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Correlation between the atomic configurations and the amorphous-to-icosahedral phase transition in metallic glasses

Published online by Cambridge University Press:  22 June 2018

Guihong Geng ,
Zhijie Yan ,
Yong Hu ,
Zhi Wang ,
Sergey V. Ketov  and
Jürgen Eckert
Guihong Geng
Affiliation:
School of Materials Science and Engineering, North Minzu University, Yinchuan 750021, People’s Republic of China
Zhijie Yan*
Affiliation:
School of Materials Science and Engineering, North Minzu University, Yinchuan 750021, People’s Republic of China; and School of Materials Science and Engineering, North University of China, Taiyuan 030051, People’s Republic of China
Yong Hu
Affiliation:
School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, People’s Republic of China
Zhi Wang
Affiliation:
School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640, China
Sergey V. Ketov
Affiliation:
Erich Schmid Institute of Materials Science, Austrian Academy of Sciences, Leoben 8700, Austria
Jürgen Eckert
Affiliation:
Erich Schmid Institute of Materials Science, Austrian Academy of Sciences, Leoben 8700, Austria; and Department of Materials Physics, Montanuniversität Leoben, Leoben 8700, Austria
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Positron annihilation spectroscopy and differential scanning calorimetry were used to evaluate the changes of the atomic configurations in Zr-based metallic glasses (MGs) due to alloying and plastic deformation. The correlation between the atomic configurations of MGs and the amorphous-to-icosahedral phase transition due to heating was investigated. The results indicate that the free volume frozen in the as-cast Zr60Al15Ni25, Zr65Al7.5Ni10Cu17.5, and Zr65Al7.5Ni10Cu17.5Ag5 MGs substantially decreases in sequence. More excess free volume is introduced in Zr65Al7.5Ni10Cu17.5Ag5 MG due to cold rolling and milling. The annihilation of free volume due to alloying considerably stabilizes the icosahedral structure of MGs, which enhances the nucleation and growth of quasicrystals upon heating. However, the nucleation and growth of quasicrystals are considerably suppressed in Zr65Al7.5Ni10Cu17.5Ag5 MG due to cold rolling and milling, during which the more introduced excess free volume results in substantial destruction of short-range order with 5-fold symmetry. The present work further provides direct evidence for the prevalence of icosahedral short-range order in MGs.

Keywords

amorphousphase transformationquasicrystal
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 18 , 28 September 2018 , pp. 2775 - 2783
Copyright
Copyright © Materials Research Society 2018 

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Footnotes

Contributing Editor: Jurgen Eckert

b)

This author was an editor of this journal during the review and decision stage. For the JMR policy on review and publication of manuscripts authored by editors, please refer to http://www.mrs.org/editor-manuscripts/.

