Hostname: page-component-586b7cd67f-2brh9 Total loading time: 0 Render date: 2024-11-28T10:39:50.177Z Has data issue: false hasContentIssue false
  • English
  • Français

Photoinduced degradation of organic dye over LiBiO3 under illumination of white fluorescent light

Published online by Cambridge University Press:  31 January 2011

Naoki Kikugawa ,
Liqun Yang ,
Takehiko Matsumoto  and
Jinhua Ye
Jinhua Ye*
Affiliation:
National Institute for Materials Science, 1-2-1 Sengen, Tsukuba 305-0047, Japan
*
b)This author was an editor of this focus issue during the review and decision stage. For the JMR policy on review and publication of manuscripts authored by editors, please refer to http://www.mrs.org/jmr_policy
Get access

Abstract

We report dye-degradation effects of a semiconductor LiBiO3 revealed under illumination of a conventionally used white fluorescent light. Optical absorbance spectra of LiBiO3 were broadened so smoothly, with the absorption edge penetrated to around 730 nm, that the material was able to absorb a wide range of visible light. Results showed that solution of a standard dye, methylene blue, was degraded completely after 4 h illumination. Furthermore, the value of total organic carbon decreased 70% in the decolorized solution, suggesting that the molecular form of the original methylene blue was mineralized effectively to nonorganic fragments by the photoinduced oxidization effect. Moreover, the wavelength dependence of apparent photonic efficiency was evaluated using a standard Xe lamp coupled with monochromatic filters. These results were interpreted from the viewpoint of this material’s electronic structure.

