Hostname: page-component-cd9895bd7-lnqnp Total loading time: 0 Render date: 2024-12-28T02:22:08.494Z Has data issue: false hasContentIssue false
  • English
  • Français

Development of sandwich-structured cobalt porphyrin/niobium molybdate nanosheets catalyst for oxygen reduction

Published online by Cambridge University Press:  15 November 2018

Mengjun Wang ,
Yan Liu ,
Xiaobo Zhang ,
Zichun Fan  and
Zhiwei Tong Open the ORCID record for Zhiwei Tong [Opens in a new window]
Mengjun Wang
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Yan Liu
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Xiaobo Zhang
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Zichun Fan
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Zhiwei Tong*
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China; and SORST, Japan Science and Technology Agency (JST), Kawaguchi-shi, Saitama 332-0012, Japan
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

In this work, the negatively charged [NbMoO6]− nanosheets (NSs) were combined with positively charged [5,10,15,20-tetrakis (N-methylpyridinium-4-yl) porphyrinato cobalt] (CoTMPyP) to fabricate a sandwich-like CoTMPyP/[NbMoO6]− NSs intercalated material by a direct self-assembling process. The results confirmed that CoTMPyP cations formed an inclined monolayer between [NbMoO6]− NSs and the inclined angle was about 68°. The electrochemical properties of CoTMPyP/[NbMoO6]− NSs composite were also investigated by cyclic voltammetry and liner sweep voltammetry, which showed the enhanced electron transferred ability. The CoTMPyP/[NbMoO6]− NSs modified electrode displayed excellent electrocatalytic activity towards oxygen reduction with the reduction peak potential shifting from −0.681 to −0.235 V. And oxygen could be reduced to generate hydrogen peroxide with a two-electron process in neutral electrolytes. Moreover, the reduction peak current was linear relationship with the square root of scan rates, implying that the catalytic reaction depended on oxygen diffusion.

Keywords

cobalt porphyrinniobium molybdatehybrid materialoxygen reduction
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 24 , 28 December 2018 , pp. 4199 - 4206
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Wood, K.N., O’Hayre, R., and Pylypenko, S.: Recent progress on nitrogen/carbon structures designed for use in energy and sustainability applications. Energy Environ. Sci. 7, 1212 (2014).CrossRefGoogle Scholar
Drogui, P., Elmaleh, S., Rumeau, M., Bernard, C., and Rambaud, A.: Hydrogen peroxide production by water electrolysis: Application to disinfection. J. Appl. Electrochem. 31, 877 (2001).CrossRefGoogle Scholar
Yamanaka, I. and Murayama, T.: Neutral H2O2 synthesis by electrolysis of water and O2. Angew. Chem., Int. Ed. 47, 1900 (2008).CrossRefGoogle ScholarPubMed
Yang, Y. and Chang, H.: Multi-scale porous graphene/activated carbon aerogel enables lightweight carbonaceous catalysts for oxygen reduction reaction. J. Mater. Res. 33, 1247 (2018).CrossRefGoogle Scholar
Tymen, S., Undisz, A., Rettenmayr, M., and Ignaszak, A.: Pt–Pd catalytic nanoflowers: Synthesis, characterization, and the activity toward electrochemical oxygen reduction. J. Mater. Res. 30, 2327 (2015).CrossRefGoogle Scholar
