Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-18T23:10:47.315Z Has data issue: false hasContentIssue false

On Marangoni drying: nonlinear kinematic waves in a thin film

Published online by Cambridge University Press:  26 April 2006

S. B. G. M. O'Brien
Affiliation:
Philips Research Laboratories, P.O. Box 80000, 5600 JA Eindhoven, The Netherlands Current address: Department of Mathematics, University of Limerick, Ireland.

Abstract

In the field of industrial drying, a recent innovation has exploited the occurrence of Marangoni effects in such a way that the resultant free-surface flow enhances the drying process. To this end, alcohol vapour, soluble in water, is introduced above a drying film and as a result of diffusion through the air and water phases a favourable concentration gradient gives rise to the required shear flow. We consider here a simple process driven by this mechanism, and by means of asymptotic simplification and the concepts of singular perturbation theory a leading-order approximation is obtained in which the alcohol concentration in the water is a specified function of space and time. The evolution of the free surface thus reduces to a single nonlinear partial differential equation of a similar form to the Korteweg–de Vries and Burgers equations, higher-derivative terms corresponding to surface tension and gravity effects. Numerical solutions of this equation are obtained and are compared to the application of first order nonlinear kinematic wave theory with corresponding shock solutions.

Type
Research Article
Copyright
© 1993 Cambridge University Press

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Benney, D. J. 1966 Long waves in liquid films. J. Math. & Phys. 45, 150.Google Scholar
Gaver, D. P. & Grotberg, J. B. 1990 The dynamics of a localized surfactant on a thin film. J. Fluid Mech. 213, 127.Google Scholar
Halpern, D. & Grotberg, J. B. 1992 Dynamics and transport of a localized soluble surfactant on a thin film. J. Fluid Mech. 237, 1.Google Scholar
Hansen, R. S. 1960 The theory of diffusion controlled absorption kinetics with accompanying evaporation. J. Colloid Si. 64, 637.Google Scholar
Haydon, R. 1958 An investigation of droplet oscillation during mass transfer. Proc. R. Soc. Lond. A 243, 483.Google Scholar
Jensen, O. E. & Grotberg, J. B. 1992 Insoluble surfactant spreading on a thin viscous film; shock evolution and film rupture. J. Fluid Mech. 240, 259.Google Scholar
Kevorkian, J. & Cole, J. D. 1981 Perturbation Methods in Applied Mathematics. Springer.
Leenaars, A. F. M., Huethorst, J. A. M. & Oekel, J. J. van 1991 Marangoni drying: a new extremely clean process. Langmuir 7, 2748.Google Scholar
Levich, V. G. & Krylov, V. S. 1969 Surface tension driven phenomena. Ann. Rev. Fluid Mech. 1, 293.Google Scholar
Marangoni, C. G. M. 1871 Ann. Phys. (Poggendorff) 143, 337.
Moriarty, J. A., Schwartz, L. W. & Tuck, E. O. 1991 Unsteady spreading of thin liquid films with small surface tension. Phys. Fluids A 3, 733.Google Scholar
Myshkis, A. D. 1986 Low Gravity Fluid Mechanics. Springer.
Overdiep, W. S. 1986 The levelling of paints. Prog. Organic Coatings 14, 159.Google Scholar
Patberg, W. B., Koers, A., Steenge, W. D. E. & Drinkenburg, A. A. H. 1983 Chem. Engng Sci. 38, 917.
Peregrine, D. H. 1966 Calculations of the development of an undular bore. J. Fluid Mech. 25, 321.Google Scholar
Pimputkar, S. M. & Ostrach, S. 1980 Transient thermocapillary flow in thin liquid layers. Phys. Fluids 23, 1281.Google Scholar
Scriven, L. E. & Sternling, C. V. 1960 The Marangoni effects. Nature 187, 186.Google Scholar
Thomson, J. 1855 Phil. Mag. (4) 10, 330.
Whitham, G. B. 1974 Linear and Nonlinear Waves. John Wiley & Sons.