Keywords

OxidationOxidePhotochemical
Type
Articles
Information
Journal of Materials Research , Volume 25 , Issue 1: Photocatalysis for Energy and Environmental Sustainability , January 2010 , pp. 177 - 181
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Fujishima, A., Hashimoto, K., Watanabe, T.TiO2 Photocatalysis Fundamentals and Applications (BKC Inc, Tokyo, Japan 1999)Google Scholar
2.Hoffmann, M.R., Martin, S.T., Choi, W.Y., Bahnemann, D.W.Environmental applications of semiconductor photocatalysis. Chem. Rev. 95, 69 (1995)Google Scholar
3.Honda, K., Fujishima, A.Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37 (1972)Google Scholar
4.Houas, A., Lachheb, H., Ksibi, M., Elaloui, E., Guillard, C., Herrmann, J.M.Photocatalytic degradation pathway of methylene blue in water. Appl. Catal., B 31, 145 (2001)CrossRefGoogle Scholar
5.Poulious, I., Micropoulou, E., Panou, R., Kostopoulou, E.Photooxidation of eodin Y in the presence of semiconducting oxides. Appl. Catal., B 41, 345 (2003)Google Scholar
6.Syoufian, A., Satriya, O.H., Nakashima, K.Photocatalytic activity of titania hollow spheres: Photodecomposition of methylene blue as a target molecule. Catal. Commun. 8, 755 (2007)CrossRefGoogle Scholar
7.Wang, W., Silva, C.G., Faria, J.L.Photocatalytic degradation of chromotrope 2R using nanocrystalline TiO2/activated-carbon composite catalysts. Appl. Catal., B 70, 470 (2007)CrossRefGoogle Scholar
8.Okada, K., Yanagisawa, T., Kameshima, Y., Nakajima, A.Properties of TiO2 prepared by acid treatment of BiTiO3. Mater. Res. Bull. 42, 1921 (2007)CrossRefGoogle Scholar
9.Syoufian, A., Satriya, O.H., Nakashima, K.Photocatalytic activity of titania hollow spheres: Photodecomposition of methylene blue as a target molecule. Catal. Commun. 8, 755 (2007)Google Scholar
10.Borgarello, E., Kiwi, J., Gratzel, M., Pelizzetti, E., Visca, M.Visible-light induced water cleavage in colloidal solutions of chromium-doped titanium dioxide particles. J. Am. Chem. Soc. 104, 2996 (1982)CrossRefGoogle Scholar
11.Asahi, R., Morikawa, T., Ohwaki, T., Aoki, K., Taga, Y.Visible-light photocatalysis in nitrogen-doped titanium oxides. Science 293, 269 (2001)Google Scholar
12.Irie, H., Watanabe, Y., Hashimoto, K.Nitrogen-concentration dependence of photocatalytic activity of TiO2–xNx powders. Chem. Lett. 32, 772 (2003)Google Scholar
13.Zou, Z., Ye, J., Sayama, K., Arakawa, H.Direct splitting water under visible light irradiation with an oxide semiconductor photocatalyst. Nature 414, 625 (2001)Google Scholar
14.Kudo, A., Ueda, K., Kato, H., Minami, I.Photocatalytic O2 evolution under visible light irradiation on BiVO4 in aqueous AgNO3 solution. Catal. Lett. 53, 229 (1998)CrossRefGoogle Scholar
15.Kudo, A., Omori, K., Kato, H.A novel aqueous process for preparation of crystal form-controlled and highly crystalline BiVO4 powder from layered vanadates at room temperature and its photocatalytic and photophysical properties. J. Am. Chem. Soc. 121, 11459 (1999)CrossRefGoogle Scholar
16.Tang, J.W., Zou, Z.G., Ye, J.H.Photocatalytic decomposition of organic contaminants by Bi2WO6 under visible light irradiation. Catal. Lett. 92, 53 (2004)CrossRefGoogle Scholar
17.Ye, J., Zou, Z.Visible light sensitive photocatalysis In1–x MxTaO4 (M = 3d transition-metal) and their activity controlling factors. J. Phys. Chem. Solids 66, 266 (2005)Google Scholar
18.Kudo, A.Development of photocatalyst materials for water splitting. Int. J. Hydrogen Energy 31, 197 (2006)Google Scholar
19.Maruyama, Y., Irie, H., Hashimoto, K.Visible light sensitive photocatalyst, delafossite structured α-AgGaO2. J. Phys. Chem. B 110, 23274 (2006)CrossRefGoogle Scholar
20.Abe, R., Takami, H., Murakami, N., Ohtani, B.Pristine simple oxides as visible light driven photocatalysis: Highly efficient decomposition of organic compounds over platinum-loaded tungsten oxide. J. Am. Chem. Soc. 130, 7780 (2008)CrossRefGoogle Scholar
21.Wang, D., Kako, T., Ye, J.Efficient photocatalytic decomposition of acetaldehyde over a solid-solution perovskite (Ag0.75Sr0.25)(Nb0.75Ti0.25)3 under visible-light irradiation. J. Am. Chem. Soc. 130, 2724 (2008)Google Scholar
22.Kako, T., Zou, Z., Katagiri, M., Ye, J.Decomposition of organic compounds over NaBiO3 under visible light irradiation. Chem. Mater. 19, 198 (2007)CrossRefGoogle Scholar
23.Ouyang, S., Kikugawa, N., Chen, D., Zou, Z., Ye, J.A systematical study on photocatalytic properties of AgMO2 (M = Al, Ga, In): Effects of chemical compositions, crystal structures, and electronic structures. J. Phys. Chem. C 133, 1560 (2009)CrossRefGoogle Scholar
24.Li, X., Ye, J.Photocatalytic degradation of rhodamine B over Pb3Nb4O13/fumed SiO2 composite under visible light irradiation. J. Phys. Chem. C 111, 13109 (2007)CrossRefGoogle Scholar
25.Li, X., Kikugawa, N., Ye, J.Nitrogen-doped lamellar niobic acid with visible light-responsive photocatalytic activity. Adv. Mater. 20, 3816 (2008)Google Scholar
26.Kohtani, S., Koshiko, M., Kudo, A., Tokumura, K., Ishigaki, Y., Toriba, A., Hayakawa, K., Nakagaki, R.Photodegradation of 4-alkylphenols using BiVO4 photocatalyst under irradiation with visible light from a solar simulator. Appl. Catal., B 46, 573 (2003)Google Scholar
27.Li, G., Kako, T., Wang, D., Zou, Z., Ye, J.Composition dependence of the photophysical and photocatalytic properties of (AgNbO3)1–x(NaNbO3)x solid solutions. J. Solid State Chem. 180, 2845 (2007)CrossRefGoogle Scholar
28.Ouyang, S., Kikugawa, N., Zou, Z., Ye, J.Effective decolorizations and mineralizations of organic dyes over a silver germanium oxide photocatalyst under indoor-illumination irradiation. Appl. Catal., A 336, 309 (2009)Google Scholar
29.Kumada, N., Takahasi, N., Nomura, N., Sleight, A.W.Preparation and crystal structure of a new lithium bismuth oxide: LiBiO3. J. Solid State Chem. 126, 121 (1996)CrossRefGoogle Scholar
30.Segall, M.D., Lindan, P.J.D., Probert, M.J., Pickard, C.J., Hasnip, P.J., Clark, S.J., Payne, M.C.First-principles simulation: Ideas, illustrations and the CASTEP code. J. Phys. Condens. Matter 14, 2717 (2002)Google Scholar
31.Yan, X., Ohno, T., Nishijima, K., Abe, R., Ohtani, B.Is methylene blue an appropriate substrate for a photocatalytic activity test? A study with visible-light responsive titania. Chem. Phys. Lett. 429, 606 (2006)Google Scholar