175
Copyright
Copyright © Materials Research Society 2008

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References

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