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Formation and compression mechanical properties of Ni–Zr–Nb–Pd bulk metallic glasses

Published online by Cambridge University Press:  31 January 2011

J.B. Qiang ,
W. Zhang  and
A. Inoue
J.B. Qiang
Affiliation:
Institute for Materials Research (IMR), Tohoku University, Aoba-ku, Sendai 980-8577, Japan
W. Zhang*
Affiliation:
Institute for Materials Research (IMR), Tohoku University, Aoba-ku, Sendai 980-8577, Japan
A. Inoue
Affiliation:
Institute for Materials Research (IMR), Tohoku University, Aoba-ku, Sendai 980-8577, Japan
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

The formation of bulk metallic glasses (BMGs) and their room temperature mechanical properties have been investigated in a serial of Ni65−xZr20Nb15Pdx (x = 0∼15; at.%) quaternary alloys, which are hopefully hydrogen-permeation materials. The partial substitution of Ni with Pd in Ni65Zr20Nb15 alloy has proved to be effective in improving glass-forming ability (GFA) and thermal stability. In particular, good BMG-forming compositions were revealed within the Pd content range of 2.5–12.5 at.%, and BMG rods of 3 mm in diameter were successfully made at compositions Ni57.5Zr20Nb15Pd7.5 and Ni55Zr20Nb15Pd10 by copper mold casting. The addition of Pd enhanced the thermal stability of the supercooled liquid. With an increase of Pd content, the supercooled liquid span, ΔTx = Tx − Tg, increased from 29 K at Ni65Zr20Nb15 to 47 K at Ni52.5Zr20Nb15Pd12.5. The Pd-bearing BMGs exhibited high fracture strength, which ranged from 2750 to 2850 MPa. These Pd-bearing BMGs showed a certain degree of toughness, and the highest plastic strain, about 2%, was reached in the Ni60Zr20Nb15Pd5 BMG.

Keywords

AmorphousNiPd
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 7 , July 2008 , pp. 1940 - 1945
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1Inoue, A., Zhang, T.Masumoto, T.: Al–La–Ni amorphous alloys with a wide supercooled liquid region. Mater. Trans., JIM 30, 965 1989CrossRefGoogle Scholar
2Peker, A.Johnson, W.L.: A highly processable metallic glass: Zr41.2Ti13.8Cu12.5Ni10.0Be22.5. Appl. Phys. Lett. 63, 2342 1993CrossRefGoogle Scholar
3Inoue, A.: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 2000CrossRefGoogle Scholar
4Wang, W.H., Dong, C.Shek, C.H.: Bulk metallic glasses. Mater. Sci. Eng., R 44, 45 2004CrossRefGoogle Scholar
5Dolan, M.D., Dave, N.C., Ilyushechkin, A.Y., Morpeth, L.D.McLennan, K.G.: Composition and operation of hydrogen-selective amorphous alloy membranes. J. Membr. Sci. 285, 30 2006CrossRefGoogle Scholar
6Hara, S., Sakaki, K., Itoh, N., Kimura, H-M., Asami, K.Inoue, A.: An amorphous alloy membrane without noble metals for gaseous hydrogen separation. J. Membr. Sci. 164, 289 2000CrossRefGoogle Scholar
7Yamaura, S., Nakata, S., Kimura, H., Shimpo, Y., Nishida, M.Inoue, A.: Hydrogen permeation of the melt-spun Ni–X–Zr amorphous membranes. Mater. Trans. 46, 1768 2005CrossRefGoogle Scholar
8Yamaura, S., Sakurai, M., Hasegawa, M., Wakoh, K., Shimpo, Y., Nishida, M., Kimura, H., Matsubara, E.Inoue, A.: Hydrogen permeation and structural features of melt-spun Ni–Nb–Zr amorphous alloys. Acta Mater. 53, 3703 2005CrossRefGoogle Scholar
9Yamaura, S., Shimpo, Y., Okouchi, H., Nishida, M., Kajita, O.Inoue, A.: The effect of additional elements on hydrogen permeation properties of melt-spun Ni–Nb–Zr amorphous alloys. Mater. Trans. 45, 330 2004CrossRefGoogle Scholar
10Qiang, J.B., Zhang, W.Inoue, A.: Formation and thermal stability of Ni-based bulk metallic glasses in Ni–Zr–Nb–Al system. Mater. Trans. 48, 2385 2007CrossRefGoogle Scholar
11Wang, X.M., Yoshii, I., Inoue, A., Kim, Y.H.Kim, I.B.: Bulk amorphous Ni75−xNb5MxP20−yBy (M = Cr, Mo) alloys with large supercooling and high strength. Mater. Trans., JIM 40, 1130 1999CrossRefGoogle Scholar
12Yi, S., Park, T.G.Kim, D.H.: Ni-based bulk amorphous alloys in the Ni–Ti–Zr–(Si,Sn) system. J. Mater. Res. 15, 2425 2000CrossRefGoogle Scholar
13Zhang, W.Inoue, A.: Formation and mechanical properties of Ni-based Ni–Nb–Ti–Hf bulk glassy alloys. Scr. Mater. 48, 641 2003CrossRefGoogle Scholar
14Choi-Yim, H., Xu, D.H.Johnson, W.L.: Ni-based bulk metallic glass formation in the Ni–Nb–Sn and Ni–Nb–Sn–X (X = B, Fe, Cu) alloy systems. Appl. Phys. Lett. 82, 1030 2003CrossRefGoogle Scholar
15Wang, A.P.Wang, J.Q.: A topological approach to design Ni-based bulk metallic glasses with high corrosion resistance. J. Mater. Res. 22, 1 2007CrossRefGoogle Scholar
16Xu, D., Duan, G., Johnson, W.L.Garland, C.: Formation and properties of new Ni-based amorphous alloys with critical casting thickness up to 5 mm. Acta Mater. 52, 3493 2004CrossRefGoogle Scholar
17Kimura, H.M., Inoue, A., Yamaura, S., Sasamori, K., Nishida, M., Shimpo, Y.Okouchi, H.: Thermal stability and mechanical properties of glassy and amorphous Ni–Nb–Zr alloys produced by rapid solidification. Mater. Trans. 44, 1167 2003CrossRefGoogle Scholar
18Lu, Z.P., Tan, H., Li, Y.Ng, S.C.: The correlation between reduced glass transition temperature and glass forming ability of bulk metallic glasses. Scr. Mater. 42, 667 2000CrossRefGoogle Scholar
19Lu, Z.P.Liu, C.T.: A new glass-forming ability criterion for bulk metallic glasses. Acta Mater. 50, 3501 2002CrossRefGoogle Scholar
20De Boer, F.R., Boom, R., Mattens, W.C.M., Miedema, A.R.Niessen, A.K.: Cohesion in Metals Elsevier Amsterdam 1989 224Google Scholar
21Japan Institute of Metals Metals Databook edited by Japan Institute Metals JIM Maruzen, Tokyo 1983 8Google Scholar
22Argon, A.S.: Plastic deformation in metallic glasses. Acta Metall. 27, 47 1979CrossRefGoogle Scholar
23Schuh, C.A., Hufnage, T.C.Ramamurty, U.: Mechanical behavior of amorphous alloys. Acta Mater. 55, 4067 2007CrossRefGoogle Scholar