Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-30T23:20:38.388Z Has data issue: false hasContentIssue false
  • English
  • Français

The electrochemical performance of SnSb/C nanofibers with different morphologies and underlying mechanism

Published online by Cambridge University Press:  05 January 2017

Xin Xia ,
Zhiyong Li ,
Leigang Xue ,
Yiping Qiu ,
Chuyang Zhang  and
Xiangwu Zhang
Xin Xia
Affiliation:
College of Textile and Clothing, Xinjiang University, Urumchi 830046, Xinjiang, China; and Fiber and Polymer Science Program, Department of Textile Engineering, Chemistry and Science, North Carolina State University, Raleigh, NC 27695-8301
Zhiyong Li
Affiliation:
College of Textile and Clothing, Xinjiang University, Urumchi 830046, Xinjiang, China
Leigang Xue
Affiliation:
Fiber and Polymer Science Program, Department of Textile Engineering, Chemistry and Science, North Carolina State University, Raleigh, NC 27695-8301
Yiping Qiu
Affiliation:
College of Textile and Clothing, Xinjiang University, Urumchi 830046, Xinjiang, China
Chuyang Zhang*
Affiliation:
College of Textile and Clothing, Xinjiang University, Urumchi 830046, Xinjiang, China
Xiangwu Zhang*
Affiliation:
Fiber and Polymer Science Program, Department of Textile Engineering, Chemistry and Science, North Carolina State University, Raleigh, NC 27695-8301
*
a) Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

SnSb nanoparticles are dispersed in carbon nanofibers by electrospinning technology and different SnSb precursors, including Sn0.92Sb0.08O2.04 nanoparticles, Sn(CH3COO)2/Sb(CH3COO)3, and SnCl4·5H2O/SbCl3, are used to tune the morphology of the resultant SnSb/C nanofibers. Porous SnSb/C nanofibers are formed during carbonization Sn0.92Sb0.08O2.04 nanoparticles and Sn(CH3COO)2/Sb(CH3COO)3 are used as precursors of SnSb, while solid nanofibers are observed with SnCl4·5H2O/SbCl3 as the precursor indicating the formation mechanism is closely related to the properties of SnSb precursors. Excellent cycling preference (99% capacity retention after 200 cycles) and high coulombic efficiency (above 99% after 10 cycles) are obtained for the SnSb/C nanofibers using Sn0.92Sb0.08O2.04 as precursor, due to its high surface area and stable SnSb/C structure. It is demonstrated that the uniquely designed composite nanofiber structure with excellent lithium storage performance can be realized simply by selecting precursors with appropriate dissolution and decomposition properties.

Keywords

SnSb/C nanofibersprecursorsmorphology controlmechanismcycling stability
Type
Articles
Information
Journal of Materials Research , Volume 32 , Issue 6 , 28 March 2017 , pp. 1184 - 1193
Check for updates
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Contributing Editor: Xiaobo Chen

