Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-24T11:38:46.413Z Has data issue: false hasContentIssue false

Microstructure, composition distribution and rupture performance of WC-(Ti,W)C-Ti(C,N)-Co gradient cemented carbonitrides with varied nitrogen

Published online by Cambridge University Press:  01 December 2016

Tian'en Yang
Affiliation:
School of Manufacturing Science and Engineering, Sichuan University, Chengdu 610065, People's Republic of China; and School of Engineering, University of Hull, East Yorkshire HU6 7RX, UK
Ji Xiong*
Affiliation:
School of Manufacturing Science and Engineering, Sichuan University, Chengdu 610065, People's Republic of China
*
a) Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

The gradient cemented carbonitrides with brittle cubic phases containing Ti removed in the surface layers were prepared in this paper. The microstructure, composition distribution, fracture morphology, and transverse rupture strength of these materials were investigated systematically. It is found that the difference between the maximum and the nominal cobalt content augments in the gradient layer, the lattice parameter of (Ti,W)C rises in the bulk inside the gradient border, and the (Ti,W)C cubic phases are refined in the inner bulk as the nitrogen is increased. Besides, the area fraction of WC in the gradient layer is higher than in the bulk, but it decreases remarkably close to the gradient border. The improvement of transverse rupture strength stability depends on thickening of gradient layers, and additionally the transgranular fracture of (Ti, W)C cubic phase can be hardly found in the gradient layer.