Dignard-Bailey, L., Trudeau, M.L., Joly, A., Schulz, R., Lalande, G., Guay, D., and Dodelet, J.P.: Graphitization and particle size analysis of pyrolyzed cobalt phthalocyanine/carbon catalysts for oxygen reduction in fuel cells. J. Mater. Res. 9, 3203 (1994).CrossRefGoogle Scholar
Liang, H., Li, C., Chen, T., Cui, L., Han, J., Peng, Z., and Liu, J.: Facile preparation of three-dimensional Co1−xS/sulfur and nitrogen-codoped graphene/carbon foam for highly efficient oxygen reduction reaction. J. Power Sources 378, 699 (2018).CrossRefGoogle Scholar
Zhong, H., Luo, Y., He, S., Tang, P., Li, D., Alonso-Vante, N., and Feng, Y.: Electrocatalytic cobalt nanoparticles interacting with nitrogen-doped carbon nanotube in situ generated from a metal-organic framework for the oxygen reduction reaction. ACS Appl. Mater. Interfaces 9, 2541 (2017).CrossRefGoogle ScholarPubMed
Yan, X., Xu, X., Liu, Q., Guo, J., Kang, L., and Yao, J.: Functionalization of multi-walled carbon nanotubes with iron phthalocyanine via a liquid chemical reaction for oxygen reduction in alkaline media. J. Power Sources 389, 260 (2018).CrossRefGoogle Scholar
Oldacre, A.N., Friedman, A.E., and Cook, T.R.: A self-assembled cofacial cobalt porphyrin prism for oxygen reduction catalysis. J. Am. Chem. Soc. 139, 1424 (2017).CrossRefGoogle ScholarPubMed
Jasinski, R.: A new fuel cell cathode catalyst. Nature 201, 1212 (1964).CrossRefGoogle Scholar
Wang, X., Wang, B., Zhong, J., Zhao, F., Han, N., Huang, W., Zeng, M., Fan, J., and Li, Y.: Iron polyphthalocyanine sheathed multiwalled carbon nanotubes: A high-performance electrocatalyst for oxygen reduction reaction. Nano Res. 9, 1497 (2016).CrossRefGoogle Scholar
Riquelme, J., Neira, K., Marco, J.F., Hermosilla-Ibáñez, P., Orellana, W., Zagal, J.H., and Tasca, F.: Biomimicking vitamin B12. A Co phthalocyanine pyridine axial ligand coordinated catalyst for the oxygen reduction reaction. Electrochim. Acta 265, 547 (2018).CrossRefGoogle Scholar
Pan, B., Ma, J., Zhang, X., Liu, L., Zhang, D., Li, J., Yang, M., Zhang, Z., and Tong, Z.: Sandwich-structured nanocomposite constructed by fabrication of exfoliation α-ZrP nanosheets and cobalt porphyrin utilized for electrocatalytic oxygen reduction. Microporous Mesoporous Mater. 223, 213 (2015).CrossRefGoogle Scholar
HaoYu, E., Cheng, S., Scott, K., and Logan, B.: Microbial fuel cell performance with non-Pt cathode catalysts. J. Power Sources 171, 275 (2007).CrossRefGoogle Scholar
Zagal, J.H., Griveau, S., Silva, J.F., Nyokong, T., and Bedioui, F.: Metallophthalocyanine-based molecular materials as catalysts for electrochemical reactions. Coord. Chem. Rev. 254, 2755 (2010).CrossRefGoogle Scholar
Putten, A.V.D., Elzing, A., Visscher, W., and Barendrecht, E.: Oxygen reduction on vacuum-deposited and adsorbed transition-metal phthalocyanine films. J. Electroanal. Chem. 214, 523 (1986).CrossRefGoogle Scholar
Tang, H., Yin, H., Wang, J., Yang, N., Wang, D., and Tang, Z.: Molecular architecture of cobalt porphyrin multilayers on reduced graphene oxide sheets for high-performance oxygen reduction reaction. Angew. Chem. 125, 5695 (2013).CrossRefGoogle Scholar
Sonkar, P.K., Prakash, K., Yadav, M., Ganesan, V., Sankar, M., Gupta, R., and Yadav, D.K.: Co(II)-porphyrin-decorated carbon nanotubes as catalysts for oxygen reduction reactions: An approach for fuel cell improvement. J. Mater. Chem. A 5, 6263 (2017).CrossRefGoogle Scholar
