Published online by Cambridge University Press: 28 March 2006
The frequency dependence of the velocity and attenuation of sound waves in a gas which undergoes vibrational relaxation have been investigated theoretically. At low audible frequencies the attenuations due to viscosity, thermal conduction and relaxationin the gas, add linearly, while the velocity is the relaxation velocity diminished by the Helmholtz-Kirchhoff factor. The relations have been confirmed experimentally, and the free gas velocities of sound at zero frequency, one atmosphere pressure and 30 °C, found for carbon dioxide, air and oxygen, are 270·57 ± 0·04 m sec−1, 349·18 ± 0·02 m sec−1 and 331·33 ± 0·03 m sec−1, respectively. The corresponding specific heats are Cp/R = 4·537 ± 0·008 for carbon dioxide and Cp/R = 3·547 ± 0·003 for oxygen.