References

REFERENCES

Shechtman, D., Blech, I., Gratias, D., and Cahn, J.W.: Metallic phase with long-range orientational order and no translational symmetry. Phys. Rev. Lett. 53, 1951 (1984).CrossRefGoogle Scholar
Chen, L.C. and Spaepen, F.: Calorimetric evidence for the micro-quasicrystalline structure of ‘amorphous’ Al/transition metal alloys. Nature 336, 366 (1988).CrossRefGoogle Scholar
Saida, J., Matsushita, M., Zhang, T., Inoue, A., Chen, M.W., and Sakurai, T.: Precipitation of icosahedral phase from a supercooled liquid region in Zr65Cu7.5Al7.5Ni10Ag10 metallic glass. Appl. Phys. Lett. 75, 3497 (1999).CrossRefGoogle Scholar
Lee, G.W., Gangopadhyay, A.K., and Kelton, K.F.: Phase diagram studies of Ti–Zr–Ni alloys containing less than 40 at.% Ni and estimated critical cooling rate for icosahedral quasicrystal formation from the liquid. Acta Mater. 59, 4964 (2011).CrossRefGoogle Scholar
Luo, W.K., Sheng, H.W., Alamgir, F.M., Bai, J.M., He, J.H., and Ma, E.: Icosahedral short-range order in amorphous alloys. Phys. Rev. Lett. 92, 145502 (2004).CrossRefGoogle ScholarPubMed
Liu, X.J., Chen, G.L., Hui, X., Liu, T., and Lu, Z.P.: Ordered clusters and free volume in a Zr–Ni metallic glass. Appl. Phys. Lett. 93, 011911 (2008).CrossRefGoogle Scholar
Shen, Y.T., Kim, T.H., Gangopadhyay, A.K., and Kelton, K.F.: Icosahedral order, frustration, and the glass transition: Evidence from time-dependent nucleation and supercooled liquid structure studies. Phys. Rev. Lett. 102, 057801 (2009).CrossRefGoogle ScholarPubMed
Zhao, Y.F., Lin, D.Y., Chen, X.H., Liu, Z.K., and Hui, X.D.: Sluggish mobility and strong icosahedral ordering in Mg–Zn–Ca liquid and glassy alloys. Acta Mater. 67, 266 (2014).CrossRefGoogle Scholar
Chen, M.W., Zhang, T., Inoue, A., Sakai, A., and Sakurai, T.: Quasicrystals in a partially devitrified Zr65Al7.5Ni10Cu12.5Ag5 bulk metallic glass. Appl. Phys. Lett. 75, 1697 (1999).CrossRefGoogle Scholar
Inoue, A., Zhang, T., Saida, J., Matsushita, M., Chen, M.W., and Sakurai, T.: Formation of icosahedral quasicrystalline phase in Zr–Al–Ni–Cu–M (M = Ag, Pd, Au or Pt) systems. Mater. Trans., JIM 40, 1181 (1999).CrossRefGoogle Scholar
Louzguine, D.V. and Inoue, A.: Nanoparticles with icosahedral symmetry in Cu-based bulk glass former induced by Pd addition. Scr. Mater. 48, 1325 (2003).CrossRefGoogle Scholar
Wang, Z., Ketov, S.V., Chen, C.L., Shen, Y., Ikuhara, Y., Tsarkov, A.A., Louzguine-Luzgin, D.V., and Perepezko, J.H.: Nucleation and thermal stability of an icosahedral nanophase during the early crystallization stage in Zr–Co–Cu–Al metallic glasses. Acta Mater. 132, 298 (2017).CrossRefGoogle Scholar
Kühn, U., Eymann, K., Mattern, N., Eckert, J., Gebert, A., Bartusch, B., and Schultz, L.: Limited quasicrystal formation in Zr–Ti–Cu–Ni–Al bulk metallic glasses. Acta Mater. 54, 4685 (2006).CrossRefGoogle Scholar
Lee, G.W., Gangopadhyay, A.K., and Kelton, K.F.: Effect of microalloying on the formation and stability of the Ti–Zr–Ni icosahedral quasicrystal. J. Alloys Compd. 537, 171 (2012).CrossRefGoogle Scholar
Saida, J., Yamada, R., Kozikowski, P., Imafuku, M., Sato, S., and Ohnuma, M.: Characterization of nano-quasicrystal-formation in correlation to the local structure in Zr-based metallic glasses containing Pd. J. Alloys Compd. 707, 46 (2017).CrossRefGoogle Scholar
Saida, J., Setyawan, A.D., and Matsubara, E.: Effect of relaxation state on nucleation and grain growth of nanoscale quasicrystal in Zr-based bulk metallic glasses prepared under various cooling rates. Appl. Phys. Lett. 99, 061903 (2011).CrossRefGoogle Scholar
Yan, Z.J., Song, K.K., Hu, Y., Dai, F.P., Chu, Z.B., and Eckert, J.: Localized crystallization in shear bands of a metallic glass. Sci. Rep. 6, 19358 (2016).CrossRefGoogle ScholarPubMed
Hori, F., Ishii, A., Ishiyama, T., Iwase, A., Yokoyama, Y., and Konno, T.J.: Composition dependence of open-volume relaxation in Zr–Cu–Al bulk amorphous alloys studied by positron annihilation. J. Alloys Compd. 707, 73 (2017).CrossRefGoogle Scholar
Nagel, C., Rätzke, K., Schmidtke, E., Faupel, F., and Ulfert, W.: Positron-annihilation studies of free-volume changes in the bulk metallic glass Zr65Al7.5Ni10Cu17.5 during structural relaxation and at the glass transition. Phys. Rev. B 60, 9212 (1999).CrossRefGoogle Scholar
Kanungo, B.P., Glade, S.C., Asoka-Kumar, P., and Flores, K.M.: Characterization of free volume changes associated with shear band formation in Zr- and Cu-based bulk metallic glasses. Intermetallics 12, 1073 (2004).CrossRefGoogle Scholar