Li, J., Song, Y., Zhang, G., Liu, H., Wang, Y., Sun, S., and Guo, X.: Pyrolysis of self-assembled iron porphyrin on carbon black as core/shell structured electrocatalysts for highly efficient oxygen reduction in both alkaline and acidic medium. Adv. Funct. Mater. 27, 1604356 (2017).CrossRefGoogle Scholar
Morozan, A., Campidelli, S., Filoramo, A., Jousselme, B., and Palacin, S.: Catalytic activity of cobalt and iron phthalocyanines or porphyrins supported on different carbon nanotubes towards oxygen reduction reaction. Carbon 49, 4839 (2011).CrossRefGoogle Scholar
Wang, M., Fan, Z., Yi, L., Xu, J., Zhang, X., and Tong, Z.: Construction of iron porphyrin/titanoniobate nanosheet sensors for the sensitive detection of nitrite. J. Mater. Sci. 53, 11403 (2018).CrossRefGoogle Scholar
Pan, B., Xu, J., Zhang, X., Li, J., Wang, M., Ma, J., Liu, L., Zhang, D., and Tong, Z.: Electrostatic self-assembly behaviour of exfoliated Sr2Nb3O10− nanosheets and cobalt porphyrins: Exploration of non-noble electro-catalysts towards hydrazine hydrate oxidation. J. Mater. Sci. 53, 6494 (2018).CrossRefGoogle Scholar
Pearson, A.J.: Structure formation and evolution in semiconductor films for perovskite and organic photovoltaics. J. Mater. Res. 32, 1798 (2017).CrossRefGoogle Scholar
Liu, C., Wu, Q., Ji, M., Zhu, H., Hou, H., Yang, Q., Jiang, C., Wang, J., Tian, L., Chen, J., and Hou, W.: Constructing z-scheme charge separation in 2D layered porous BiOBr/graphitic C3N4 nanosheets nanojunction with enhanced photocatalytic activity. J. Alloys Compd. 723, 1121 (2017).CrossRefGoogle Scholar
Liu, C., Zhu, H., Zhu, Y., Dong, P., Hou, H., Xu, Q., Chen, X., Xi, X., and Hou, W.: Ordered layered N-doped KTiNbO5/g-C3N4 heterojunction with enhanced visible light photocatalytic activity. Appl. Catal., B 228, 54 (2018).CrossRefGoogle Scholar
Liu, M., Hou, Y., and Qu, X.: Enhanced power conversion efficiency of dye-sensitized solar cells with samarium doped TiO2 photoanodes. J. Mater. Res. 32, 3469 (2017).CrossRefGoogle Scholar
Zhang, X., Li, S., Liu, C., Feng, D., Zhang, T., Tong, Z., and Inoue, H.: Characterization of photoelectrochemical active intercalation compound of K4Nb6O17 with methylviologen. Microporous Mesoporous Mater. 117, 326 (2009).CrossRefGoogle Scholar
Tong, Z., Takagi, S., Tachibana, H., Takagi, K., and Inoue, H.: Novel soft chemical method for optically transparent Ru(bpy)3-K4Nb6O17 thin film. J. Phys. Chem. B 109, 21612 (2005).CrossRefGoogle ScholarPubMed
Tong, Z., Takagi, S., Shimada, T., Tachibana, H., and Inoue, H.: Photoresponsive multilayer spiral nanotubes: Intercalation of polyfluorinated cationic azobenzene surfactant into potassium niobate. J. Am. Chem. Soc. 128, 684 (2006).CrossRefGoogle ScholarPubMed
Liu, C., Han, R., Ji, H., Sun, T., Zhao, J., Chen, N., Chen, J., Guo, X., Hou, W., and Ding, W.: S-doped mesoporous nanocomposite of HTiNbO5 nanosheets and TiO2 nanoparticles with enhanced visible light photocatalytic activity. Phys. Chem. Chem. Phys. 18, 801 (2016).CrossRefGoogle ScholarPubMed
Zhai, Z., Yang, X., Xu, L., Hu, C., Zhang, L., Hou, W., and Fan, Y.: Novel mesoporous NiO/HTiNbO5 nanohybrids with high visible-light photocatalytic activity and good biocompatibility. Nanoscale 4, 547 (2012).CrossRefGoogle ScholarPubMed