Type
Articles
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Zhou, X., Wang, K., Xu, Z., Liu, T., Li, G., Wang, Q., and He, J.: Effect of powder particle size on gradient formation and grain growth in ultrafine crystalline gradient cemented carbide. Int. J. Refract. Met. Hard Mater. 56, 63 (2015).CrossRefGoogle Scholar
Zhou, X., Xu, Z., Wang, K., Li, G., Liu, T., Wang, Q., and He, J.: One-step Sinter-HIP method for preparation of functionally graded cemented carbide with ultrafine grains. Ceram. Int. 42, 5362 (2015).Google Scholar
Zhang, W., Du, Y., and Peng, Y.: Effect of TaC and NbC addition on the microstructure and hardness in graded cemented carbides: Simulations and experiments. Ceram. Int. 42, 428 (2016).CrossRefGoogle Scholar
Frykholm, R., Jansson, B., and Andrén, H.O.: The influence of carbon content on formation of carbo-nitride free surface layers in cemented carbides. Int. J. Refract. Met. Hard Mater. 20, 345 (2002).Google Scholar
Mohammadpour, M., Abachi, P., and Pourazarang, K.: Effect of cobalt replacement by nickel on functionally graded cemented carbonitrides. Int. J. Refract. Met. Hard Mater. 30, 42 (2012).CrossRefGoogle Scholar
Garcia, J.: Investigations on kinetics of formation of fcc-free surface layers on cemented carbides with Fe–Ni–Co binders. Int. J. Refract. Met. Hard Mater. 29, 306 (2011).Google Scholar
Xiong, J., Guo, Z., Yang, M., Xiong, S., Chen, J., Wu, Y., Wen, B., and Cao, D.: Effect of ultra-fine TiC0.5N0.5 on the microstructure and properties of gradient cemented carbide. J. Mater. Process. Technol. 209, 5293 (2009).Google Scholar
Zhang, W., Du, Y., Peng, Y., Xie, W., Wen, G., and Wang, S.: Experimental investigation and simulation of the effect of Ti and N contents on the formation of fcc-free surface layers in WC-Ti(C,N)-Co cemented carbides. Int. J. Refract. Met. Hard Mater. 41, 638 (2013).Google Scholar
Yang, T., Xiong, J., Sun, L., Guo, Z., and Ding, D.: Effect of nitrogen introduction methods on the microstructure and properties of gradient cemented carbides. Int. J. Miner., Metall. Mater. 18, 709 (2011).CrossRefGoogle Scholar
Frykholm, R., Ekroth, M., and Jansson, B.: Effect of cubic phase composition on gradient zone formation in cemented carbides. Int. J. Refract. Met. Hard Mater. 19, 527 (2001).Google Scholar
Zhang, W., Du, Y., Chen, W., Peng, Y., Zhou, P., Wang, S., Wen, G., and Xie, W.: CSUDDCC1-A diffusion database for multicomponent cemented carbides. Int. J. Miner., Metall. Mater. 43, 164 (2014).Google Scholar
Ekroth, M., Frykholm, R., Lindholm, M., Andrén, H.O., and Ågren, J.: Gradient zones in WC-Ti(C,N)-Co-based cemented carbides: Experimental study and computer simulations. Acta Mater. 48, 2177 (2000).Google Scholar
Schwarzkopf, M., Exner, H., and Fischmeister, H.F.: Kinetics of compositional modification of (W, Ti)C-WC-Co alloy surfaces. Mater. Sci. Eng., A 105–106, 225 (1988).CrossRefGoogle Scholar
Streitenberger, P. and Zöllner, D.: The envelope of size distributions in Ostwald ripening and grain growth. Acta Mater. 88, 334 (2015).CrossRefGoogle Scholar
Li, J., Guo, C., Ma, Y., Wang, Z., and Wang, J.: Effect of initial particle size distribution on the dynamics of transient Ostwald ripening: A phase field study. Acta Mater. 90, 10 (2015).CrossRefGoogle Scholar
Morton, C.W., Wills, D.J., and Stjernberg, K.: The temperature ranges for maximum effectiveness of grain growth inhibitors in WC–Co alloys. Int. J. Refract. Met. Hard Mater. 23, 287 (2005).Google Scholar
Frykholm, R. and Andrén, H.O.: Development of the microstructure during gradient sintering of a cemented carbide. Mater. Chem. Phys. 67, 203 (2001).Google Scholar
Yang, Q., Xiong, W., Zhang, M., Huang, B., and Chen, S.: Microstructure and mechanical properties of Mo-free Ti(C,N)-based cermets with Ni–xCr binders. J. Alloys Compd. 636, 270 (2015).Google Scholar
Xu, Q., Ai, X., Zhao, J., Zhang, H., Qin, W., and Gong, F.: Effect of heating rate on the mechanical properties and microstructure of Ti(C,N)-based cermets. Mater. Sci. Eng., A 628, 281 (2015).CrossRefGoogle Scholar
Zhou, W., Zheng, Y., Zhao, Y., Ma, Y., and Xiong, W.: Microstructure characterization and mechanical properties of Ti(C,N)-based cermets with AlN addition. Ceram. Int. 41, 5010 (2015).CrossRefGoogle Scholar
Xu, Q., Zhao, J., Ai, X., Qin, W., Wang, D., and Huang, W.: Effect of Mo2C/(Mo2C + WC) weight ratio on the microstructure and mechanical properties of Ti(C,N)-based cermet tool materials. J. Alloys Compd. 649, 885 (2015).CrossRefGoogle Scholar
Lindahl, P., Gustafson, P., Rolander, U., Stals, L., and Andrén, H.: Microstructure of model cermets with high Mo or W content. Int. J. Refract. Met. Hard Mater. 17, 411 (1999).Google Scholar
Liu, Y., Wang, H., Long, Z., Yang, J., and Zhang, W.: Enhancement on the transverse fracture strength of functional graded structure cemented carbides. J. Mater. Sci. 40, 5525 (2005).CrossRefGoogle Scholar
Khalili, A. and Kromp, K.: Statistical properties of Weibull estimators. J. Mater. Sci. 26, 6741 (1991).Google Scholar
Klein, C.A.: Characteristic strength, Weibull modulus, and failure probability of fused silica glass. Opt. Eng. 48, 933 (2009).CrossRefGoogle Scholar
Xie, H., Liu, Y., Ye, J., Li, M., Zhu, Y., and Fan, H.: Effect of (Cr0.8V0.2)2(C,N) addition on microstructure and mechanical properties of WC-8Co cemented carbides. Int. J. Refract. Met. Hard Mater. 47, 145 (2014).Google Scholar
Sun, Y., Su, W., Yang, H., and Ruan, J.: Effects of WC particle size on sintering behavior and mechanical properties of coarse grained WC-8Co cemented carbides fabricated by unmilled composite powders. Ceram. Int. 41, 14482 (2015).Google Scholar
Shatov, A., Ponomarev, S., and Firstov, S.: Fracture of WC-Ni cemented carbides with different shape of WC crystals. Int. J. Refract. Met. Hard Mater. 26, 68 (2008).Google Scholar