Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-28T05:45:11.408Z Has data issue: false hasContentIssue false

Formation of highly conductive composite coatings and their applications to broadband antennas and mechanical transducers

Published online by Cambridge University Press:  31 January 2011

Kang-Shyang Liao*
Affiliation:
Institute for NanoEnergy, Department of Physics, University of Houston, Houston, Texas 77004
Jamal A. Talla
Affiliation:
Department of Physics, King Faisal University, Al-Ahsa 31982, Kingdom of Saudi Arabia
Soniya D. Yambem
Affiliation:
Institute for NanoEnergy, Department of Physics, University of Houston, Houston, Texas 77004
Donald Birx
Affiliation:
Office for the Vice Chancellor of Research, University of Houston, Houston, Texas 77004
Guo Chen
Affiliation:
Department of Electrical Engineering, University of Houston, Houston, Texas 77004
David L. Carroll
Affiliation:
Department of Physics, Wake Forest University, Winston-Salem, North Carolina 27109
Pulickel M. Ajayan
Affiliation:
Department of Materials Engineering, Rice University, Houston, Texas 77005
Donghui Zhang
Affiliation:
Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803
Seamus A. Curran
Affiliation:
Institute for NanoEnergy, Department of Physics, University of Houston, Houston, Texas 77004
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Tight networks of interwoven carbon nanotube bundles are formed in our highly conductive composite. The composite possesses properties suggesting a two-dimensional percolative network rather than other reported dispersions displaying three-dimensional networks. Binding nanotubes into large but tight bundles dramatically alters the morphology and electronic transport dynamics of the composite. This enables it to carry higher levels of charge in the macroscale leading to conductivities as high as 1600 S/cm. We now discuss in further detail, the electronic and physical properties of the nanotube composites through Raman spectroscopy and transmission electron microscopy analysis. When controlled and used appropriately, the interesting properties of these composites reveal their potential for practical device applications. For instance, we used this composite to fabricate coatings, which improve the properties of an electromagnetic antenna/amplifier transducer. The resulting transducer possesses a broadband range up to GHz frequencies. A strain gauge transducer was also fabricated using changes in conductivity to monitor structural deformations in the composite coatings.

Type
Articles
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Curran, S.A., Ajayan, P.M., Blau, W.J., Carroll, D.L., Coleman, J.N., Dalton, A.B., Davey, A.P., Drury, A., McCarthy, B., Maier, S., Strevens, A.A composite from poly(m-phenylenevinylene-co-2,5-dioctoxy-p-phenylenevinylene) and carbon nanotubes: A novel material for molecular optoelectronics. Adv. Mater. 10, 1091 (1988)3.0.CO;2-L>CrossRefGoogle Scholar
2.Jung, Y.J., Kar, S., Talapatra, S., Soldano, C., Viswanathan, G., Li, X., Yao, Z., Ou, F.S., Avadhanula, A., Vajtai, R., Curran, S., Nalamasu, O., Ajayan, P.M.Aligned carbon nanotube-polymer hybrid architectures for diverse flexible electronic applications. Nano Lett. 6, 413 (2006)CrossRefGoogle ScholarPubMed
