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In situ graphitized hard carbon xerogel: A promising high-performance anode material for Li-ion batteries

Published online by Cambridge University Press:  13 November 2020

Mayur M. Gaikwad Open the ORCID record for Mayur M. Gaikwad [Opens in a new window]  and
Chandra S. Sharma
Mayur M. Gaikwad*
Affiliation:
Creative & Advanced Research Based on Nanomaterials (CARBON) Laboratory, Department of Chemical Engineering, Indian Institute of Technology Hyderabad, Kandi, Sangareddy502285, Telangana, India
Chandra S. Sharma
Affiliation:
Creative & Advanced Research Based on Nanomaterials (CARBON) Laboratory, Department of Chemical Engineering, Indian Institute of Technology Hyderabad, Kandi, Sangareddy502285, Telangana, India
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

To address the challenges of capacity fading and poor electronic conductivity of hard carbons as anode in Li-ion batteries (LIBs), we report here the catalytic graphitization of resorcinol–formaldehyde xerogel (RFX)-derived hard carbon via a single-step synthesis by incorporating two transition metal catalysts (Co and Ni) with different loadings (5 and 10%) at a modest temperature of 1100 °C. Loading of both the catalysts affects the extent of graphitization and other physiochemical properties that have a direct influence on the anodic performance of as graphitized RFX-derived hard carbon. A 10% Ni catalyst in RFX-derived carbon induces the highest degree of graphitization of 81.4% along with partial amorphous carbon and nickel phases. This improved crystallinity was conducive enough to facilitate rapid electron and Li-ion transfer while the amorphous carbon phase contributed to higher specific capacity, resulting in overall best anodic performance as ever reported for RFX-derived carbon. A specific capacity of 578 mAh/g obtained after 210 cycles at 0.2 C with coulombic efficiency greater than 99% confirms the potential of graphitized RFX-derived carbon as an anode for high-performance LIBs.

Keywords

catalytic graphitizationresorcinol–formaldehyde carbon xerogelNi- and Co-graphitizing catalystanode materialLi-ion battery
Type
Article
Information
Journal of Materials Research , Volume 35 , Issue 21 , 16 November 2020 , pp. 2989 - 3003
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Copyright
Copyright © The Author(s), 2020, published on behalf of Materials Research Society by Cambridge University Press

