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Spectroscopic study of l-arginine interaction with potassium dihydrogen phosphate crystals

Published online by Cambridge University Press:  31 January 2011

Jayesh R. Govani ,
William G. Durrer ,
Marian Manciu ,
Cristian Botez  and
Felicia S. Manciu
Felicia S. Manciu*
Affiliation:
Department of Physics, University of Texas at El Paso, El Paso, Texas 79968
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

Inorganic potassium dihydrogen phosphate (KDP) is widely known for its value as a nonlinear optical material. In this study, pure and l-arginine–doped KDP single crystals were grown by the slow solvent evaporation technique and further subjected to infrared absorption and Raman studies for the confirmation of chemical group functionalization and possible bonding between the organic and inorganic materials. The appearance in the infrared absorption spectra of additional vibrational lines, which mostly originate from disturbed N–H, C–H, and C–N bonds of the l-arginine–doped salt, confirm the interaction between KDP and the organic material. This affirmation is supported by more evidence from Raman measurements, where the disappearance of NH vibrations of the amino group is observed. We are thus led to the possibility of hydrogen bonding primarily between the nucleophilic O− of the phosphate unit of KDP and the amino group of the l-arginine.

Keywords

Infrared (IR) spectroscopyRaman spectroscopy
Type
Articles
Information
Journal of Materials Research , Volume 24 , Issue 7 , July 2009 , pp. 2316 - 2320
Copyright
Copyright © Materials Research Society 2009

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