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Instability and symmetry breaking in binary evaporating thin films over a solid spherical dome

Published online by Cambridge University Press:  12 March 2021

Xingyi Shi Open the ORCID record for Xingyi Shi [Opens in a new window] ,
Mariana Rodríguez-Hakim Open the ORCID record for Mariana Rodríguez-Hakim [Opens in a new window] ,
Eric S.G. Shaqfeh  and
Gerald G. Fuller
Xingyi Shi
Affiliation:
Department of Chemical Engineering, Stanford University, Stanford, CA94305, USA
Mariana Rodríguez-Hakim
Affiliation:
Department of Chemical Engineering, Stanford University, Stanford, CA94305, USA Department of Materials, ETH Zürich, Vladimir-Prelog-Weg 5, 8093Zurich, Switzerland
Eric S.G. Shaqfeh*
Affiliation:
Department of Chemical Engineering, Stanford University, Stanford, CA94305, USA Department of Mechanical Engineering, Stanford University, Stanford, CA94305, USA
Gerald G. Fuller
Affiliation:
Department of Chemical Engineering, Stanford University, Stanford, CA94305, USA
*
†Email address for correspondence: [email protected]
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Abstract

We examine the axisymmetric and non-axisymmetric flows of thin fluid films over a spherical glass dome. A thin film is formed by raising a submerged dome through a silicone oil mixture composed of a volatile, low surface tension species (1 cSt, solvent) and a non-volatile species at a higher surface tension (5 cSt, initial solute volume fraction $\phi _0$). Evaporation of the 1 cSt silicone oil establishes a concentration gradient and, thus, a surface tension gradient that drives a Marangoni flow that leads to the formation of an initially axisymmetric mound. Experimentally, when $\phi _0 \leqslant 0.3\,\%$, the mound grows axisymmetrically for long times (Rodríguez-Hakim et al., Phys. Rev. Fluids, vol. 4, 2019, pp. 1–22), whereas when $\phi _0 \geqslant 0.35\,\%$, the mound discharges in a preferred direction, thereby breaking symmetry. Using lubrication theory and numerical solutions, we demonstrate that, under the right conditions, external disturbances can cause an imbalance between the Marangoni flow and the capillary flow, leading to symmetry breaking. In both experiments and simulations, we observe that (i) the apparent, most amplified disturbance has an azimuthal wavenumber of unity, and (ii) an enhanced Marangoni driving force (larger $\phi _0$) leads to an earlier onset of the instability. The linear stability analysis shows that capillarity and diffusion stabilize the system, while Marangoni driving forces contribute to the growth in the disturbances.

JFM classification

Interfacial Flows (free surface): Thin films Low-Reynolds-number flows: Lubrication theory
Type
JFM Papers
Information
Journal of Fluid Mechanics , Volume 915 , 25 May 2021 , A45
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Copyright
© The Author(s), 2021. Published by Cambridge University Press

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