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References

Nazir, M.S., Mahdi, A.J., Bilal, M., Sohail, H.M., Ali, N., and Iqbal, H.M.N.: Environmental impact and pollution-related challenges of renewable wind energy paradigm – a review. Sci. Total Environ. 683, 436–444 (2019).CrossRefGoogle ScholarPubMed
Sinsel, S.R., Riemke, R.L., and Hoffmann, V.H.: Challenges and solution technologies for the integration of variable renewable energy sources – a review. Renew. Energy RENE, 11879 (2019).Google Scholar
Amirante, R., Cassone, E., Distaso, E., and Tamburrano, P.: Overview on recent developments in energy storage: Mechanical, electrochemical and hydrogen technologies. Energy Convers. Manag. 132, 372–387 (2017).CrossRefGoogle Scholar
Goodenough, J.B.: Energy storage materials: A perspective. Energy Storage Mater. 1, 158–161 (2015).CrossRefGoogle Scholar
Wang, Y., Zhang, F., Guo, W., Rao, S., Mao, P., and Xiao, P.: Highly reversible lithium storage of nitrogen-doped Carbon@MnO hierarchical hollow spheres as advanced anode materials. ChemElectroChem (2019). doi:10.1002/celc.201901041.Google Scholar
Zhao, M., Xiong, J., Yang, Y., and Zhao, J.: Template-assisted synthesis of honeycomb-like CoFe2O4/CNTs/rGO composite as remarkable anode material for Li/Na ion batteries. ChemElectroChem (2019). doi:10.1002/celc.201900800.Google Scholar
Placke, T., Kloepsch, R., Dühnen, S., and Winter, M.: Lithium ion, lithium metal, and alternative rechargeable battery technologies: The odyssey for high energy density. J. Solid State Electrochem. 21, 1939–1964 (2017).CrossRefGoogle Scholar
Reddy, M.V., Subba Rao, G.V., and Chowdari, B.V.R.: Metal oxides and oxysalts as anode materials for Li ion batteries. Chem. Rev. 113, 5364–5457 (2013).CrossRefGoogle ScholarPubMed
Damodar, D., Kumar, S.K., Martha, S.K., and Deshpande, A.S.: Nitrogen-doped graphene-like carbon nanosheets from commercial glue: Morphology, phase evolution and Li-ion battery performance. Dalton Trans. 47, 12218–12227 (2018).CrossRefGoogle ScholarPubMed
Wu, Y.P., Rahm, E., and Holze, R.: Carbon anode materials for lithium ion batteries. J. Power Sources 114, 228–236 (2003).CrossRefGoogle Scholar
Yoshio, M., Wang, H., Fukud, K., Hara, Y., and Adachi, Y.: Effect of carbon coating on electrochemical performance of treated natural graphite as lithium-ion battery anode material. J. Electrochem. Soc. 147, 1245–1250 (2000).CrossRefGoogle Scholar
Roselin, L.S., Juang, R., Hsieh, C., Sagadevan, S., Umar, A., Selvin, R., and Hegazy, H.H.: Recent advances and perspectives of carbon-based nanostructures as anode materials for Li-ion batteries. Materials 12, 1229 (2019).CrossRefGoogle ScholarPubMed
Qi, W., Shapter, J.G., Wu, Q., Yin, T., Gao, G., and Cui, D.: Nanostructured anode materials for lithium-ion batteries: Principle, recent progress and future perspectives. J. Mater. Chem. A 5, 19521–19540 (2017).CrossRefGoogle Scholar
Lee, S., Kang, D., and Roh, J.: Bulk graphite: Materials and manufacturing process. Carbon Lett. 16, 135–146 (2015).CrossRefGoogle Scholar
Ridgway, P., Zheng, H., Bello, A.F., Song, X., Xun, S., and Chong, J.: Comparison of cycling performance of lithium ion cell anode graphites. J. Electrochem. Soc. 159, A520–A524 (2012).CrossRefGoogle Scholar
Cameán, I., Lavela, P., Tirado, J.L., and García, A.B.: On the electrochemical performance of anthracite-based graphite materials as anodes in lithium-ion batteries. Fuel 89, 986–991 (2010).CrossRefGoogle Scholar
Winter, B.M., Besenhard, J.O., Spahr, M.E., and Novak, P.: Insertion electrode materials for rechargeable lithium batteries. Adv. Mater. 10, 725–763 (1998).3.0.CO;2-Z>CrossRefGoogle Scholar
Buiel, E. and Dahn, J.R.: Li-insertion in hard carbon anode materials for Li-ion batteries. Electrochim. Acta 45, 121.130 (1999).CrossRefGoogle Scholar
Piotrowska, A., Kierzek, K., Rutkowski, P., and Machnikowski, J.: Properties and lithium insertion behavior of hard carbons produced by pyrolysis of various polymers at 1000 ◦C. J. Anal. Appl. Pyrolysis 102, 1–6 (2013).CrossRefGoogle Scholar