References

REFERENCES

Li, H., Wang, Z., Chen, L., and Huang, X.: Research on advanced materials for Li-ion batteries. Adv. Mater. 21(45), 4593 (2009).CrossRefGoogle Scholar
Li, X., He, X., Xu, Y., Huang, L., Li, J., Sun, S., and Zhao, J.: Superiority of the bi-phasic mixture of a tin-based alloy nanocomposite as the anode for lithium ion batteries. J. Mater. Chem. A 3(7), 3794 (2015).CrossRefGoogle Scholar
Zhang, M., Wang, T., and Cao, G.: Promises and challenges of tin-based compounds as anode materials for lithium-ion batteries. Int. Mater. Rev. 60(6), 330 (2015).CrossRefGoogle Scholar
Nithyadharseni, P., Reddy, M.V., Nalini, B., Kalpana, M., and Chowdari, B.V.R.: Sn-based intermetallic alloy anode materials for the application of lithium ion batteries. Electrochim. Acta 161, 261 (2015).CrossRefGoogle Scholar
Yu, Y., Chen, C.H., and Shi, Y.: A tin-based amorphous oxide composite with a porous, spherical, multideck-cage morphology as a highly reversible anode material for lithium-ion batteries. Adv. Mater. 19(7), 993 (2007).Google Scholar
Fu, K., Yildiz, O., Bhanushali, H., Wang, Y., Stano, K., Xue, L., Zhang, X., and Bradford, P.D.: Aligned carbon nanotube-silicon sheets: A novel nano-architecture for flexible lithium ion battery electrodes. Adv. Mater. 25(36), 5109 (2013).CrossRefGoogle Scholar
Roberts, A.D., Li, X., and Zhang, H.: Porous carbon spheres and monoliths: morphology control, pore size tuning and their applications as Li-ion battery anode materials. Chem. Soc. Rev. 43(13), 4341 (2014).CrossRefGoogle ScholarPubMed
Liang, J., Li, X., Hou, Z., Zhang, T., Zhu, Y., Yan, X., and Qian, Y.: Honeycomb-like macro-germanium as high-capacity anodes for lithium-ion batteries with good cycling and rate performance. Chem. Mater. 27(11), 4156 (2015).CrossRefGoogle Scholar
Zhu, C., Xia, X., Liu, J., Fan, Z., Chao, D., Zhang, H., and Fan, H.J.: TiO2 nanotube @ SnO2 nanoflake core–branch arrays for lithium-ion battery anode. Nano Energy 4, 105 (2014).CrossRefGoogle Scholar
Kong, J., Wong, S.Y., Zhang, Y., Tan, H.R., Li, X., and Lu, X.: One-dimensional carbon-SnO2 and SnO2 nanostructures via single-spinneret electrospinning: Tunable morphology and the underlying mechanism. J. Mater. Chem. 21(40), 15928 (2011).CrossRefGoogle Scholar
Zhang, X., Liang, J., Gao, G., Ding, S., Yang, Z., Yu, W., and Li, B.Q.: The preparation of mesoporous SnO2 nanotubes by carbon nanofibers template and their lithium storage properties. Electrochim. Acta 98, 263 (2013).CrossRefGoogle Scholar
Jeong, G., Kim, J-G., Park, M-S., Seo, M., Hwang, S.M., Kim, Y-U., Kim, Y-J., Kim, J.H., and Dou, S.X.: Core–shell structured silicon nanoparticles@TiO2–x /carbon mesoporous microfiber composite as a safe and high-performance lithium-ion battery anode. ACS Nano 8(3), 2977 (2014).CrossRefGoogle ScholarPubMed
Wu, J., Qin, X., Miao, C., He, Y-B., Liang, G., Zhou, D., Liu, M., Han, C., Li, B., and Kang, F.: A honeycomb-cobweb inspired hierarchical core–shell structure design for electrospun silicon/carbon fibers as lithium-ion battery anodes. Carbon 98, 582 (2016).CrossRefGoogle Scholar
Zhang, J., Wang, Z., Hong, Y., Li, S., Jin, X., and Chen, G.Z.: Electrochemical fabrication of porous Sn/SnSb negative electrodes from mixed SnO2–Sb2O3 . Electrochem. Commun. 38, 36 (2014).CrossRefGoogle Scholar
Park, C-M. and Jeon, K-J.: Porous structured SnSb/C nanocomposites for Li-ion battery anodes. Chem. Commun. 47(7), 2122 (2011).CrossRefGoogle ScholarPubMed
Kennedy, T., Mullane, E., Geaney, H., Osiak, M., O’Dwyer, C., and Ryan, K.M.: High-performance germanium nanowire-based lithium-ion battery anodes extending over 1000 cycles through in situ formation of a continuous porous network. Nano Lett. 14(2), 716 (2014).CrossRefGoogle ScholarPubMed
