Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-03T00:47:21.161Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of mesostructured lamellar lead sulfide in acidic media

Published online by Cambridge University Press:  31 January 2011

Shuxi Zhou ,
Yanxiong Ke ,
Jianmin Li ,
Shemin Lu ,
Guien Zhou  and
Shuyuan Zhang
Shuxi Zhou
Affiliation:
Department of Chemical Physics, University of Science and Technology, Hefei, Anhui 230026, People's Republic of China and Department of Chemical Engineering, Yancheng Technology College, Yancheng Jiangsu 224003, People's Republic of China
Yanxiong Ke
Affiliation:
Department of Chemical Physics, University of Science and Technology, Hefei, Anhui 230026, People's Republic of China
Jianmin Li*
Affiliation:
Department of Chemical Physics, University of Science and Technology, Hefei, Anhui 230026, People's Republic of China
Shemin Lu
Affiliation:
Department of Chemical Physics, University of Science and Technology, Hefei, Anhui 230026, People's Republic of China
Guien Zhou
Affiliation:
Structure Research Laboratory, University of Science and Technology, Hefei, Anhui 230026, People's Republic of China
Shuyuan Zhang
Affiliation:
Structure Research Laboratory, University of Science and Technology, Hefei, Anhui 230026, People's Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Mesostructured lamellar lead sulfide has been synthesized for the first time at room temperature in acidic media, employing sodium dodecyl sulfonate (SDS) as template and soluble lead salts, and hydrated sodium sulfide as the inorganic sources. The material was chiefly characterized by x-ray powder diffraction, high-resolution transmission electron microscopy, Raman spectroscopy, x-ray photoelectron spectroscopy, and thermogravimetric analysis. In the material, the Pb:S molar ratio for the inorganic phase is about 1:1.2, with a distance of about 2.7 nm between the inorganic layers.

Type
Rapid Communications
Information
Journal of Materials Research , Volume 18 , Issue 3 , March 2003 , pp. 549 - 551
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Kresge, C.T., Leonowicz, M.E., Roth, W.J., Vartuli, J.C., and Beck, J.S., Nature 359, 710 (1992).Google Scholar
2.Beck, J.S., Vartuli, J.C., Roth, W.J., Leonowicz, M.E., Kresge, C.T., Schmitt, K.D., Chu, C.T-W., Olesen, D.H., Sheppard, E.W., McCullen, S.B., Higgins, J.B., and Schleker, J.L., J. Am. Chem. Soc. 114, 10834 (1992).CrossRefGoogle Scholar
3.Schûth, F., Chem. Mater. 13, 318 (2001).Google Scholar
4.Trikalitis, P.N., Rangan, K.K., and Kanatzidis, M.G., J. Am. Chem. Soc. 124, 2604 (2002).CrossRefGoogle Scholar
5.Rangan, K.K., Trikalitis, P.N., and Kanatzidis, M.G., J. Am. Chem. Soc. 122, 10230 (2000).Google Scholar
6.Maclachlan, M.J., Coombs, N., Bedard, R.L., White, S., Thompson, L.K., Ozin, G.A., J. Am. Chem. Soc. 121, 112005 (1999).Google Scholar
7.Li, J. and Nazar, L.F., Chem. Commun. 1749 (2000).Google Scholar
8.Froba, M. and Oberender, N., Chem. Commun. 1729 (1997).Google Scholar
9.Maclachlan, M.J., Coombs, N., and Ozin, G.A., Nature 397, 681 (1999).CrossRefGoogle Scholar
10.Braun, P.V., Osener, P., and Stupp, S.I., Nature 380, 325 (1996).Google Scholar
11.Lifshitz, E., Sirota, M., and Porteariu, H., J. Crystal Growth 196, 126 (1999).CrossRefGoogle Scholar
12.Yada, M., Ohya, M., Machida, M., and Kijima, T., Chem. Commun. 1941 (1998).Google Scholar
13.Sukarova, B.M., Najdoski, M., Grozdanov, I., and Chunnilall, C.J., J. Mol. Struct. 410–411, 267 (1997).Google Scholar
14.Lee, J.D., Concise Inorganic Chemistry, 4th ed. (Chapman and Hall Ltd., London, U.K., 1991), p. 61.Google Scholar
15.Bellamy, L.J., The Infra-red Spectra of Complex Molecules, 2nd ed. (Chapman and Hall Ltd., London, U.K., 1980), pp. 15, 17, 225, and 235.Google Scholar