The relationship between the supersaturation at the point of crystallization and the rate at which supersaturation increases has been studied from nucleation experiments on barite BaSO4, strontianite SrCO3, witherite BaCO3 and gypsum CaSO4.2H2O. The crystallization experiments have been carried out by the counter-diifusion of cations and anions through a column of porous silica gel transport medium. Nucleation is suppressed in a finely-porous medium resulting in very high values of supersaturation before crystallization from the solution begins. This threshold supersaturation for nucleation depends on the solubility of the salt, the porosity of the medium and the supersaturation rate. Nucleation inhibitors were used to extend the range of supersaturation attainable. In all cases the experimental data fits the general expression: rate of change of supersaturation ∝ (threshold supersaturation)m. These results are compared to previous work from the field of chemical engineering on the relationship between supersaturation, volume and cooling rate in aqueous salt solutions. These experiments have important implications to supersaturation in natural fluids and subsequent crystallization in relation to geological problems including crystallization in low temperature sedimentary environments and fluid-rock ratios in hydrothermal mineral deposits.

This paper is a revision of the standard chronostratigraphy of the Ordovician of the historical type area in England and Wales. The revision is a response to the need for more precise definitions of series and stages, especially for practical international correlation. In some cases this has entailed moving horizons for Series bases away from those in the classical sections. The scheme will be used as the standard for a forthcoming revision of the Correlation Chart of the British Ordovician System. The Ordovician is divided into five series: Tremadoc, Arenig, Llanvirn, Caradoc and Ashgill. The Llanvirn is extended to include part of the classical Llandeilo Series, which is included within it as a stage. Where stage subdivisions of standard series have not yet been defined, as in the Tremadoc, they are proposed in this paper. However, Bancroft’s fine stadial divisions of the Caradoc, which have been criticized for their brevity and local utility, are combined into four new stages, which will have wider application. The former Caradoc subdivisions are retained as substages for the purposes of regional correlation.

A 2-m-thick bed of sandstone and conglomerate in early Cretaceous desert sediments in the Andes of northern Chile contains thousands of scattered pterosaur bones. The bed displays sedimentary features which suggest that it was the product of a single major flood event. It seems possible that a large pterosaur colony was overwhelmed by the waters of an exceptional flood sweeping across a flat alluvial plain.

The Upper Allochthonous Thrust Complex (UATC) of the Bragança massif in northern Portugal contains a set of ultrabasic rocks interthrust with granulites. The ultrabasic rocks have refractory silicate mineral and whole rock compositions which indicate an origin as depleted mantle. Phase relationships of harzburgite samples suggest that they formed in equilibrium with high-Mg picritic melts created through a high degree of mantle partial melt extraction. Chromite in small podiform deposits has 100 Cr/(Cr + Al) ratios of 62–85, which are consistent with crystallization from such melts. Most of the chromite composition parameters are similar to those of ophiolite deposits except for the high ferric iron contents (2.77–8.95 wt% Fe2O3). Such enrichment is a feature of chromite from island arc magmas. It is suggested that the extensive partial melt extraction and chromite mineralization in the ultrabasic rocks occurred in the upper few kilometres of island arc mantle. The ultrabasic rocks were tectonically emplaced into a granulite and eclogite-bearing arc-continent collision complex during the Early Ordovician and subsequently, in the mid-Devonian emplaced over the Central-Iberian terrane.

The mid- to Upper Permian Radok Conglomerate, the lowermost formation of the Permo-Triassic Amery Group, crops out in the Beaver Lake area of the northern Prince Charles Mountains, East Antarctica. Outcrop is confined to a north-south elongate, fault-bounded corridor interpretedas a remnant of a continental extensional basin formed during Late Palaeozoic times. This basinforms a small part of the much larger Lambert Graben, a major continental rift system. The RadokConglomerate consists of interbedded conglomerates, argillaceous sandstones, siltstones, and minor, thin carbonaceous siltstones and coals. Textural, petrographic, palaeocurrent and other data suggestlocal derivation from Precambrian massifs to the immediate west, during a period of fault activity.The unit is a minimum of 400 m thick, the base being unexposed, and grossly fines upward. It isabruptly overlain by quartzo-feldspathic sandstone-dominated rocks of the Upper Permian Bainmedart Coal Measures. Seven recurrent lithofacies have been recognized with the Radok Conglomerate, and are interpreted as the products of poorly-confined stream flow, sheet flow and sediment gravity flow processes, suspension fallout in shallow standing water, and organic sediment accumulation in peat-forming wetlands. The unit as a whole is interpreted as having accumulated as a coarse alluvial apron along the western margin of a ?graben extensional trough. Similar, though poorly exposed, facies are exposed on the eastern margin of the basin and may reflect similar depositional systems. Towards the top of the Radok Conglomerate, typical Radok lithologies are interbedded with quartzo-feldspathic sandstones derived from the south, precursors of the overlying Bainmedart Coal Measures. Interference between transverse (Radok) and axial (Bainmedart) drainage is possibly related to progressive infilling of extensional topography, thereby allowing axially flowing rivers to avulse increasingly into the Beaver Lake region from the main Lambert Graben.