3.Qu, L.T., Peng, Q., Dai, L.M., Spinks, G.M., Wallace, G.G., Baughman, R.H.Carbon nanotube electroactive polymer materials: Opportunities and challenges. MRS Bull. 33, 215 (2008)CrossRefGoogle Scholar
4.Lu, W., Lieber, C.M.Nanoelectronics from the bottom up. Nat. Mater. 6, 841 (2007)CrossRefGoogle ScholarPubMed
5.An, K.H., Kim, W.S., Park, Y.S., Moon, J-M., Bae, D.J., Lim, S.C., Lee, Y.S., Lee, Y.H.Electrochemical properties of high-power supercapacitors using single-walled carbon nanotube electrodes. Adv. Funct. Mater. 11, 387 (2001)3.0.CO;2-G>CrossRefGoogle Scholar
6.Chen, J., Liu, Y., Minett, A.I., Lynam, C., Wang, J., Wallace, G.G.Flexible, aligned carbon nanotube/conducting polymer electrodes for a lithium-ion battery. Chem. Mater. 19, 3595 (2007)CrossRefGoogle Scholar
7.Rowell, M.W., Topinka, M.A., McGehee, M.D., Hu, L., Gruner, G.Organic solar cells with carbon nanotube network electrodes. Appl. Phys. Lett. 88, 233506 (2006)CrossRefGoogle Scholar
8.Kang, I., Schulz, M.J., Kim, J.H., Shanov, V., Shi, D.A carbon nanotube strain sensor for structural health monitoring. Smart Mater. Struct. 15, 737 (2006)CrossRefGoogle Scholar
9.Thostenson, E.T., Chou, T-W.Carbon nanotube networks: Sensing of distributed strain and damage for life prediction and self healing. Adv. Mater. 18, 2837 (2006)CrossRefGoogle Scholar
10.Gau, C., Ko, H.S., Chen, H.T.Piezoresistive characteristics of MWNT nanocomposites and fabrication as a polymer pressure sensor. Nanotechnology 20, 185503 (2009)CrossRefGoogle ScholarPubMed
11.Saafi, M.Wireless and embedded carbon nanotube networks for damage detection in concrete structures. Nanotechnology 20, 395502 (2009)CrossRefGoogle ScholarPubMed
12.Yu, X., Kwon, E.A carbon nanotube/cement composite with piezoresistive properties. Smart Mater. Struct. 18, 055010 (2009)CrossRefGoogle Scholar
13.Coleman, J.N., Curran, S., Dalton, A.B., Davey, A.P., McCarthy, B., Blau, W., Barklie, R.C.Percolation-dominated conductivity in a conjugated-polymer-carbon-nanotube composite. Phys. Rev. B 58, 7492 (1998)CrossRefGoogle Scholar
14.Baughman, R.H., Zakhidov, A.A., de Heer, W.A.Carbon nanotubes—The route toward applications. Science 297, 787 (2002)CrossRefGoogle ScholarPubMed
15.Dalton, A.B., Byrne, H.J., Coleman, J.N., Curran, S.A., Davey, A.P., McCarthy, B.Optical absorption and fluorescence of a multi-walled nanotube-polymer composite. Synth. Met. 102, 1176 (1999)CrossRefGoogle Scholar
16.Zhang, M., Fang, S.L., Zakhidov, A.A., Lee, S.B., Aliev, A.E., Williams, C.D., Atkinson, K.R., Baughman, R.H.Strong, transparent, multifunctional, carbon nanotube sheets. Science 309, 1215 (2005)CrossRefGoogle ScholarPubMed
17.Curran, S.A., Talla, J., Dias, S., Zhang, D., Carroll, D.L., Birx, D.Electrical transport measurements of highly conductive carbon nanotube/poly(bisphenol A carbonate) composite. J. Appl. Phys. 105, 073711 (2009)CrossRefGoogle Scholar
18.Chiang, C.K., Fincher, C.R., Park, Y.W., Heeger, A.J., Shirakawa, H., Louis, E.J., Gau, S.C., MacDiarmid, A.G.Electrical conductivity of polyacetylene. Phys. Rev. Lett. 39, 1098 (1977)CrossRefGoogle Scholar
19.Lyons, P.E., De, S., Blighe, F., Nicolosi, V., Pereira, L.F.C., Ferreira, M.S., Coleman, J.N.The relationship between network morphology and conductivity in nanotube films. J. Appl. Phys. 104, 044302 (2008)CrossRefGoogle Scholar
