Hostname: page-component-cd9895bd7-jn8rn Total loading time: 0 Render date: 2024-12-18T19:55:08.488Z Has data issue: false hasContentIssue false
  • English
  • Français

Mesoporous silica beads encapsulated with functionalized palladium nanocrystallites: Novel catalyst for selective hydrogen evolution

Published online by Cambridge University Press:  15 June 2017

Prem Chandra Pandey Open the ORCID record for Prem Chandra Pandey [Opens in a new window] ,
Shubhangi Shukla  and
Yashashwa Pandey
Prem Chandra Pandey*
Affiliation:
Department of Chemistry, Indian Institute of Technology (BHU), Varanasi 221005, India
Shubhangi Shukla
Affiliation:
Department of Chemistry, Indian Institute of Technology (BHU), Varanasi 221005, India
Yashashwa Pandey
Affiliation:
Department of Chemistry, Indian Institute of Technology (BHU), Varanasi 221005, India
*
a) Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

2-(3,4 epoxycyclohexyl)ethyltrimethoxysilane (EETMS)/3-glycidoxypropyltrimethoxysilane (GPTMS) mediated, in situ synthesis of functional palladium (Pd) nanocomposites over the graphene oxide (GO) surface is reported. The prepared nanocomposites viz, Pd/EETMS, Pd/GPTMS, Pd/GO/EETMS, and Pd/GO/GPTMS, are encapsulated into mesoporous (2–10 nm) silica-alginate beads to primarily serve the development of cost-effective catalyst for on-board generation of hydrogen. Major findings involve: (i) the synthesis of porous silica alginate beads, with the controlled pore sizes (2–10 nm) as a function of concentration of alkoxysilanes, (ii) onboard release of hydrogen from the decomposition of hydrazine, which is evaluated as: (1) time-dependent disappearance of the N–N bond stretching band at 1069 cm−1 based on the FTIR spectroscopy, (2) volumetric estimation of the equimolar hydrogen using methylene blue (MB); (3) catalytic reduction of p-nitroaniline (PNA). The decomposition of high concentration of hydrazine is made possible using very low concentration of palladium. On calcination the efficiency of catalysts found to enhance further. The noteworthy finding is probing the hydrogen evolution using FTIR spectroscopy. Hydrogen selectivity of ∼100% is obtained from the most efficient catalyst (Pd/GO/EETMS-623 K).

Keywords

mesoporoussilica-alginate beadsencapsulationhydrazinehydrogen evolution
Type
Articles
Information
Journal of Materials Research , Volume 32 , Issue 18 , 28 September 2017 , pp. 3574 - 3584
Check for updates
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Contributing Editor: Xiaobo Chen

