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Effects of electromigration on the growth of intermetallic compounds in Cu/SnBi/Cu solder joints

Published online by Cambridge University Press:  31 January 2011

X. Gu
Affiliation:
Department of Electronic Engineering, City University of Hong Kong, Kowloon Tong, Hong Kong, People’s Republic of China
D. Yang
Affiliation:
Department of Electronic Engineering, City University of Hong Kong, Kowloon Tong, Hong Kong, People’s Republic of China
Y.C. Chan*
Affiliation:
Department of Electronic Engineering, City University of Hong Kong, Kowloon Tong, Hong Kong, People’s Republic of China
B.Y. Wu
Affiliation:
Department of Electronic Engineering, City University of Hong Kong, Kowloon Tong, Hong Kong, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

In this study, the effects of electromigration (EM) on the growth of Cu–Sn intermetallic compounds (IMCs) in Cu/SnBi/Cu solder joints under 5 × 103 A/cm2 direct current stressing at 308, 328, and 348 K were investigated. For each Cu/SnBi/Cu solder joint under current stressing, the IMCs at the cathode side grew faster than that at the anode side. The growth of these IMCs at the anode side and the cathode side were enhanced by electric current. The growth of these IMCs at the cathode followed a parabolic growth law. The kinetics parameters of the growth of the IMCs were calculated from the thickness data of the IMCs at the cathode side at different ambient temperatures. The calculated intrinsic diffusivity (D0) of the Cu–Sn IMCs was 9.91 × 10−5 m2/s, and the activation energy of the growth of the total Cu–Sn IMC layer was 89.2 kJ/mol (0.92 eV).

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Articles
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1Puttlitz, K.J., Gaylon, G.T.: Impact of the ROHS directive on high-performance electronic systems. Part I: Need for lead utilization in exempt systems. J. Mater. Sci.-Mater. Electron. 18, 331 2007Google Scholar
2Zeng, K., Tu, K.N.: Six cases of reliability study of Pb-free solder joints in electronic packaging technology. Mater. Sci. Eng., R 38, 55 2002Google Scholar
3Suganuma, K., Kim, K-S.: Sn–Zn low temperature solder. J. Mater. Sci.-Mater. Electron. 18, 121 2007CrossRefGoogle Scholar
4Miao, H-W., Duh, J-G.: Microstructure evolution in Sn–Bi and Sn–Bi–Cu solder joints under thermal aging. Mater. Chem. Phys. 71, 255 2001Google Scholar
5Tu, K.N.: Recent advances on electromigration in very-large-scale integration of interconnects. J. Appl. Phys. 94, 5451 2003CrossRefGoogle Scholar
6Lai, Y-S., Chen, K-M., Kao, C-L., Lee, C-W., Chiu, Y-T.: Electromigration of Sn–37Pb and Sn–3Ag–1.5Cu/Sn–3Ag–0.5Cu composite flip-chip solder bumps with Ti/Ni(V)/Cu under bump metallurgy. Microelectron. Reliabil. 47, 1273 2007CrossRefGoogle Scholar
7Nah, J.W., Ren, F., Tu, K.N., Venk, S., Camara, G.: Electromigration in Pb-free flip chip solder joints on flexible substrates. J. Appl. Phys. 99, 023520 2006Google Scholar
8Wu, J.D., Zheng, P.J., Lee, C.W., Hung, S.C., Lee, J.J.: A study in flip-chip UBM/ bump reliability with effects of SnPb solder composition. Microelectron. Reliabil. 46, 41 2006Google Scholar
9Zhang, X.F., Guo, J.D., Shang, J.K.: Abnormal polarity effect of electromigration on intermetallic compound formation in Sn–9Zn solder interconnect. Scr. Mater. 57, 513 2007Google Scholar
10Chen, L-T., Chen, C-M.: Electromigration study in the eutectic SnBi solder joint on the Ni/Au metallization. J. Mater. Res. 21, 962 2006CrossRefGoogle Scholar
11Yang, Q.L., Shang, J.K.: Interfacial segregation of Bi during current stressing of Sn–Bi/Cu solder interconnect. J. Electron. Mater. 34, 1363 2005Google Scholar
12Chen, C-M., Chen, L-T., Lin, Y-S.: Electromigration-induced Bi segregation in eutectic SnBi solder joint. J. Electron. Mater. 36, 168 2007Google Scholar
13Wu, B.Y., Chan, Y.C., Zhong, H.W., Alam, M.O., Lai, J.K.L.: Study of the thermal stress in a Pb-free half-bump solder joint under current stressing. Appl. Phys. Lett. 90, 232112 2007Google Scholar
14Chen, S-W., Chen, C-M., Liu, W-C.: Electric current effects upon the Sn–Cu and Sn–Ni interfacial reactions. J. Electron. Mater. 27, 1193 1998CrossRefGoogle Scholar
15Chen, C-M., Chen, S-W.: Electromigration effect upon the Sn–0.7 wt% Cu/Ni and Sn–3.5 wt% Ag/Ni interfacial reactions. J. Appl. Phys. 90, 1208 2001Google Scholar
16Gan, H., Tu, K.N.: Polarity effect of electromigration on kinetics of intermetallic compound formation in Pb-free solder V-groove samples. J. Appl. Phys. 97, 063514 2005Google Scholar
17Kumar, A., He, M., Chen, Z., Teo, P.S.: Effect of electromigration on interfacial reactions between electroless Ni-P and Sn–3.5% Ag solder. Thin Solid Films 413, 462 2004Google Scholar
18Ren, F., Nah, J-W., Tu, K.N., Xiong, B.S., Xu, L.H., Pang, J.H.L.: Electromigration induced ductile-to-brittle transition in lead-free solder joints. Appl. Phys. Lett. 89, 141914 2006Google Scholar
19Yan, M.Y., Suh, J.O., Ren, F., Tu, K.N., Vairagar, A.V., Mhaisalkar, S.G., Krishnamoorthy, A.: Effect of Cu3Sn coatings on electromigration lifetime improvement of Cu dual-damascene interconnects. Appl. Phys. Lett. 87, 211103 2005Google Scholar
20Garay, J.E., Anselmi-Tamburini, U., Munir, Z.A.: Enhanced growth of intermetallic phases in the Ni–Ti system by current effects. Acta Mater. 51, 4487 2003Google Scholar
21Nah, J-W., Kim, J.H., Lee, H.M., Paik, K-W.: Electromigration in flip chip solder bump of 97Pb–3Sn/37Pb–63Sn combination structure. Acta Mater. 52, 129 2004Google Scholar
22Nah, J-W., Suh, J.O., Tu, K.N., Yoon, S.W., Rao, V.S., Kripesh, V., Hua, F.: Electromigration in flip chip solder joints having a thick Cu column bump and a shallow solder interconnect. J. Appl. Phys. 100, 123513 2006Google Scholar
23Lee, T.Y., Choi, W.J., Tu, K.N., Jang, J.W., Kuo, S.M., Lin, J.K., Frear, D.R., Zeng, K., Kivilahti, J.K.: Morphology, kinetics, and thermodynamics of solid-state aging of eutectic SnPb and Pb-free solders (Sn–3.5Ag, Sn–3.8Ag–0.7Cu and Sn–0.7Cu) on Cu. J. Mater. Res. 17, 291 2002CrossRefGoogle Scholar