Fritsch, J., Rose, M., Wollmann, P., Böhlmann, W., and Kaskel, S.: New element organic frameworks based on Sn, Sb, and Bi, with permanent porosity and high catalytic activity. Materials 3(4), 2447 (2010).CrossRefGoogle Scholar
Saikia, D., Wang, T-H., Chou, C-J., Fang, J., Tsai, L-D., and Kao, H-M.: A comparative study of ordered mesoporous carbons with different pore structures as anode materials for lithium-ion batteries. RSC Adv. 5(53), 42922 (2015).CrossRefGoogle Scholar
Li, Y., Guo, B., Ji, L., Lin, Z., Xu, G., Liang, Y., Zhang, S., Toprakci, O., Hu, Y., Alcoutlabi, M., and Zhang, X.: Structure control and performance improvement of carbon nanofibers containing a dispersion of silicon nanoparticles for energy storage. Carbon 51, 185 (2013).CrossRefGoogle Scholar
Aravindan, V., Sundaramurthy, J., Suresh Kumar, P., Lee, Y-S., Ramakrishna, S., and Madhavi, S.: Electrospun nanofibers: A prospective electro-active material for constructing high performance Li-ion batteries. Chem. Commun. 51(12), 2225 (2015).CrossRefGoogle ScholarPubMed
Huang, Z-M., Zhang, Y.Z., Kotaki, M., and Ramakrishna, S.: A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos. Sci. Technol. 63(15), 2223 (2003).CrossRefGoogle Scholar
Liu, J., He, L., Ma, S., Liang, J., Zhao, Y., and Fong, H.: Effects of chemical composition and post-spinning stretching process on the morphological, structural, and thermo-chemical properties of electrospun polyacrylonitrile copolymer precursor nanofibers. Polymer 61, 20 (2015).CrossRefGoogle Scholar
Ji, L., Lin, Z., Alcoutlabi, M., and Zhang, X.: Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries. Energy Environ. Sci. 4(8), 2682 (2011).CrossRefGoogle Scholar
Raza, A., Yu, J., Zhai, Y., Sun, G., and Ding, B.: Applications of electrospinning in design and fabrication of electrodes for lithium-ion batteries. In Electrospun Nanofibers for Energy and Environmental Applications, Ding, B. and Yu, J. eds. (Springer Berlin, Heidelberg, 2014); p. 69.CrossRefGoogle Scholar
Niu, X., Zhou, H., Li, Z., Shan, X., and Xia, X.: Carbon-coated SnSb nanoparticles dispersed in reticular structured nanofibers for lithium-ion battery anodes. J. Alloys Compd. 620, 308 (2015).CrossRefGoogle Scholar
Sing, K.S.W.: Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984). Pure Appl. Chem. 57(4), 603 (1985).CrossRefGoogle Scholar
Ji, L., Gu, M., Shao, Y., Li, X., Engelhard, M.H., Arey, B.W., Wang, W., Nie, Z., Xiao, J., Wang, C., Zhang, J-G., and Liu, J.: Controlling SEI formation on SnSb-porous carbon nanofibers for improved Na ion storage. Adv. Mater. 26(18), 2901 (2014).CrossRefGoogle ScholarPubMed
Hassoun, J., Derrien, G., Panero, S., and Scrosati, B.: A SnSb–C nanocomposite as high performance electrode for lithium ion batteries. Electrochim. Acta 54(19), 4441 (2009).CrossRefGoogle Scholar
Xue, L., Xia, X., Tucker, T., Fu, K., Zhang, S., Li, S., and Zhang, X.: A simple method to encapsulate SnSb nanoparticles into hollow carbon nanofibers with superior lithium-ion storage capability. J. Mater. Chem. A 1(44), 13807 (2013).CrossRefGoogle Scholar
Liu, N., Hu, L., McDowell, M.T., Jackson, A., and Cui, Y.: Prelithiated silicon nanowires as an anode for lithium ion batteries. ACS Nano 5(8), 6487 (2011).CrossRefGoogle ScholarPubMed
Tirado, J.L.: Inorganic materials for the negative electrode of lithium-ion batteries: state-of-the-art and future prospects. Mater. Sci. Eng., R 40(3), 103 (2003).CrossRefGoogle Scholar
Supplementary material: File

Xia supplementary material

Xia supplementary material 1

Download Xia supplementary material(File)
File 133.6 KB