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Low-temperature one-step synthesis of covalently chelated ZnO/dopamine hybrid nanoparticles and their optical properties

Published online by Cambridge University Press:  31 January 2011

WeiMin Huang ,
Peng Jiang ,
ChenYang Wei ,
DaKui Zhuang  and
Jianlin Shi
WeiMin Huang
Affiliation:
State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics of Chinese Academy of Sciences, Shanghai 200050, China
Peng Jiang
Affiliation:
State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics of Chinese Academy of Sciences, Shanghai 200050, China
ChenYang Wei
Affiliation:
State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics of Chinese Academy of Sciences, Shanghai 200050, China
DaKui Zhuang
Affiliation:
State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics of Chinese Academy of Sciences, Shanghai 200050, China
Jianlin Shi*
Affiliation:
State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics of Chinese Academy of Sciences, Shanghai 200050, China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Dopamine covalently chelated ZnO nanoparticles were synthesized by a nonaqueous one-step chemical process at a temperature as low as 60 °C. The formation of ZnO/dopamine hybrid structure was proved by x-ray powder diffraction (XRD), transmission electron microscopy (TEM), and Fourier transform infrared (FTIR) techniques. Detailed absorption, luminescence, and time-resolved decay studies were performed for these ZnO/dopamine hybrid nanoparticles. We observed an enhanced green emission, which could be assigned to a new band-gap emission based on the fast of nanosecond lifetime of the green emission. Our results demonstrated that the change of optical properties of ZnO nanoparticles after covalently chelated by dopamine ligands is closely associated with the formation of new band structure.

Keywords

NanostructureOptical propertiesOxide
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 7 , July 2008 , pp. 1946 - 1952
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1Shionoya, S.Yen, W.M.: Phosphor Handbook CRC Press LLC Boca Raton, FL 1999 255Google Scholar
2Travnikov, V.V., Freiberg, A.Savikhin, S.F.: Surface excitons in ZnO crystals. J. Lumin. 47, 107 1999CrossRefGoogle Scholar
3Anpo, M.Kubokawa, Y.: Photoluminescence of zinc oxide powder as a probe of electron–hole surface processes. J. Phys. Chem. 88, 5556 1984CrossRefGoogle Scholar
4Mollwo, E.: The effect of hydrogen on the conductivity and luminescence of zinc oxide crystals. J. Phys. A 138, 478 1954Google Scholar
5Kröger, F.A.Vink, H.J.: The origin of the fluorescence in self-activated ZnS, CdS, and ZnO. J. Chem. Phys. 22(2), 250 1954Google Scholar
6van Craeynest, F., Maenhout-van der Vorst, W.Dekeyser, W.: Interpretation of the yellow colour of heat-treated ZnO powder. Phys. Status Solidi B 8, 841 1965CrossRefGoogle Scholar
7Lehman, W.: Zinc oxide and zinc–cadmium oxide phosphors. J. Electrochem. Soc. 115, 538 1968CrossRefGoogle Scholar
8Davide Cozzoli, P., Kornowski, A.Weller, H.: Colloidal synthesis of organic-capped ZnO nanocrystals via a sequential reduction–oxidation reaction. J. Phys. Chem. B 109, 2638 2005CrossRefGoogle Scholar
9Gong, Y-Y., Andelman, T., Neumark, G.F., O’Brien, S.Kuskovsky, I.L.: Origin of defect-related green emission from ZnO nanoparticles: Effect of surface modification. Nanoscale Res. Lett. 2, 297 2007CrossRefGoogle Scholar
10Guo, L., Yang, S-H., Yang, C-L., Yu, P., Wang, J-N., Ge, W-K.Wong, G.K.L.: Synthesis and characterization of poly(vinylpyrrolidone)-modified zinc oxide nanoparticles. Chem. Mater. 12, 2268 2000CrossRefGoogle Scholar
11Norberg, N.S.Gamelin, D.R.: Influence of surface modification on the luminescence of colloidal ZnO nanocrystals. J. Phys. Chem. B 109, 20810 2005Google Scholar
12Rajh, T., Chen, L.X., Lukas, K., Liu, T., Thurnauer, M.C.Tiede, D.M.: Surface restructuring of nanoparticles: An efficient route for ligand–metal oxide crosstalk. J. Phys. Chem. B 106, 10543 2002CrossRefGoogle Scholar
13Rajh, T., Nedeljkovic, J.M., Chen, L.X., Poluektov, O.Thurnauer, M.C.: Improving optical and charge separation properties of nanocrystalline TiO2 by surface modification with vitamin C. J. Phys. Chem. B 103, 3515 1999CrossRefGoogle Scholar
14Thurnauer, M.C., Rajh, T.Tiede, D.M.: Surface modification of TiO2: Correlation between structure, charge separation and reduction properties. Acta Chem. Scand. A 51, 610 1997CrossRefGoogle Scholar
15Niederberger, M., Bartl, M.H.Stucky, G.D.: Benzyl alcohol and titanium tetrachloride—A versatile reaction system for the nonaqueous and low-temperature preparation of crystalline and luminescent titania nanoparticles. Chem. Mater. 14, 4364 2002Google Scholar
16Niederberger, M., Bartl, M.H.Stucky, G.D.: Benzyl alcohol and transition metal chlorides as a versatile reaction system for the nonaqueous and low-temperature synthesis of crystalline nano-objects with controlled dimensionality. J. Am. Chem. Soc. 124, 13642 2002CrossRefGoogle ScholarPubMed
17JCPDS No. 36-1451 International Center for Diffraction Data Newton Square, PA 1987Google Scholar
18Wood, D.L.Tauc, J.: Weak absorption tails in amorphous semiconductors. Phys. Rev. B 5, 3144 1972CrossRefGoogle Scholar
19Niederberger, M., Garnweitner, G., Krumeich, F., Nesper, R., Cölfen, H.Antonietti, M.: Tailoring the surface and solubility properties of nanocrystalline titania by a nonaqueous in situ functionalization process. Chem. Mater. 16, 1202 2004CrossRefGoogle Scholar
20Ba, J-H.: Nonaqueous synthesis of metal oxide nanaoparticles and their assembly into mesoporous materials.Dissertation in Mathematisch-Naturwissenschaftlichen Fakultät der Universität Potsdam, Aus dem Max-Planck-Institute für Kolloid-und Grenzflächenforchung Abteilung Kolloidchemie,2006Google Scholar
21Yang, R.D., Tripathy, S., Li, Y-T.Sue, H-J.: Photoluminescence and micro- Raman scattering in ZnO nanoparticles: The influence of acetate adsorption. Chem. Phys. Lett. 411, 150 2005CrossRefGoogle Scholar
22Andelman, T., Gong, Y-Y., Polking, M., Yin, M., Kuskovsky, I.L., Neumark, G.O’Brien, S.: Morphological control and photoluminescence of zinc oxide nanocrystals. J. Phys. Chem. B 109, 14314 2005CrossRefGoogle ScholarPubMed