20.Naebe, M., Lin, T., Staiger, M.P., Dai, L., Wang, X.G.Electrospun single-walled carbon nanotube/polyvinyl alcohol composite nanofibers: Structure–property relationships. Nanotechnology 19, 305702 (2008)CrossRefGoogle ScholarPubMed
21.Munoz, M., Suh, D.S., Collins, S., Selvidge, M., Dalton, A.B., Kim, B.G., Razel, J.M., Ussery, G., Rinzler, A.G., Martinez, M.T., Baughman, R.H.Highly conducting carbon nanotube/polyethyleneimine composite fibers. Adv. Mater. 17, 1064 (2005)CrossRefGoogle Scholar
22.Palaniappan, S., John, A.Polyaniline materials by emulsion polymerization pathway. Prog. Polym. Sci. 33, 732 (2008)CrossRefGoogle Scholar
23.Rahy, A., Yang, D.J.Synthesis of highly conductive polyaniline nanofibers. Mater. Lett. 62, 4311 (2008)CrossRefGoogle Scholar
24.Curran, S.A., Zhang, D., Wondmagegn, W.T., Ellis, A.V., Cech, J., Roth, S., Carroll, D.L.Dynamic electrical properties of polymer-carbon nanotube composites: Enhancement through covalent bonding. J. Mater. Res. 21, 1071 (2006)CrossRefGoogle Scholar
25.Dresselhaus, M.S., Dresselhaus, G., Saito, R., Jorio, A.Raman spectroscopy of carbon nanotubes. Phys. Rep. 409, 47 (2005)CrossRefGoogle Scholar
26.Rocquefelte, X., Rignanese, G-M., Meunier, V., Terrones, H., Terrones, M., Charlier, J-C.How to identify Haeckelite structures: A theoretical study of their electronic and vibrational properties. Nano Lett. 4, 805 (2004)CrossRefGoogle Scholar
27.Curran, S.A., Talla, J.A., Zhang, D., Carroll, D.L.Defect-induced vibrational response of multi-walled carbon nanotubes using resonance Raman spectroscopy. J. Mater. Res. 20, 3368 (2005)CrossRefGoogle Scholar
28.Chakrapani, N., Curran, S.A., Wei, B., Ajayan, P.M., Carrillo, A., Kane, R.S.Spectral fingerprinting of structural defects in plasma-treated carbon nanotubes. J. Mater. Res. 18, 2515 (2003)CrossRefGoogle Scholar
29.Singh, C., Shaffer, M.S., Windle, A.H.Production of controlled architectures of aligned carbon nanotubes by an injection chemical vapour deposition method. Carbon 41, 359 (2003)CrossRefGoogle Scholar
30.Ebbesen, T.W.Carbon nanotubes. Annu. Rev. Mater. Sci. 24, 235 (1994)CrossRefGoogle Scholar
31.Schmidt, R.H., Kinloch, I.A., Burgess, A.N., Windle, A.H.The effect of aggregation on the electrical conductivity of spin-coated polymer/carbon nanotube composite films. Langmuir 23, 5707 (2007)CrossRefGoogle ScholarPubMed
32.Lee, C.Y., Strano, M.S.Amine basicity (pK b) controls the analyte binding energy on single walled carbon nanotube electronic sensor arrays. J. Am. Chem. Soc. 130, 1766 (2008)CrossRefGoogle ScholarPubMed
33.Stutzman, W.L., Thiele, G.A.Antenna Theory and Design 2nd ed (John Wiley & Sons, Inc., New York 1998)Google Scholar
34.Asmontas, S., Anisimovas, F., Dapkus, L., Gradauskas, J., Kiprijanovic, O., Prosycevas, I., Puiso, J., Slapikas, K., Vengalis, B.Radiation of ultra-wideband electromagnetic pulses by pulsed excitation of rectangular antenna. Lith. J. Phys. 49, 29 (2009)CrossRefGoogle Scholar
35.Tombler, T.W., Zhou, C., Alexseyev, L., Kong, J., Dai, H., Liu, L., Jayanthi, C.S., Tang, M., Wu, S-Y.Reversible electromechanical characteristics of carbon nanotubes under local-probe manipulation. Nature 405, 769 (2000)CrossRefGoogle ScholarPubMed
36.Nardelli, M.B., Berholc, J.Mechanical deformations and coherent transport in carbon nanotubes. Phys. Rev. B 60, R16338 (1999)CrossRefGoogle Scholar