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Synthesis and characterization of new layered polyoxometallates–1,10-decanediamine intercalative nanocomposites

Published online by Cambridge University Press:  03 March 2011

Guangjin Zhang ,
Haohao Ke ,
Tao He ,
Debao Xiao ,
Zhaohui Chen ,
Wensheng Yang  and
Jiannian Yao
Guangjin Zhang
Affiliation:
Key Laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
Haohao Ke
Affiliation:
Key Laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
Tao He
Affiliation:
Key Laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
Debao Xiao
Affiliation:
Key Laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
Zhaohui Chen
Affiliation:
Key Laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
Wensheng Yang
Affiliation:
Key Laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
Jiannian Yao*
Affiliation:
Key Laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
*
b)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Hydrothermal reaction of phosphomolybdic acid (PMo12) and phosphotungstic acid (PW12) with the surfactant template 1,10-decanediamine (1,10-DAD) yielded two new nanocomposites, [C10H20(NH2)2]2·H3PMo12O40·(H2O)7.5 and [C10H20(NH2)2]2·H3PW12O40·(H2O)2.4. The produced needlelike crystals of the two nanocomposites have fine-layered structures. X-ray diffraction analyses indicate that change of polyoxometallates has little effect on the tilt angle of the 1,10-DAD molecules for such polyoxometallates–organic amine systems. Fourier transform infrared and Raman spectra show that in the hybrid, the PMo12 forms infinite two-dimensional networks, and the PW12 keeps its Keggin structure in the hybrid except distortion to some degree. The two nanocomposites show different photochromic properties; PMo12–DAD hybrid can be colored under ultraviolet irradiation, whereas PW12–DAD hybrid cannot.

Keywords

HydrothermalCompositeMicrostructure
Type
Articles
Information
Journal of Materials Research , Volume 19 , Issue 2 , February 2004 , pp. 496 - 500
Copyright
Copyright © Materials Research Society 2004

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References

REFERENCES

1Kagan, C.R., Mitzi, D.B. and Dimitrakopoulos, C.D.: Science 286 945 (1999).CrossRefGoogle Scholar
2Li, H., Eddaoudi, M., O’Keeffe, M. and Yaghi, O.M.: Nature 402 276 (1999).CrossRefGoogle Scholar
3Huo, Q., Margolese, D.I., Clesla, U., Feng, P., Gler, T.E., Sleger, P., Leon, R., Petroff, P.M., Schuth, F. and Stucky, G.D.: Nature 368 317 (1994).CrossRefGoogle Scholar
4Janauer, G.G., Dobley, A., Guo, J., Zavalij, P. and Whittingham, M.S.: Chem. Mater. 8 2096 (1996).CrossRefGoogle Scholar
5Kerr, T.A., Wu, H. and Nazar, L.F.: Chem. Mater. 8 2005 (1996).CrossRefGoogle Scholar
6Wu, C.G., Degroot, D.C., Marcy, H.O., Schindler, J.L., Kannewurf, C.R., Liu, Y.J., Hirpo, W. and Kanatzidis, M.G.: Chem. Mater. 8 1992 (1996).CrossRefGoogle Scholar
7Kurmoo, M., Bonamico, M., Bellitto, C., Fares, V., Federici, F., Guionneau, P., Ducasse, L., Kitagawa, H. and Day, P.: Adv. Mater. 10 545 (1998).3.0.CO;2-M>CrossRefGoogle Scholar
8Yamase, T.: Chem. Rev. 98 307 (1998).CrossRefGoogle Scholar
9Renneke, R.F., Pasquah, M. and Hill, C.L.: J. Am. Chem. Soc. 112 6585 (1990).CrossRefGoogle Scholar
10Gomez-Romero, P. and Lira-Cantu, M.: Adv. Mater. 2 144 (1997).CrossRefGoogle Scholar
11Stein, A., Fendorf, M., Jarvie, T.P., Mueller, K.T., Benesi, A.J. and Mallouk, T.E.: Chem. Mater. 7 304 (1995).CrossRefGoogle Scholar
12Ouahab, L.: Chem. Mater. 9 1909 (1997).CrossRefGoogle Scholar
13Strandberg, R.: Acta Chem. Scand. Ser. A 358 (1975).Google Scholar
14Mahmoud, S.K., Song, I.K., Duncan, D.C., Hill, C.L. and Barteau, M.A.: Inorg. Chem. 37 398 (1998).Google Scholar
15Bouhaouss, A. and Aldebert, P.: Mater. Res. Bull. 83 292 (1983).Google Scholar
16Brown, G.M., Noe-Sprilet, M.R., Busing, W.R. and Levy, H.A.: Acta Crystallogr. Sect B 33 1038 (1977).CrossRefGoogle Scholar
17Rocchiccioli-deltcheff, C., Fournier, M., Franck, R. and Thouvenot, R.: Inorg. Chem. 22 207 (1983).CrossRefGoogle Scholar
18Thouvenot, R., Fournier, M., Franck, R. and Rocchiccioli-deltcheff, C.: Inorg. Chem. 23 598 (1984).CrossRefGoogle Scholar
19Pope, M.T. and Varga, G.M.: Inorg. Chem. 5 1249 (1966).CrossRefGoogle Scholar
20Altenau, J.J., Pope, M.T. and Prados, R.A.: Inorg. Chem. 14 417 (1975).CrossRefGoogle Scholar