Nishi, Y.: The development of lithium ion secondary batteries. Chem. Rec. 1, 406–413 (2001).CrossRefGoogle ScholarPubMed
Wang, X., Liu, L., and Niu, Z.: Carbon-based materials for lithium-ion capacitors. Mater. Chem. Front. 3, 1265–1279 (2019).CrossRefGoogle Scholar
Oya, A. and Marsh, H.: Review phenomena of catalytic graphitization. J. Mater. Sci. 17, 309–322 (1982).CrossRefGoogle Scholar
Oya, A. and Otani, S.: Catalytic graphitization of carbon by various metals. Carbon 17, 131–137 (1979).CrossRefGoogle Scholar
Sevilla, M. and Fuertes, A.B.: Fabrication of porous carbon monoliths with a graphitic frameworks. Carbon 56, 155–166 (2013).CrossRefGoogle Scholar
Wickramaratne, N.P., Perera, V.S., Park, B.W., Gao, M., McGimpsey, G.W., and Huang, S.D.: Graphitic mesoporous carbons with embedded Prussian blue-derived iron oxide nanoparticles synthesized by soft templating and low-temperature graphitization. Chem. Mater. 25, 2803–2811 (2013).CrossRefGoogle Scholar
Liu, Y., Liu, Q., Gu, J., Kang, D., Zhou, F., Zhang, W., Wu, Y., and Zhang, D.: Highly porous graphitic materials prepared by catalytic graphitization. Carbon 64, 132–140 (2013).CrossRefGoogle Scholar
Liu, T., Liu, E., Ding, R., Luo, Z., Hu, T., and Li, Z.: Preparation and supercapacitive performance of clew-like porous nanocarbons derived from sucrose by catalytic graphitization. Electrochim. Acta 173, 50–58 (2015).CrossRefGoogle Scholar
Obrovac, M.N., Zhao, X., Burke, L.T., and Dunlap, R.A.: Reversible lithium insertion in catalytically graphitized sugar carbon. Electrochem. Commun. 60, 221–224 (2015).CrossRefGoogle Scholar
Kicinski, W., Bystrzejewski, M., Rümmeli, M.H., and Gemming, T.: Porous graphitic materials obtained from carbonization of organic xerogels doped with transition metal salts. Bull. Mater. Sci. 37, 141–150 (2014).CrossRefGoogle Scholar
Thompson, E., Danks, A., Bourgeois, L., and Schnepp, Z.: Iron-catalyzed graphitization of biomass. Green Chem. 17, 551 (2015).CrossRefGoogle Scholar
Maksimova, N., Krivoruchko, O., Mestl, G., Zaikovskii, V., Chuvilin, A., Salanov, A., and Burgina, E.: Catalytic synthesis of carbon nanostructures from polymer. J. Mol. Catal. A Chem. 158, 301–307 (2000).CrossRefGoogle Scholar
Hoekstra, J., Beale, A.M., Soulimani, F., Versluijs-Helder, M., Geus, J.W., and Jenneskens, L.W.: Base metal catalyzed graphitization of cellulose: A combined Raman spectroscopy, temperature-dependent X-ray diffraction and high-resolution transmission electron microscopy study. J. Phys. Chem. C 119, 10653–10661 (2015).CrossRefGoogle Scholar
Thambiliyagodage, C.J., Ulrich, S., Araujo, P.T., and Bakker, M.G.: Catalytic graphitization in nanocast carbon monoliths by iron, cobalt and nickel. Carbon 134, 452–463 (2018).CrossRefGoogle Scholar
Maldonado-Hódar, F.J., Moreno-Castilla, C., Rivera-Utrilla, J., Hanzawa, Y., and Yamada, Y.: Catalytic graphitization of carbon aerogels by transition. Langmuir 16, 4367–4373 (2000).CrossRefGoogle Scholar
Hasegawa, G., Kanamori, K., and Nakanishi, K.: Facile preparation of macroporous graphitized carbon monoliths from iron-containing resorcinol–formaldehyde gels. Mater. Lett. 76, 1–4 (2012).CrossRefGoogle Scholar
Kiciński, W., Norek, M., and Bystrzejewski, M.: Monolithic porous graphitic carbons obtained through catalytic graphitization of carbon xerogels. J. Phys. Chem. Solids 74, 101–109 (2012).CrossRefGoogle Scholar
Gomez-Martin, A., Martinez-Fernandez, J., Ruttert, M., Heckmann, A., Winter, M., Placke, T., and Ramirez-Rico, J.: Fe-catalyzed graphitic carbon materials from biomass resources as anodes for lithium ion batteries. ChemSusChem 11, 2776–2787 (2018).CrossRefGoogle Scholar
Kakunuri, M., Kali, S., and Sharma, C.S.: Catalytic graphitization of resorcinol-formaldehyde xerogel and its effect on lithium ion intercalation. J. Anal. Appl. Pyrolysis 117, 317–324 (2016).CrossRefGoogle Scholar
Yan, Q., Li, J., Zhang, X., Hassan, E.B., Wang, C., Zhang, J., and Cai, Z.: Catalytic graphitization of kraft lignin to graphene-based structures with four different transitional metals. J. Nanopart. Res. 20, 223 (2018).CrossRefGoogle Scholar
