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Crystal orientation of β-Sn grain in Ni(P)/Sn–0.5Cu/Cu and Ni(P)/Sn–1.8Ag/Cu joints

Published online by Cambridge University Press:  31 January 2011

Hyuck Mo Lee*
Affiliation:
Department of Materials Science and Engineering, KAIST, Yuseong-gu, Daejeon, 305-701, Republic of Korea
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Electron backscatter diffraction analysis was used to compare the crystal orientation of β-Sn grains in Ni(P)/Sn–0.5Cu/Cu and Ni(P)/Sn–1.8Ag/Cu joints before and after aging. In Ni(P)/solder/Cu joints, the solder composition (Cu versus Ag) significantly affects β-Sn grain orientation. In Ni(P)/Sn–0.5Cu/Cu, there are two types of small columnar grains grown from Ni(P) and Cu under bump metallurgy with a high-angle grain boundary crossing the joint closer to the Ni side; in contrast, Ni(P)/Sn–1.8Ag/Cu has large grains with low-angle boundaries. During thermal aging at 150 °C for 250 h, the Ni(P)/Sn–0.5Cu/Cu joints undergo a more significant microstructural change than the Ni(P)/Sn–1.8Ag/Cu joint. Additionally, obvious ledges developed along the high-angle grain boundary between the upper and lower areas in the Sn–0.5Cu joint.

Type
Articles
Copyright
Copyright © Materials Research Society 2010

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References

REFERENCES

1.Park, S., Dhakal, R., Lehman, L., Cotts, E.Measurement of deformations in SnAgCu solder interconnects under in situ thermal loading. Acta Mater. 55, 3253 (2007)CrossRefGoogle Scholar
2.Henderson, D.W., Woods, J.J., Gosselin, T.A., Bartelo, J., King, D.E., Korhonen, T.M., Korhonen, M.A., Lehman, L.P., Cotts, E.J., Kang, S.K., Lauro, P., Shih, D-Y., Goldsmith, C., Puttlitz, K.J.The microstructure of Sn in near-eutectic Sn–Ag–Cu alloy solder joints and its role in thermomechanical fatigue. J. Mater. Res. 19, 1608 (2004)CrossRefGoogle Scholar
3.Lu, M., Shih, D-Y., Lauro, P., Goldsmith, C., Henderson, D.W.Effect of Sn grain orientation on electromigration degradation mechanism in high Sn-based Pb-free solders. Appl. Phys. Lett. 92, 211909 (2008)CrossRefGoogle Scholar
4.Telang, A.U., Bieler, T.R., Zamiri, A., Pourboghrat, F.Incremental recrystallization/grain growth driven by elastic strain energy release in a thermomechanically fatigued lead-free solder joint. Acta Mater. 55, 2265 (2007)CrossRefGoogle Scholar
5.Matin, M.A., Coenen, E.W.C., Vellinga, W.P., Geers, M.G.D.Correlation between thermal fatigue and thermal anisotropy in a Pb-free solder alloy. Scr. Mater. 53, 927 (2005)CrossRefGoogle Scholar
6.Seo, S-K., Kang, S.K., Cho, M.G., Shih, D-Y., Lee, H.M.The crystal orientation of β-Sn grains in Sn–Ag and Sn–Cu solders affected by their interfacial reactions with Cu and Ni(P) under bump metallurgy. J. Electron. Mater. 38, 2461 (2009)CrossRefGoogle Scholar
7.Seo, S-K., Kang, S.K., Shih, D-Y., Lee, H.M.An investigation of microstructure and microhardness of Sn–Cu and Sn–Ag solders as functions of alloy composition and cooling rate. J. Electron. Mater. 38, 257 (2009)CrossRefGoogle Scholar
8.Lehman, L.P., Athavale, S.N., Fullem, T.Z., Giamis, A.C., Kinyanjui, R.K., Lowenstein, M., Mather, K., Patel, R., Rae, D., Wang, J., Xing, Y., Zavalij, L., Borgesen, P., Cotts, E.J.Growth of Sn and intermetallic compounds in Sn–Ag–Cu solder. J. Electron. Mater. 33, 1429 (2004)CrossRefGoogle Scholar
9.Cho, M.G., Kang, S.K., Lee, H.M.Undercooling and microhardness of Pb-free solders on various under bump metallurgies. J. Mater. Res. 23, 1147 (2008)CrossRefGoogle Scholar
10.Telang, A.U., Bieler, T.R., Lucas, J.P., Subramanian, K.N., Lehman, L.P., Xing, Y., Cotts, E.J.Grain-boundary character and grain growth in bulk tin and bulk lead-free solder alloys. J. Electron. Mater. 33, 1412 (2004)CrossRefGoogle Scholar
11.Henderson, D.W., Woods, J.J., Gosselin, T.A., Bartelo, J., King, D.E., Korhonen, T.M., Korhnen, M.A., Lehman, L.P., Cotts, E.J., Kang, S.K., Lauro, P., Shih, D-Y., Goldsmith, C., Puttlitz, K.J.The microstructure of Sn in near-eutectic Sn–Ag–Cu alloy solder joints and its role in thermomechanical fatigue. J. Mater. Res. 19, 1608 (2004)CrossRefGoogle Scholar
12.Bieler, T.R., Jiang, H.R., Lehman, L.P., Kirkpatrick, T., Cotts, E.J., Nandagopal, B.Influence of Sn grain size and orientation on the thermomechanical response and reliability of Pb-free solder joints. IEEE Trans. Compon. Packag. Technol. 31, (2)370 (2008)CrossRefGoogle Scholar
13.Verhoeven, J.D.Fundamentals of Physical Metallurgy (John Wiley & Sons Inc., New York 1975)Google Scholar