Dong, F.Y., Su, Y.Q., Luo, L.S., Guo, J.J., Fu, H.Z., Li, Z.X., and Wang, B.Y.: Characterization of hydrogen-induced structural changes in Zr-based bulk metallic glasses using positron annihilation spectroscopy. J. Mater. Res. 27, 2587 (2012).CrossRefGoogle Scholar
Evenson, Z., Koschine, T., Wei, S., Gross, O., Bednarčik, J., Gallino, I., Kruzic, J.J., Rätzke, K., Faupel, F., and Busch, R.: The effect of low-temperature structural relaxation on free volume and chemical short-range ordering in a Au49Cu26.9Si16.3Ag5.5Pd2.3 bulk metallic glass. Scr. Mater. 103, 14 (2015).CrossRefGoogle Scholar
Filipečka, K., Pawlik, R., and Filipečki, J.: The effect of annealing on magnetic properties, phase structure and evolution of free volumes in Pr–Fe–B–W metallic glasses. J. Alloys Compd. 694, 228 (2017).CrossRefGoogle Scholar
Slipenyuk, A. and Eckert, J.: Correlation between enthalpy change and free volume reduction during structural relaxation Zr55Cu30Al10Ni5 metallic glass. Scr. Mater. 50, 39 (2004).CrossRefGoogle Scholar
Xu, Y.L., Fang, J.X., Gleiter, H., Hahn, H., and Li, J.G.: Quantitative determination of free volume in Pd40Ni40P20 bulk metallic glass. Scr. Mater. 62, 674 (2010).CrossRefGoogle Scholar
Yan, Z.J., Yan, J., Tuo, L.F., Hu, Y., and Deng, S.E.: Microstructure evolution of Zr60Al15Ni25 bulk metallic glass subjected to rolling at room temperature. J. Alloys Compd. 504S, S251 (2010).CrossRefGoogle Scholar
Köster, U., Meinhardt, J., Roos, S., and Liebertz, H.: Formation of quasicrystals in bulk glass forming Zr–Cu–Ni–Al alloys. Appl. Phys. Lett. 69, 179 (1996).CrossRefGoogle Scholar
Sheng, H.W., Luo, W.K., Alamgir, F.M., Bai, J.M., and Ma, E.: Atomic packing and short-to-medium-range order in metallic glasses. Nature 439, 419 (2006).CrossRefGoogle ScholarPubMed
Hirata, A., Guan, P.F., Fujita, T., Hirotsu, Y., Inoue, A., Yavari, A.R., Sakurai, T., and Chen, M.W.: Direct observation of local order in a metallic glasses. Nat. Mater. 10, 28 (2011).CrossRefGoogle Scholar
Fang, X.W., Wang, C.Z., Hao, S.G., Kramer, M.J., Yao, Y.X., Mendelev, M.I., Ding, Z.J., Napolitano, R.E., and Ho, K.M.: Spatially resolved distribution function and the medium-range order in metallic liquid and glass. Sci. Rep. 1, 194 (2011).CrossRefGoogle ScholarPubMed
Bernal, J.D.: Geometry of the structure of monatomic liquids. Nature 185, 68 (1960).CrossRefGoogle Scholar
Boudreaux, D.S. and Frost, H.J.: Short-range order in theoretical models of binary metallic glass alloys. Phys. Rev. B 28, 1506 (1981).CrossRefGoogle Scholar
Frank, F.C.: Supercooling of liquids. Proc. R. Soc. London, Ser. A 215, 43 (1952).CrossRefGoogle Scholar
Sadoc, J.F.: Use of regular polytopes for the mathematical description of the order in amorphous structures. J. Non-Cryst. Solids 44, 1 (1981).CrossRefGoogle Scholar
Cheng, Y.Q. and Ma, E.: Atomic-level structure and structure–property relationship in metallic glasses. Prog. Mater. Sci. 56, 379 (2011).CrossRefGoogle Scholar
Fujita, T., Konno, K., Zhang, W., Kumar, V., Matsuura, M., Inoue, A., Sakurai, T., and Chen, M.W.: Atomic-scale heterogeneity of a multicomponent bulk metallic glass with excellent glass forming ability. Phys. Rev. Lett. 103, 075502 (2009).CrossRefGoogle ScholarPubMed
Hirata, A., Kang, L.J., Fujita, T., Klumov, B., Matsue, K., Kotani, M., Yavari, A.R., and Chen, M.W.: Geometric frustration of icosahedron in metallic glasses. Science 341, 376 (2013).CrossRefGoogle ScholarPubMed
Yavari, A.R., Le Moulec, A., Inoue, A., Nishiyama, N., Lupu, N., Matsubara, E., Botta, W.J., Vaughan, G., Di Michiel, M., and Kvick, Å.: Excess free volume in metallic glasses measured by X-ray diffraction. Acta Mater. 53, 1611 (2005).CrossRefGoogle Scholar
Nelson, D.R.: Order, frustration, and defects in liquids and glasses. Phys. Rev. B 28, 5515 (1983).CrossRefGoogle Scholar
Saksl, K., Franz, H., Jóvári, P., Klementiev, K., Welter, E., Ehnes, A., Saida, J., Inoue, A., and Jiang, J.Z.: Evidence of icosahedral short-range order in Zr70Cu30 and Zr70Cu29Pd1 metallic glasses. Appl. Phys. Lett. 83, 3924 (2003).CrossRefGoogle Scholar
Ritter, Y. and Albe, K.: Thermal annealing of shear bands in deformed metallic glasses: Recovery mechanisms in Cu64Zr36 studied by molecular dynamics simulations. Acta Mater. 59, 7082 (2011).CrossRefGoogle Scholar
Zhang, Y., Mattern, N., and Eckert, J.: Effect of uniaxial loading on the structural anisotropy and the dynamics of atoms of Cu50Zr50 metallic glasses within the elastic regime studied by molecular dynamics simulation. Acta Mater. 59, 4303 (2011).CrossRefGoogle Scholar