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Synthesis of hierarchical mesoporous zirconia fiber by using collagen fiber as a template

Published online by Cambridge University Press:  31 January 2011

Dehui Deng ,
Xuepin Liao ,
Xin Liu  and
Bi Shi
Dehui Deng
Affiliation:
Key Laboratory of Leather Chemistry and Engineering of Ministry of Education, Sichuan University, Chengdu 610065, People’s Republic of China
Xuepin Liao*
Affiliation:
Department of Biomass Chemistry and Leather Engineering, Sichuan University, Chengdu 610065, People’s Republic of China
Xin Liu
Affiliation:
Department of Biomass Chemistry and Leather Engineering, Sichuan University, Chengdu 610065, People’s Republic of China
Bi Shi*
Affiliation:
Key Laboratory of Leather Chemistry and Engineering of Ministry of Education, Sichuan University, Chengdu 610065, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)Address all correspondence to these authors. e-mail: [email protected]
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Abstract

Ordered hierarchical mesoporous zirconia fiber was prepared by using collagen fiber as a template, and it was characterized by scanning electron microscopy, transmission electron microscopy, N2 adsorption techniques, x-ray photoelectron spectroscopy, x-ray diffraction, and elemental analysis. It was found that the zirconia fiber obtained is approximately 1–4 μm in outer diameter and 0.5–1 mm in length, and the surface of the fiber exhibits unique corncob-like mesoporous morphology. This study indicates that collagen fiber, with hierarchical supermolecular structures, could be used as an ideal template to prepare porous metal oxide fibers.