He, J., Li, Q., Tang, Y., Yang, P., Li, A., Li, R., and Li, H.: Characterization of HNbMoO6, HNbWO6, and HTiNbO5 as solid acids and their catalytic properties for esterification reaction. Appl. Catal., A 443–444, 145 (2012).CrossRefGoogle Scholar
Shen, P., Zhang, H., Liu, H., Xin, J., Fei, L., Luo, X., Ma, R., and Zhang, S.: Core–shell Fe3O4@SiO2@HNbMoO6 nanocomposites: New magnetically recyclable solid acid for heterogeneous catalysis. J. Mater. Chem. A 3, 3456 (2015).CrossRefGoogle Scholar
Bhuvanesh, N.S.P. and Gopalakrishnan, J.: Synthesis of rutile-related oxides, LiMMoO6 (M = Nb, Ta), and their proton derivatives. Intercalation chemistry of novel broensted acids, HMMoO6.cntdot.H2O. Inorg. Chem. 34, 3760 (1995).CrossRefGoogle Scholar
Hambright, P. and Fleischer, E.B.: Acid-base equilibria, kinetics of copper ion incorporation, and acid-catalyzed zinc ion displacement from the water-soluble porphyrin. alpha.,.beta.,.gamma.,.delta.-tetrakis (1-methyl-4-pyridinio) porphine tetraiodide. Inorg. Chem. 9, 1757 (1970).CrossRefGoogle Scholar
Wang, P., Zhou, F., Wang, Z., Lai, C., and Han, X.: Substrate-induced assembly of PtAu alloy nanostructures at choline functionalized monolayer interface for nitrite sensing. J. Electroanal. Chem. 750, 36 (2015).CrossRefGoogle Scholar
Liu, L., Ma, J., Shao, F., Zhang, D., Gong, J., and Tong, Z.: A nanostructured hybrid synthesized by the intercalation of CoTMPyP into layered titanate: Direct electrochemistry and electrocatalysis. Electrochem. Commun. 24, 74 (2012).CrossRefGoogle Scholar
Zhang, X., Wang, M., Li, D., Liu, L., Ma, J., Gong, J., Yang, X., Xu, X., and Tong, Z.: Electrochemical investigation of a novel metalloporphyrin intercalated layered niobate modified electrode and its electrocatalysis on ascorbic acid. J. Solid State Electrochem. 17, 3177 (2013).CrossRefGoogle Scholar
Fuerte, A., Corma, A., Iglesias, M., Morales, E., and Sánchez, F.: Approaches to the synthesis of heterogenised metalloporphyrins: Application of new materials as electrocatalysts for oxygen reduction. J. Mol. Catal. A: Chem. 246, 109 (2006).CrossRefGoogle Scholar
Zuo, G., Yuan, H., Yang, J., Zuo, R., and Lu, X.: Study of orientation mode of cobalt-porphyrin on the surface of gold electrode by electrocatalytic dioxygen reduction. J. Mol. Catal. A: Chem. 269, 46 (2007).CrossRefGoogle Scholar
Huang, W., Zhong, H., Li, D., Tang, P., and Feng, Y.: Reduced graphene oxide supported CoO/MnO2 electrocatalysts from layered double hydroxides for oxygen reduction reaction. Electrochim. Acta 173, 575 (2015).CrossRefGoogle Scholar
Yin, H., Tang, H., Wang, D., Gao, Y., and Tang, Z.: Facile synthesis of surfactant-free Au cluster/graphene hybrids for high-performance oxygen reduction reaction. ACS Nano 6, 8288 (2012).CrossRefGoogle ScholarPubMed
Liu, H., Zhang, L., Zhang, J., Ghosh, D., Jung, J., Downing, B.W., and Whittemore, E.: Electrocatalytic reduction of O2 and H2O2 by adsorbed cobalt tetramethoxyphenyl porphyrin and its application for fuel cell cathodes. J. Power Sources 161, 743 (2006).CrossRefGoogle Scholar
Durand, R.R. Jr. and Anson, F.C.: Catalysis of dioxygen reduction at graphite electrodes by an adsorbed cobalt(ii) porphyrin. J. Electroanal. Chem. Interfacial Electrochem. 134, 273 (1982).CrossRefGoogle Scholar