The palaeomagnetism of a Late Ordovician dolerite suite widely distributed in the northern Welsh Borderlands has been investigated to evaluate (i) regional rotations associated with later deformations and (ii) Lower Palaeozoic latitudes of Eastern Avalonia. Only local effects of Acadian and Variscan overprinting are observed in this region and most bodies appear to preserve a primary cooling-related magnetization. Magnetic properties in the Breidden Dolerite are related to primary igneous differentiation and a dual polarity characteristic remanence (D/I = 333.1/−71.6°, 6 sites, α95 = 10.4°) predates Late Ordovician folding. Dolerites elsewhere in the Breidden Hills Inlier record the same reversal of remanence and the combined mean (D/I = 314.3/−72.8°) is rotated clockwise from the mean remanence (D/I = 291.5/−59.5°, 21 sites, α95 = 6.0°) in a similar dolerite suite within the adjoining Shelve Inlier which is also of dual polarity and predates Late Ordovician folding. The difference in magnetic declinations is similar to the rotation of Late Ordovician fold axes and fracture systems between the two inliers and is probably the resultant effect of local rotation, possibly about a constraining bend in the Severn Valley Fault System. The Moel-y-Golfa Andesite of Caradocian (Soudleyan) age has a remanence (D/I = 294.3/−50.4°, 13 samples, α95 = 2.8°) which study of an adjoining volcanic conglomerate shows to be of primary cooling-related origin. The equivalent palaeolatitude is ˜ 31° S in early Caradocian times. A similar estimate is derived from a probable diagenetic overprint in the contemporaneous Castle Hill Conglomerate at Montgomery. The Mynydd-Bryn Andesite in the Berwyn Inlier, of probable similar origin and age to Moel-y-Golfa, has a magnetization of opposite polarity but similar inclination (D/I − 239.1/47.4°, 14 samples, α86 = 5.5°). Declination differences between these volcanic outcrops are a possible signature of later block rotations between the Lower Palaeozoic inliers and identify the importance of terrane definition in analysis of Lower Palaeozoic palaeomagnetic results from the Caledonides. A dolerite sheet complex at Hendre in the Berwyn Hills has a younger remanence (D/I − 182.3/ − 3.0°, 20 samples, α95 = 7.8°), probably of mid-Carboniferous age.

The collective Upper Ordovician results define a rapid movement of the Avalonian Plate, probably spanning no more than 10 Ma, from ˜ 30° S in early Caradocian times to ˜ 57° S prior to folding of the dolerites in late Caradocian to early Ashgill times. This motion into higher southerly palaeolatitudes marks a reversal of the motion of Avalonia into more shallow southerly palaeolatitudes between Arenig and Llanvirn times and shows that Ordovician closure of the Iapetus Ocean was more complex than recognized hitherto.

The Clarke Head fault megabreccia was produced within a major Late Palaeozoic transcurrent structure (the Minas fault system) which separates the displaced Meguma terrane of southern Nova Scotia from rocks more typical of the Avalon Superterrane. A large clast of anomalously high grade metabasite embedded in the clay matrix of the fault megabreccia displays a fresh granulite facies mineralogy (2-pyroxene + garnet + plagioclase) and mylonitic to ultramylonitic textures induced by anhydrous shearing deep in the roots of the fault zone. Whole rock geochemistry reveals the granulite protolith to have been a continental, within-plate mafic magma transitional between theoleiitic and alkaline. The original geochemical signature has survived strong dynamic recrystallization at granulite grade. Well-preserved REE abundances testify to a lack of metasomatic fractionation during high grade shearing under water-absent conditions. Sm—Nd data indicate that the basic granulite has a TDM age of c. 1 Ga. Isotopic comparisons with adjacent areas reveal similar TDM ages both north and south of the Minas fault system. The high grade clast may be typical of the lower crust in Nova Scotia and is thought to offer a rare window into the deep crust of the Avalon Superterrane in North America.

Structural mapping of the North West Mayo Inlier has investigated the kinematics of ductile fault and shear zones within the Dalradian and pre-Dalradian rocks. The area is characterized by an intense east to southeast trending elongation direction. Pre-Caledonian deformation is preserved as west-northwest trending sinistral mylonite zones. These are cross-cut by Grenville pegmatites and by undated mafic dykes. Subsequent deformation has been influenced by the majorbasement structures. During the Caledonian deformation, the pre-existing sinistral structures were reactivated coaxially as steep sinistral shear zones, deforming the mafic dykes. Major northwesterly verging thrusts are widespread in flat-lying zones which occur over much of the inlier. These are interpreted as D2 in age. The S2 fabric is the dominant fabric and contains an east to northeast trending mineral lineation. The southeastern part of the inlier is characterized by very large scale (wavelengths of kilometres) reclined D2 folding. This is interpreted as a crustal scale ramp zone. In the vicinity of this ramp there is evidence of earlier (F1) folds which are possibly the product of ramprelated deformation. All of these structures are interpreted as the product of northwest verging thrusting with crustal scale frontal and lateral ramps.

Recently published radiometric data show the duration of the Silurian Period to be approximately 32 Ma, significantly longer than previous estimates. Radiometric and graphic correlation studies demonstrate considerable variation in the durations of the four Silurian epochs: approximately 13 Ma for the Llandovery, 4 Ma for the Wenlock, 5 Ma for the Ludlow and 10 Ma for the Přídolí. Using this new geochronological data, figures for average graptolite zone duration are presented for each epoch, ranging from as little as 0.44 Ma in the Wenlock, to 1.43 Ma in the Přídolí. The figures provide a refined subdivision of the Silurian timescale, of value to studies which use Silurian graptolite zones to calibrate geological processes.

Phosphatized soft tissues are preserved in abundance in the trigoniids (Bivalvia) Laevitrigonia gibbosa and Myophorella incurva from the Portland Roach (Upper Jurassic) of Dorset. Cellular structures are preserved and fossilization is almost exclusively the result of a dense coating of mineralized microbes. Phosphatized soft tissues are restricted entirely to those trigoniids whose valves remained tightly closed after death. Only in these specimens was sufficient phosphorus concentrated by the decay of their most ‘labile’ soft tissues to trigger the precipitation of apatite in and around microbes infesting their more ‘refractory’ soft tissues. The absence of fossilized soft tissues in the rest of the fauna implies that phosphatization was very taxon-specific.