Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-08T05:32:22.275Z Has data issue: false hasContentIssue false

A chemical reaction in a turbulent jet

Published online by Cambridge University Press:  12 April 2006

John R. Shea
Affiliation:
Department of Mechanics and Engineering Science, Air Force Institute of Technology, Wright-Patterson AFB, Ohio 45433

Abstract

This experimental investigation determines the effect of the various parameters of a subsonic axisymmetric jet upon a fast chemical reaction between ozone contained dilutely in the primary jet and diluted nitric oxide being entrained from the ambient fluid. Radial profiles of ozone densities are determined from absorption measurements of a thin beam of ultraviolet light which is probed across the jet. Data have been obtained for five jet Reynolds numbers between 4000 and 32 000 to reflect variations in both gas density and nozzle velocity; the data confirm Reynolds number independence of reactant concentration profiles to within experimental accuracy. When the non-dimensional chemical reaction rate exceeds a determined value, the ozone profiles are observed to be independent of further increases in the reaction speed. The measured ozone concentration profiles are related directly to the molecular-scale mixing in the jet and to mixing intermittency in the mixing zone in particular.

Type
Research Article
Copyright
© 1977 Cambridge University Press

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Alber, I. E. & Batt, R. G. 1974 An analysis of diffusion limited first and second order chemical reactions in a turbulent shear layer. A.I.A.A. 7th Fluid Plasma Dyn. Conf., Palo Alto. A.I.A.A. Paper no. 74–595.Google Scholar
Bradshaw, P., Ferriss, D. H. & Johnson, R. F. 1964 Turbulence in the noise-producing regions of a circular jet. J. Fluid Mech. 19, 591.Google Scholar
Davies, P. O. A. L., Fisher, M. & Barratt, M. 1963 The characteristics of the turbulence in the mixing region of a round jet. J. Fluid Mech. 15, 337.Google Scholar
Gibson, C. H. & Libby, P. A. 1972 On turbulent flows with fast chemical reactions. Part II. The distribution of reactants and products near a reacting surface. Combustion Sci. Tech. 6, 29.Google Scholar
Griggs, M. 1968 Absorption coefficients on ozone in the ultraviolet and visible regions. J. Chem. Phys. 49, 857.Google Scholar
Hawthorne, W. R., Weddell, D. S. & Hottel, H. C. 1949 Mixing and combustion in turbulent gas jets. 3rd Int. Symp. Combustion, p. 266.
Herron, J. T. & Hine, R. E. 1973 The reaction between NO and O3. J. Phys. Chem. Ref. Data 2, 292.Google Scholar
Hottel, H. C. 1952 Burning in laminar and turbulent fuel jets. 4th Int. Symp. Combustion, p. 97.
Hudson, R. D. 1971 Critical review of ultraviolet photoabsorption cross sections for molecules of astrophysical and aeronomic interest. Nat. Stand. Ref. Data Ser., Nat. Bur. Stand. 38, 306.Google Scholar
Johnston, H. S. & Crosby, H. J. 1951 Rapid gas phase reaction between NO and O3. J. Chem. Phys. 19, 799.Google Scholar
Johnston, H. S. & Crosby, H. J. 1954 Kinetics of fast gas phase reaction between O3 and NO. J. Chem. Phys. 22, 689.Google Scholar
Jones, E. J. & Wulf, O. R. 1937 The absorptive coefficient of nitrogen pentoxide in the ultraviolet and the visible absorption spectrum of NO3. J. Chem. Phys. 5, 873.Google Scholar
Kent, J. H. & Bilger, R. W. 1972 Turbulent diffusion flames. 14th Int. Symp. Combustion, p. 615.
Kuethe, A. 1935 Investigations of the turbulent mixing regions formed by jets. A.S.M.E. Trans. 2, A87.Google Scholar
Melvin, E. H. & Wulf, O. R. 1935 Ultraviolet absorption of mixtures of NO, NO2 and H2O. J. Chem. Phys. 3, 755.Google Scholar
Shea, J. R. 1976 A chemical reaction in a turbulent jet. Ph.D. thesis, California Institute of Technology.
Weddel, D. 1941 Turbulent mixing in gas flames. Ph.D. thesis, Massachusetts Institute of Technology.
Wohl, K., Gazley, C. & Kapp, N. 1949 Diffusion flames. 3rd Int. Symp. Combustion, p. 288.
Yagi, S. & Saji, K. 1952 Problems of turbulent diffusion and flame jets. 4th Int. Symp. Combustion, p. 771.