Gaikwad, M.M., Kakunuri, M., and Sharma, C.S.: Enhanced catalytic graphitization of resorcinol formaldehyde derived carbon xerogel to improve its anodic performance for lithium ion battery. Mater. Today Commun 20, 100569 (2019).CrossRefGoogle Scholar
ElKhatat, A.M. and Al-Muhtaseb, S.A.: Advances in tailoring resorcinol-formaldehyde organic and carbon gels. Adv. Mater. 23, 2887–2903 (2011).CrossRefGoogle ScholarPubMed
Awadallah-F, A. and Al-Muhtaseb, S.A.: Novel controlled synthesis of nanoporous carbon nanorods from resorcinol-formaldehyde xerogels. Mater. Lett. 201, 181–184 (2017).CrossRefGoogle Scholar
Sharma, C.S., Kulkarni, M.M., Sharma, A., and Madou, M.: Synthesis of carbon xerogel particles and fractal-like structures. Chem. Eng. Sci. 64, 1536–1543 (2009).CrossRefGoogle Scholar
Kakunuri, M., Vennamalla, S., and Sharma, C.S.: Synthesis of carbon xerogel nanoparticles by inverse emulsion polymerization of resorcinol–formaldehyde and their use as anode materials for lithium-ion battery. RSC Adv. 5, 4747–4753 (2015).CrossRefGoogle Scholar
Rey-Raap, N., Arenillas, A., and Menendez, J.A.: A visual validation of the combined effect of pH and dilution on the porosity of carbon xerogels. Micropor. Mesopor. Mater. 223, 89–93 (2016).CrossRefGoogle Scholar
Alonso-Buenaposada, I.D., Rey-Raap, N., Calvo, E.G., Menéndez, J.A., and Arenillas, A.: Effect of methanol content in commercial formaldehyde solutions on the porosity of RF carbon xerogels. J. Non-Cryst. Solids 426, 13–18 (2015).CrossRefGoogle Scholar
Rey-Raap, N., Calvo, E.G., Menendez, J.A., and Arenillas, A.: Exploring the potential of resorcinol-formaldehyde xerogels as thermal insulators. Micropor. Mesopor. Mater. 244, 50–54 (2017).CrossRefGoogle Scholar
Canal-Rodríguez, M., Arenillas, A., Menendez, J.A., Beneroso, D., and Rey-Raap, N.: Carbon xerogels graphitized by microwave heating as anode materials in lithium-ion batteries. Carbon 137, 384–394 (2018).CrossRefGoogle Scholar
Piedboeuf, M.C., Léonard, A.F., Reichenauer, G., Balzer, C., and Job, N.: How do the micropores of carbon xerogels influence their electrochemical behavior as anodes for lithium-ion batteries. Micropor. Mesopor. Mater. 275, 278–287 (2019).CrossRefGoogle Scholar
Malard, L.M., Pimenta, M.A., Dresselhaus, G., and Dresselhaus, M.S.: Raman spectroscopy in graphene. Phys. Rep. 473, 51–87 (2009).CrossRefGoogle Scholar
Nguyen, V., Le, H., Nguyen, V., Ngo, T., Le, D., Nguyen, X., and Phan, N.: Synthesis of multi-layer graphene films on copper tape by atmospheric pressure chemical vapor deposition method. Adv. Nat. Sci.: Nanosci. Nanotechnol. 4, 035012 (2013).Google Scholar
Cançado, L.G., Takai, K., Enoki, T., Endo, M., Kim, Y.A., Mizusaki, H., Jorio, A., Coelho, L.N., Magalhães-Paniago, R., and Pimenta, M.A.: General equation for the determination of the crystallite size La of nanographite by Raman spectroscopy. App. Phys. Lett. 88, 1–4 (2006).CrossRefGoogle Scholar
Baker, H. and Okamoto, H.: ASM Handbook Alloy phase diagrams. ASM Int. 3, 2–319 (1992).Google Scholar
Dhar, S. and Kestner, N.R.: Ionization potentials of cobalt and nickel ions in the local-spin-density approximation. Phys. Rev. B 41, 803–806 (1990).CrossRefGoogle ScholarPubMed
Fan, Z., Liang, J., Yu, W., Ding, S., Cheng, S., Yang, G., Wang, G., Xi, Y., Xi, K., and Kumar, R.V.: Ultrathin NiO nanosheets anchored on a highly ordered nanostructured carbon as an enhanced anode material for lithium ion batteries. Nano Energy 16, 152–162 (2015).CrossRefGoogle Scholar
Guo, H., Li, X., Zhang, X., Wang, H., Wang, Z., and Peng, W.: Diffusion coefficient of lithium in artificial graphite, mesocarbon microbeads, and disordered carbon. New Carbon Mater. 22, 7–11 (2007).CrossRefGoogle Scholar
Kim, J., Kim, J.Y., Pham-Cong, D., Jeong, S.Y., Chang, J., Choi, J.H., Braun, P.V., and Cho, C.R.: Individually carbon-coated and electrostatic-force-derived graphene-oxide-wrapped lithium titanium oxide nanofibers as anode material for lithium-ion batteries. Electrochim. Acta 199, 35–44 (2016).CrossRefGoogle Scholar