Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-28T16:57:56.906Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and Characterization of Synthetic F-Mica Containing Glass-Ceramics in the System SiO2·Al2O3·B2O3·CaO·MgO·Li2O·(K,Na)2O·F

Published online by Cambridge University Press:  03 March 2011

D.U. Tulyaganov ,
S. Agathopoulos ,
H.R. Fernandes  and
J.M.F. Ferreira
D.U. Tulyaganov
Affiliation:
Department of Ceramics and Glass Engineering, CICECO, University of Aveiro,Aveiro 3810-193, Portugal
S. Agathopoulos
Affiliation:
Department of Ceramics and Glass Engineering, CICECO, University of Aveiro,Aveiro 3810-193, Portugal
H.R. Fernandes
Affiliation:
Department of Ceramics and Glass Engineering, CICECO, University of Aveiro,Aveiro 3810-193, Portugal
J.M.F. Ferreira*
Affiliation:
Department of Ceramics and Glass Engineering, CICECO, University of Aveiro,Aveiro 3810-193, Portugal
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Ions of Li, Na, K, and B were incorporated in Ca-mica, CaMg3Al2Si2O10F2. The crystallization process and the properties of the resulting glass-ceramics were experimentally determined, and the role of the anions and cations is discussed. According to the results, Li, K, and Na ions strongly affected the formation of the crystalline phases. Until 900 °C, pargasite and F-cannilloite amphiboles and KLi-mica were predominately crystallized. The two amphiboles are dissociated, yielding stable forsterite at 900 °C and Ca-mica and spinel at 950 °C. KLi-mica showed remarkable stability and growth within the investigated temperature range, until 1000 °C. The optimum crystallization temperature for the investigated glass-ceramics is between800 °C and 900 °C. The produced glass-ceramics exhibited capability for easy bulk crystallization, high whiteness, translucency, and mechanical and chemical properties suitable for several applications.

Keywords

AmphibolesGlass-ceramicsCrystallization
Type
Articles
Information
Journal of Materials Research , Volume 19 , Issue 4 , April 2004 , pp. 1234 - 1242
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Ryan, W.: Properties of Ceramic Materials , 2nd ed. (Pergamon Press, Oxford, England, 1978)Google Scholar
2Grossman, D.G.: Glass-ceramic articles with oriented crystals and method, U.S. Patent No. 3 905 824 (16 Sept. 1975).Google Scholar
3Pauling, L.: Structure of micas and related minerals. Nat. Acad. Soc. Proc. 16, 123 (1930).CrossRefGoogle ScholarPubMed
4 Annual Minerals Review. Am. Ceram. Soc. Bull. 8, 136 (1999).Google Scholar
5Noda, T.: Synthetic mica research in Japan. J. Am. Ceram. Soc. 38, 147 (1955).CrossRefGoogle Scholar
6Kukolev, G.V.: Silicon Chemistry and Physical Chemistry of Silicates (Vyshayashkola, Moscow, 1966) (in Russian)Google Scholar
7Grossman, D.G.: Machinable glass-ceramics based on thetrasilicic mica. J. Am. Ceram. Soc. 55, 446 (1972).CrossRefGoogle Scholar
8Daniels, W.H. and Moore, R.L.: Crystallization of a thetrasilicic fluormica glass. J. Am. Ceram. Soc. 58, 217 (1975).CrossRefGoogle Scholar
9Beall, G.N.: Glass-ceramics: Recent development and applications. Ceram. Trans. 30, 241 (1993).Google Scholar
10Hölland, W. and Vogel, W.: A new type of phlogopite crystal in machinable glass-ceramics. Glass Technology. 24, 318 (1983).Google Scholar
11Chyung, C.K., Beall, G.H., and Grossman, D.G.: Proc. 10th Int. Congress on Glass, Tokyo, 14, (1974), p. 33.Google Scholar
12Saraswati, V.: Additive induced crystallization of mica phase in K2O-SiO2-MgO-F glass-ceramics. J. Non-Cryst. Solids. 124, 254 (1990).CrossRefGoogle Scholar
13Fang, P.A. and Wu, Z.P.: Effect of microstructural evolution on the mechanical properties of lepidolite based glass-ceramics. J. Eur. Ceram. Soc. 22, 1381 (2002).CrossRefGoogle Scholar
14Huang, W. and Zhu, P.: Change in microstructure during the crystallization process of lepidolite based glass/ceramics. J. Chinese Silicate Society. 11, 430 (1983).Google Scholar
15Tomoko, U., Toshishiro, K., Shin, N. and Akira, J.I.: Microstructure of mica-based nanocomposite glass-ceramics: Microstructure of mica-based nanocomposite glass-ceramics. J. Am. Ceram. Soc. 76, 539 (1993).Google Scholar
16Taruta, S., Mukoyama, K., Suzuki, S.S., Kitajima, K. and Takusagawa, N.: Crystallization process and some properties of calcium mica-apatite glass-ceramics. J. Non-Cryst. Solids. 296, 201 (2001).CrossRefGoogle Scholar
17Henry, J. and Hill, R.G.: The influence of lithia content on the properties of fluorphlogopite glass-ceramics. I. Nucleation and crystallization behaviour. J. Non-Cryst. Solids. 319, 1 (2003).CrossRefGoogle Scholar
18Henry, J. and Hill, R.G.: The influence of lithia content on the properties of fluorphlogopite glass-ceramics. II. Microstructure hardness and machinability. J. Non-Cryst. Solids. 319, 13 (2003).CrossRefGoogle Scholar
19Denry, I.L., Lejus, A.M., Thery, J. and Masse, M.: Preparation and characterization of new lithium containing glass-ceramic. Mater. Res. Bull. 34, 1615 (1999).CrossRefGoogle Scholar
20Vogel, W.: Chemistry of Glasses (The American Ceramic Society, Westerwille, OH, 1985)Google Scholar
21Ibrahim, D.M. and El-Meliegy, E.A.: Mica leucite dental porcelain. Br. Ceram. Trans. 100, 260 (2001).CrossRefGoogle Scholar
22Pavlushkin, N.M.: Principals of Glass Ceramics Technology , 2nd ed. (Stroiizdat, Moscow, 1979) (in Russian)Google Scholar
23Gebhardt, A., Höche, T., Carl, G. and Khodos, I.I.: TEM study of the origin of cabbage shaped mica crystal aggregates in machinable glass-ceramics. Acta Mater. 47, 4427 (1999).CrossRefGoogle Scholar
24Omar, A.A., El-Shennawi, A.W.A. and Hamzawi, E.M.: Effect of isomorphous substitutions on crystallization of fluorrichterite glasses. Key Eng. Mater. 132136, 836 (1997).CrossRefGoogle Scholar
25Fu, D., Faust, W.D. and Lee, A.W.: Porcelain enamels with improved chip resistance. Ceramic Engineering and Science Proceedings. 21, 25 (2000).Google Scholar
26Mirsaneh, M., Reaney, I.M., and James, P.F.: Phase evolution in K-fluorrichterite glass-ceramic, Extended Abstracts Int. Congress on Glass, 2, Edinburgh, Scotland, 1–6 July 2001, pp. 9–10.Google Scholar
27Stokes, C.W., Hand, R.J., and van Noort, R.: Flourcanasite glass-ceramics for dental applications, Extended Abstracts Int. Congress on Glass, 2, Edinburgh, Scotland, 1–6 July 2001, p. 15.Google Scholar