Hostname: page-component-cd9895bd7-gvvz8 Total loading time: 0 Render date: 2024-12-12T12:43:52.807Z Has data issue: false hasContentIssue false

Chemistry in Shocks

Published online by Cambridge University Press:  14 August 2015

T.W. Hartquist*
Affiliation:
Max-Planck-Institute for Physics and Astrophysics, Institute for Extraterrestrial Physics, 8046 Garching, Federal Republic of Germany

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The column densities of interstellar CH+, first detected about fifty years ago, cannot be explained with models of the chemistry in low temperature gas. The resolution of this classic problem is necessary for us to have confidence in our understanding of interstellar chemistry and its role in determining the physical conditions in interstellar clouds and in the utility of molecular abundance measurements as diagnostics. The possibility that the observed CH+ is formed primarily in shocks in diffuse clouds is addressed. The way in which the chemistry affects the structure of such a diffuse cloud shock is also discussed. The analogous chemical influence on the structures of shocks in dense molecular clouds is also considered as is the possibility that gas in some dense molecular clouds passes repeatedly through dynamical cycles and is shocked frequently enough to influence the global chemical structures in those clouds. Some atomic and molecular data needs are mentioned.

Type
Joint Discussions
Copyright
Copyright © Kluwer 1989

References

Charnley, S.B., Dyson, J.E., Hartquist, T.W., and Williams, D.A. (1988) ‘Chemical limit cycles for a region of low mass star formation’, M.N.R.A.S., in press.Google Scholar
Chernoff, D.F. and McKee, C.F. (1989) ‘Shocks in dense molecular clouds’, in Hartquist, T.W. (ed.), Molecular Astrophysics – A Volume Honouring Alexander Daigarno, Cambridge University Press, Cambridge, in press.Google Scholar
Danby, G., Flower, D.R., and Monteiro, T.S. (1987) ‘Rotationally inelastic collisions between H2 molecules in interstellar magnetohydrodynamical shocks’, M.N.R.A.S. 226, 739715.CrossRefGoogle Scholar
Draine, B.T. (1980) ‘Interstellar shock waves with magnetic precursors’, Ap. J. 241, 10211038.CrossRefGoogle Scholar
Draine, B.T. (1986) ‘Magnetohydrodynamic shocks in diffuse clouds – III. The line of sight towards ζOph’, Ap. J. 310, 408418.Google Scholar
Draine, B.T., Roberge, W.G., and Daigarno, A. (1983) ‘Magnetohydrodynamic shocks in molecular clouds’, Ap. J. 264, 485507.Google Scholar
Elitzur, M. and Watson, W.D. (1978) ‘Formation of molecular CH in Interstellar Shocks’, Ap. J. (Letters) 222, 141144.CrossRefGoogle Scholar
Elmegreen, B.G. (1979) ‘Magnetic diffusion and ionization fractions in dense molecular clouds: the role of charged grains’, Ap. J. 232, 729739.CrossRefGoogle Scholar
Flower, D.R., Pineau des Forêts, G., and Hartquist, T.W. (1985) ‘Theoretical studies of interstellar molecular shocks – I. General formulation and effects of the ion-molecule chemistry’, M.N.R.A.S. 216, 775794.CrossRefGoogle Scholar
Goldsmith, P.F., Langer, W.D., and Wilson, R.W. (1986) ‘Molecular outflows, gas density distribution, and the effects of star formation in the dark cloud Barnard 5’, Ap. J. (Letters) 303, 1115.CrossRefGoogle Scholar
Hartquist, T.W., Flower, D.R., and Pineau des Forêts, G. (1989) ‘Shock chemistry in diffuse clouds’, in Hartquist, T.W. (ed.), Molecular Astrophysics – A Volume Honouring Alexander Dalgarno, Cambridge University Press, Cambridge, in press.Google Scholar
Havnes, O., Hartquist, T.W., and Pilipp, W. (1987) ‘The effects of dust on the ionization structures and dynamics in magnetized clouds’ in Morfill, G.E. and Scholer, M. (eds.), Physical Processes in Interstellar Clouds, D. Reidel Publishing Company, Dordrecht, pp. 389412.Google Scholar
Kirby, K. (1980) ‘The photodissociation of interstellar CH+ ’ in Andrew, B.H. (ed.), Interstellar Molecules -IAU Symposium No. 87 D. Reidel Publishing Company, Dordrecht, pp. 283287.Google Scholar
Langer, W.D. (1989), ‘Observations of velocity and density structure in diffuse clouds’, in Hartquist, T.W. (ed.), Molecular Astrophysics – A Volume Honouring Alexander Dalgarno, Cambridge University Press, Cambridge, in press.Google Scholar
McKee, C.F. and Ostriker, J.P.A theory of the interstellar medium: Three components regulated by supernova explosions in an inhomogeneous substrateAp. J. 218, 148169.Google Scholar
Mullan, D.J. (1971) ‘The structure of transverse hydromagnetic shocks in regions of low ionization’, M.N.R.A.S. 153, 145170.CrossRefGoogle Scholar
Oppenheimer, M. and Dalgarno, A. (1974) ‘The fractional ionization in dense interstellar clouds’, Ap. J. 192, 2932.CrossRefGoogle Scholar
Pineau des Forêts, G., Flower, D.R., Hartquist, T.W., and Dalgarno, A. (1986) ‘Theoretical studies of interstellar molecular shocks – III. The formation of CH+ in diffuse cloudsM.N.R.A.S. 220, 801824.Google Scholar
Spitzer, L. (1978) Physical Processes in the Interstellar Medium, John Wiley & Sons, New York.Google Scholar
Williams, D.A. and Hartquist, T.W. (1984) ‘On C° and CO in dense interstellar clouds – evidence that cloud material is frequently shocked’, M.N.R.A.S. 210, 141145.CrossRefGoogle Scholar