References

REFERENCES

Li, X., Yu, J., Low, J., Fang, Y., Xiaoc, J., and Chen, X.: Engineering heterogeneous semiconductors for solar water splitting. J. Mater. Chem. A 3, 2485–2534 (2015).CrossRefGoogle Scholar
Chen, X., Shen, S., Guo, L., and Mao, S.S.: Semiconductor-based photocatalytic hydrogen generation. Chem. Rev. 110, 6503–6570 (2010).CrossRefGoogle ScholarPubMed
Chen, X., Li, C., Grätzel, M., Kosteckid, R., and Mao, S.S.: Nanomaterials for renewable energy production and storage. Chem. Soc. Rev. 41, 7909–7937 (2012).Google Scholar
Singh, S.K. and Xu, Q.: Nanocatalysts for hydrogen generation from hydrazine. Catal. Sci. Technol. 3, 1889–1900 (2013).CrossRefGoogle Scholar
Orimo, S.I., Nakamori, Y., Jennifer, R.E., Zuttel, A., and Jensen, C.M.: Complex hydrides for hydrogen storage. Chem. Rev. 107, 4111–4132 (2007).CrossRefGoogle ScholarPubMed
Yadav, M. and Xu, Q.: Liquid-phase chemical hydrogen storage materials. Energy Environ. Sci. 5, 9698–9725 (2012).CrossRefGoogle Scholar
Zheng, M., Cheng, R., Chen, X., Li, N., Li, L., Wang, X., and Zhang, T.: A novel approach for CO-free H2 production via catalytic decomposition of hydrazine. Int. J. Hydrogen Energy 30, 1081–1089 (2005).Google Scholar
Singh, S.K., Singh, A.K., Aranishi, K., and Xu, Q.: Noble-metal-free bimetallic nanoparticle-catalyzed selective hydrogen generation from hydrous hydrazine for chemical hydrogen storage. J. Am. Chem. Soc. 133, 19638–19641 (2011).CrossRefGoogle ScholarPubMed
Singh, S.K., Zhang, X.B., and Xu, Q.: Room-temperature hydrogen generation from hydrous hydrazine for chemical hydrogen storage. J. Am. Chem. Soc. 131, 9894–9895 (2009).Google Scholar
Liu, L.J., Burghaus, U., Besenbacher, F., and Wang, Z.L.: Preparation and characterization of nanomaterials for sustainable energy production. ACS Nano 4, 5517–5526 (2010).CrossRefGoogle ScholarPubMed
Bunker, C.E. and Smith, M.J.: Nanoparticles for hydrogen generation. J. Mater. Chem. 21, 12173–12180 (2011).CrossRefGoogle Scholar
Manukyan, K.V., Cros, A., Rouvimov, S., Miller, J., Mukasyan, A.S., and Wolf, E.E.: Low temperature decomposition of hydrous hydrazine over FeNi/Cu nanoparticles. Appl. Catal., A 476, 47–53 (2014).CrossRefGoogle Scholar
Oliaee, S.N., Zhang, C., Hwang, S.Y., Cheung, H.M., and Peng, Z.: Hydrogen production via hydrazine decomposition on model platinum–nickel nanocatalyst with a single (111) facet. J. Phys. Chem. C 120, 9764–9772 (2016).Google Scholar
Singh, S.K. and Xu, Q.: Complete conversion of hydrous hydrazine to hydrogen at room temperature for chemical hydrogen storage. J. Am. Chem. Soc. 131, 18032–18033 (2009).Google Scholar
Wang, J., Zhang, X-B., Wang, Z-L., Wang, L-M., and Zhang, Y.: Rhodium–nickel nanoparticles grown on graphene as highly efficient catalyst for complete decomposition of hydrous hydrazine at room temperature for chemical hydrogen storage. Energy Environ. Sci. 5, 6885–6888 (2012).Google Scholar
Yang, X., Zhang, X., Ma, Y., Huang, Y., Wang, Y., and Chen, Y.: Superparamagnetic graphene oxide–Fe3O4 nanoparticles hybrid for controlled targeted drug carriers. J. Mater. Chem. 19, 2710–2714 (2009).Google Scholar
Choi, Y., Bae, H.S., Seo, E., Jang, S., Park, K.H., and Kim, B.S.: Hybrid gold nanoparticle-reduced graphene oxide nanosheets as active catalysts for highly efficient reduction of nitroarenes. J. Mater. Chem. 21, 15431–15436 (2011).CrossRefGoogle Scholar