Keywords

Biomimetic (chemical reaction)NanostructureScanning electron microscopy (SEM)
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 12: Biomimetic and Bio-enabled Materials Science and Engineering , December 2008 , pp. 3263 - 3268
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1Yang, P.D., Zhao, D.Y., Margolese, D.I., Chmelka, B.F., Stucky, G.D.: Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks. Nature 396, 152 1998CrossRefGoogle Scholar
2Zong, S.Z., Cao, Y., Zhou, Y.M., Ju, H.X.: Zirconia nanoparticles enhanced grafted collagen tri-helix scaffold for unmediated biosensing of hydrogen peroxide. Langmuir 22, 8915 2006CrossRefGoogle ScholarPubMed
3Ciesla, U., Fröba, M., Stucky, G., Schüth, F.: Highly ordered porous zirconias from surfactant-controlled syntheses: Zirconium oxide-sulfate and zirconium oxo phosphate. Chem. Mater. 11, 227 1999CrossRefGoogle Scholar
4Carreon, M.A., Guliants, V.V.: Ordered meso- and macroporous binary and mixed metal oxides. Eur. J. Inorg. Chem. 27 2005CrossRefGoogle Scholar
5Lin, C.K., Zhang, C.M., Lin, J.: Phase transformation and photoluminescence properties of nanocrystalline ZrO2 powders prepared via the pechini-type sol-gel process. J. Phys. Chem. C 111, 3300 2007CrossRefGoogle Scholar
6Huang, Y.Y., McCarthy, T.J., Sachtler, W.M.H.: Preparation and catalytic testing of mesoporous sulfated zirconium dioxide with partially tetragonal wall structure. Appl. Catal., A 148, 135 1996CrossRefGoogle Scholar
7Chen, H.R., Wang, X.M., Shia, J.L., Xiao, P., Yan, D.S.: A novel structural mesoporous alumina/yttrium doped zirconia nanocrystalline composite derived by solvothermal approach. J. Mater. Res. 20, 42 2005CrossRefGoogle Scholar
8Ormerod, R.M.: Solid oxide fuel cells. Chem. Soc. Rev. 32, 17 2003CrossRefGoogle ScholarPubMed
9Lyu, Y.Y., Yi, S.H., Shon, J.K., Chang, S., Pu, L.S., Lee, S.Y., Yie, J.E., Char, K., Stucky, G.D., Kim, J.M.: Highly stable mesoporous metal oxides using nano-propping hybrid Gemini surfactants. J. Am. Chem. Soc. 126, 2310 2004CrossRefGoogle ScholarPubMed
10Wong, M.S., Ying, J.Y.: Amphiphilic templating of mesostructured zirconium oxide. Chem. Mater. 10, 2067 1998CrossRefGoogle Scholar
11Reddy, J.S., Sayari, A.: Nanoporous zirconium oxide prepared using the supramolecular templating approach. Catal. Lett. 38, 219 1996CrossRefGoogle Scholar
12Fang, H., Wan, T.L., Shi, W.H., Zhang, M.: Design and synthesis of large-pore p6mm mesoporus zirconia thin films templated by a novel block copolymer. J. Non-Cryst. Solids 353, 1657 2007CrossRefGoogle Scholar
13Chen, S.Y., Jang, L.Y., Cheng, S.: Synthesis of thermally stable zirconia-based mesoporous materials via a facile post-treatment. J. Phys. Chem. B 110, 11761 2006CrossRefGoogle Scholar
14Signoretto, M., Breda, A., Somma, F., Pinna, F., Cruciani, G.: Mesoporous sulphated zirconia by liquid-crystal templating method. Microporous Mesoporous Mater. 91, 23 2006CrossRefGoogle Scholar
15Friess, W.: Collagen—Biomaterial for drug delivery. J. Pharm. Biopharm. 45, 113 1998CrossRefGoogle ScholarPubMed
16Smith, J.W.: Molecular pattern in native collagen. Nature 219, 157 1968CrossRefGoogle ScholarPubMed
17Steplewski, A., Hintze, V., Fertala, A.: Molecular basis of organization of collagen fibrils. J. Struct. Biol. 157, 297 2007CrossRefGoogle ScholarPubMed
18Eglin, D., Mosser, G., Giraud-Guille, M.M., Livage, J., Coradin, T.: Type I collagen, a versatile liquid crystal biological template for silica structuration from nano- to microscopic scales. Soft Matter 1, 129 2005CrossRefGoogle ScholarPubMed
19Heinemann, S., Heinemann, C., Ehrlich, H., Meyer, M., Baltzer, H., Worch, H., Hanke, T.: A novel biomimetic hybrid material made of silicified collagen: Perspectives for bone replacement. Adv. Eng. Mater. 9, 1061 2007CrossRefGoogle Scholar
20Bai, H.Y., Xu, K., Xu, Y.J., Matsui, H.: Fabrication of Au nanowires of uniform length and diameter using a monodisperse and rigid biomolecular template: Collagen-like triple helix. Angew. Chem. Int. Ed. 46, 3319 2007CrossRefGoogle ScholarPubMed
21Deng, D.H., Liao, X.P., Shi, B.: Synthesis of porous carbon fibers from collagen fiber. Chem. Sus. Chem 1, 298 2008CrossRefGoogle ScholarPubMed
22Covington, A.D.: Modern tanning chemistry. Chem. Soc. Rev. 26, 111 1997CrossRefGoogle Scholar
23Evans, N.A., Milligan, B., Montgomery, K.C.: Collagen cross-linking: New binding sites for mineral tannage. J. Am. Leather Chem. Assoc. 82, 86 1987Google Scholar
24Deng, D.H., Tang, R., Liao, X.P., Shi, B.: Using collagen fiber as a template to synthesize hierarchical mesoporous alumina fiber. Langmuir 24, 368 2008CrossRefGoogle ScholarPubMed
25Lu, X.Y.: A brief discussion on manufacture of hide powder for tannin analysis. Chem. Ind. Forest Products 20, 71 2000Google Scholar
26Barrett, E.P., Joyner, L.G., Halenda, P.H.: The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J. Am. Chem. Soc. 73, 373 1951CrossRefGoogle Scholar
27Brunauer, S., Emmett, P.H., Teller, E.: Adsorption of gases in multimolecular layers. J. Am. Chem. Soc. 60, 309 1938CrossRefGoogle Scholar
28Jorge-Herrero, E., Fernandez, P., Turnay, J., Olmo, N., Calero, P., Garcia, R., Freile, I., Castillo-Olivares, J.L.: Influence of different chemical cross-linking treatments on the properties of bovine pericardium and collagen. Biomaterials 20, 539 1999CrossRefGoogle ScholarPubMed
29Singhal, A., Toth, L.M., Lin, J.S., Affholter, K.: Zirconium(IV) tetramer/octamer hydrolysis equilibrium in aqueous hydrochloric acid solution. J. Am. Chem. Soc. 118, 11529 1996CrossRefGoogle Scholar
30Baes, C.F., Mesmer, R.F.: The Hydrolysis of Cations Wiley Press New York 1976Google Scholar
31Kruk, M., Jaroniec, M.: Gas adsorption characterization of ordered organic-inorganic nanocomposite materials. Chem. Mater. 13, 3169 2001CrossRefGoogle Scholar
32Sun, Z.Y., Zhang, X.R., Na, N., Liu, Z.M., Han, B.X., An, G.M.: Synthesis of ZrO2-carbon nanotube composites and their application as chemiluminescent sensor material for ethanol. J. Phys. Chem. B 110, 13410 2006CrossRefGoogle ScholarPubMed
33Zhu, L.Q., Fang, Q., He, G., Liu, M., Zhang, L.D.: Microstructure and optical properties of ultra-thin zirconia films prepared by nitrogen-assisted reactive magnetron sputtering. Nanotechnology 16, 2865 2005CrossRefGoogle Scholar
34Shukla, S., Seal, S., Vij, R., Bandyopadhyay, S., Rahman, Z.: Effect of nanocrystallite morphology on the metastable tetragonal phase stabilization in zirconia. Nano Lett. 2, 989 2002CrossRefGoogle Scholar