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Interface modification for increased fracture toughness in reaction-formed yttrium aluminum garnet/alumina eutectic composites

Published online by Cambridge University Press:  31 January 2011

Luke N. Brewer
Affiliation:
Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208
Derrick P. Endler
Affiliation:
Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208
Shani Austin
Affiliation:
Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208
Vinayak P. Dravid
Affiliation:
Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208
Joseph M. Collins
Affiliation:
Saphikon Inc., Milford, New Hampshire 03055
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Abstract

The validity of controlling interfacial toughness in reaction-formed composites was explored using solid-state reaction processing and microanalysis techniques. A variety of rare-earth oxides was added to a yttrium aluminum garnet (YAG)/alumina powder mixture and then melted in air. Some melts retained the crystallography and microstructure of the pure, binary YAG–alumina eutectic. Using scanning transmission electron microscopy in conjunction with energy dispersive X-ray spectroscopy, rare-earth ions were observed both to segregate to the YAG/alumina interface and to form a third phase. Some evidence of increased crack deflection at these interfaces was observed via indentation fracture.

Type
Articles
Copyright
Copyright © Materials Research Society 1999

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References

REFERENCES

1.Marshall, D.B., Davis, J.B., Porter, J.R., and Morgan, P.E.D, Key Eng. Mater. 127–131, 27 (1997).Google Scholar
2.Morgan, P.E.D and Marshall, D.B., Mater. Sci. Eng. A 162, 15 (1993).CrossRefGoogle Scholar
3.Goettler, R.W., Sambasivan, S., and Dravid, V.P., in Ceramic Engineering and Science Proceedings (Am. Ceram. Soc., Westerville, OH, 1997), Vol. 18, pp. 279286.Google Scholar
4.Davis, J.B., Lofvander, J.P.A, Evans, A.G., Bischoff, E., and Emiliani, M.L., J. Am. Ceram. Soc. 76, 1249 (1993).CrossRefGoogle Scholar
5.Cinibulk, M.K. and Hay, R.S., J. Am. Ceram. Soc. 79, 1233 (1996).CrossRefGoogle Scholar
6.Kim, S.T., Dravid, V.P., and Sambasivan, S., J. Mater. Res. 14, 1325 (1999).Google Scholar
7.Levi, C.G., Yang, J.Y., Dalgleish, B.J., Zok, F.W., and Evans, A.G., J. Am. Ceram. Soc. 81, 2077 (1998).CrossRefGoogle Scholar
8.Sambasivan, S., Topical Report to Morgantown Energy Technology Center for Interfacial Coatings for Ceramic-Matrix Composites (B.I.R.L., Evanston, IL, 1997).Google Scholar
9.Sayir, A. and Matson, L.E., NASA Conference Publication 10082 (1991), pp. 83–1–13.Google Scholar
10.Sayir, A., Dickerson, R.M., Yun, H.M., Heidger, S., and Matson, L.E., NASA Conference Publication 10146 (1994).Google Scholar
11.Parthasarathy, T.A., Mah, T., and Matson, L.E., J. Am. Ceram. Soc. 76, 29 (1993).Google Scholar
12.Caslavsky, J.L. and Veichnicki, D.J., J. Mater. Sci. 15, 1709 (1980).Google Scholar
13.Mah, T., Parthasarathy, T.A., and Matson, L.E., Ceram. Eng. Sci. Proc. 11, 1617 (1990).CrossRefGoogle Scholar
14.Sambasivan, S., Parthasarathy, T.A., Scheltens, F.J., and Kerans, R.J., in Ceramic Engineering and Science Proceedings (Am. Ceram. Soc., Westerville, OH, 1993), pp. 873877.Google Scholar
15.Bakradze, R.V., Kovba, L.M., Kuznetsova, G.P., and Trunov, V.K., Dokl. Chem. 179, 279 (1968).Google Scholar
16.Udalov, Y.P., Appen, Z.S., and Parshina, V.V., Russ. J. Inorg. Chem. (Engl. Trans.) 24, 1549 (1979).Google Scholar
17.Hay, R.S. and Matson, L.E., Acta Metall. Mater. 39, 1981 (1991).Google Scholar
18.Thompson, A.M., Soni, K.K., Chan, H.M., J. Am. Ceram. Soc. 80, 373 (1997).CrossRefGoogle Scholar
19.Voronko, Y.K. and Sobol, A.A., Physica Status Solidi A27, 257 (1975).Google Scholar
20.Brown, K.R. and Bonnell, D.A., Surf. Sci. 414, 341 (1998).CrossRefGoogle Scholar