Kim, Y.K., Han, S.W., and Min, D.H.: Graphene oxide sheath on Ag nanoparticle/graphene hybrid films as an antioxidative coating and enhancer of surface-enhanced Raman scattering. ACS Appl. Mater. Interfaces 4, 6545–6551 (2012).Google Scholar
Bezbaruah, A.N., Krajangpan, S., Chisholm, B.J., Khan, E., and Elorza Bermudez, J.J.: Entrapment of iron nanoparticles in calcium alginate beads for groundwater remediation applications. J. Hazard. Mater. 166, 1339–1343 (2009).Google Scholar
Kim, H., Hong, H.J., Jung, J., Kim, S.H., and Yang, J.W.: Degradation of trichloroethylene (TCE) by nanoscale zero-valent iron (nZVI) immobilized in alginate bead. J. Hazard. Mater. 176, 1038–1043 (2010).Google Scholar
Pankongadisak, P., Ruktanonchai, U.R., Supaphol, P., and Suwantong, O.: Preparation and characterization of silver nanoparticles-loaded calcium alginate beads embedded in gelatin scaffolds. AAPS PharmSciTech 15, 1105–1115 (2014).CrossRefGoogle ScholarPubMed
Kuang, Y., Jianhua, D., Zhou, R., Chen, Z., Megharaj, M., and Naidu, R.: Calcium alginate encapsulated Ni/Fe nanoparticles beads for simultaneous removal of Cu (II) and monochlorobenzene. J. Colloid Interface Sci. 447, 85–91 (2015).Google Scholar
Klein, J., Stock, J., and Vorlop, K.D.: Pore size and properties of spherical Ca-alginate biocatalysts. Eur. J. Appl. Microbiol. Biotechnol. 18, 86–91 (1983).Google Scholar
Brunel, D., Cauvel, A., Renzo, F.D., Fajula, F., Fubini, B., Onida, B., and Garrone, E.: Preferential grafting of alkoxysilane coupling agents on the hydrophobic portion of the surface of micelle-templated silica. New J. Chem. 24, 807–813 (2000).Google Scholar
Pandey, P.C. and Singh, R.: Tetrahydrofuran hydroperoxide and 3-aminopropyl trimethoxysilane mediated controlled synthesis of Pd, Pd–Au, Au–Pd nanoparticles: Role of palladium nanoparticles on the redox electrochemistry of ferrocene monocarboxylic acid. Electrochim. Acta 138, 163–173 (2014).CrossRefGoogle Scholar
Pandey, P.C. and Pandey, G.: One-pot two-step rapid synthesis of 3-aminopropyltrimethoxysilane-mediated highly catalytic Ag@(PdAu) trimetallic nanoparticles. Catal. Sci. Technol. 6, 3911–3917 (2016).Google Scholar
Pandey, P.C., Shukla, S., and Pandey, Y.: 3-aminopropyltrimethoxysilane and grapheneoxide/reduced graphene oxide-induced generation of gold nanoparticles and their nanocomposites: Electrocatalytic and kinetic activity. RSC Adv. 6, 80549–80556 (2016).CrossRefGoogle Scholar
Pandey, P.C. and Pandey, G.: Synthesis of gold nanoparticles resistant to pH and salt for biomedical applications; functional activity of organic amine. J. Mater. Res. 31, 3313–3323 (2016).CrossRefGoogle Scholar
Tafreshi, S., Roldanab, A., and Nora de Leeuw, H.: Density functional theory calculations of the hydrazine decomposition mechanism on the planar and stepped Cu (111) surfaces. Phys. Chem. Chem. Phys. 17, 21533–21546 (2015).Google Scholar
Seo, T., Kurokawa, R., and Sato, B.: A convenient method for determining the concentration of hydrogen in water: Use of methylene blue with colloidal platinum. Med. Gas Res. 2, 1 (2012). doi: 10.1186/2045-9912-2-1.CrossRefGoogle ScholarPubMed
Pozun, Z.D., Rodenbusch, S.E., Keller, E., Tran, K., Tang, W., Stevenson, K.J., and Henkelman, G.: A systematic investigation of p-nitrophenol reduction by bimetallic dendrimer encapsulated nanoparticles. J. Phys. Chem. C 117, 7598–7604 (2013).Google Scholar
Gu, S., Wunder, S., Lu, Y., and Ballauff, M.: Kinetic analysis of the catalytic reduction of 4-nitrophenol by metallic nanoparticles. J. Phys. Chem. C 118, 18618–18625 (2014).CrossRefGoogle Scholar
Zhang, R., Liu, Lu., Li, Y., Wang, W., Li, R.: Electroxidation Kinetics of Hydrazine on Y-type Zeolite encapsulated Ni(II)(salen) Complex Supported on Graphite Modified Electrode. Int. J. Electrochem. Sci., 10, 2355–2369 (2015).Google Scholar
Darensbourg, D.J., Rodgers, J.L., and Fang, C.C.: The copolymerization of carbon dioxide and [2-(3,4-epoxycyclohexyl)ethyl]trimethoxysilane catalyzed by (salen)CrCl. Formation of a CO2 soluble polycarbonate. Inorg. Chem. 42, 4498–4500 (2003).Google Scholar
Paredes, J.I., Villar-Rodil, S., Martínez-Alonso, A., and Tascón, J.M.D.: Graphene oxide dispersions in organic solvents. Langmuir 24, 10560–10564 (2008).Google Scholar
Konios, D., Stylianakis, M.M., Stratakis, E., and Kymakis, E.: Dispersion behaviour of graphene oxide and reduced graphene oxide. J. Colloid Interface Sci. 430, 108–112 (2014).Google Scholar
Pérez-Lorenzo, M.: Palladium nanoparticles as efficient catalysts for Suzuki cross-coupling reactions. J. Phys. Chem. Lett. 3, 167–174 (2012).Google Scholar
Krittayavathananon, A., Srimuk, P., Luanwuthi, S., and Sawangphruk, M.: Palladium nanoparticles decorated on reduced graphene oxide rotating disk electrodes toward ultrasensitive hydrazine detection: Effects of particle size and hydrodynamic diffusion. Anal. Chem. 86, 12272–12278 (2014).Google Scholar
Zhang, X., Zhu, J., Tiwary, C.S., Ma, Z., Huang, H., Zhang, J., Lu, Z., Huang, W., and Wu, Y.: Palladium nanoparticles supported on nitrogen and sulfur dual-doped graphene as highly active electrocatalysts for formic acid and methanol oxidation. ACS Appl. Mater. Interfaces 8, 10858–10865 (2016).Google Scholar
Huang, Y.X., Xie, J.F., Zhang, X., Xiong, L., and Yu, H.Q.: Reduced graphene oxide supported palladium nanoparticles via photoassisted citrate reduction for enhanced electrocatalytic activities. ACS Appl. Mater. Interfaces 6, 15795–15801S (2014).Google Scholar
Kocak, C.C., Altın, A., Aslisen, B., and Kocak, S.: Electrochemical preparation and characterization of gold and platinum nanoparticles modified poly(taurine) film electrode and its application to hydrazine determination. Int. J. Electrochem. Sci. 11, 233–249 (2016).Google Scholar
Park, K., Yu, H.J., Chung, W.K., Kim, B.J., and Kim, S.H.: Effect of heat-treatment on CdS and CdS/ZnS nanoparticles. J. Mater. Sci. 44, 4315–4320 (2009).Google Scholar
Kuroda, K., Ishida, T., and Haruta, M.: Reduction of 4-nitrophenol to 4-aminophenol over Au nanoparticles deposited on PMMA. J. Mol. Catal. 298, 7–11 (2009).Google Scholar
Wunder, S., Polzer, F., Lu, Y., Mei, Y., and Ballauff, M.: Kinetic analysis of catalytic reduction of 4-nitrophenol by metallic nanoparticles immobilized in spherical polyelectrolyte brushes. J. Phys. Chem. C 114, 8814–8820 (2010).CrossRefGoogle Scholar
Kastner, C. and Thunemann, A.F.: Catalytic reduction of 4-nitrophenol using silver nanoparticles with adjustable activity. Langmuir 32, 7383–7391 (2016).Google Scholar
Supplementary material: File

Pandey supplementary material

Figures S1-S5 and Table1

Download Pandey supplementary material(File)
File 4.3 MB