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Preservation of shell microstructure in silicified brachiopods from the Upper Cretaceous Wilmington Sands of Devon

Published online by Cambridge University Press:  01 May 2009

H. K. Holdaway  and
C. J. Clayton
H. K. Holdaway
Affiliation:
Department of GeologyUniversity of LondonKing's CollegeThe StrandLondon WC2R 2LS.
C. J. Clayton
Affiliation:
Department of GeologyUniversity of LondonKing's CollegeThe StrandLondon WC2R 2LS.
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Summary

From a study of silicified fossils, and in particular the microstructure of brachiopods, from the Wilmington Sands (Upper Cretaceous) of Devon, a model of skeletal silicification is proposed. Three distinct morphologies of silica were formed, controlled by the relative rates of silica supply and carbonate dissolution: (a) a fine-scale replacement of the original shell microstructure where silica was abundant; (b) a concentric ring morphology called ‘beekite’ where silica supply was limited, and (c) a granular white crust formed where carbonate dissolution was restricted. Silicification occurred during early diagenesis as a result of bacterial decay of organic matter intimately associated with skeletal fragments, within a sediment of restricted permeability. A build-up of CO2 probably caused dissolution of skeletal carbonate, and bicarbonate released from this caused local precipitation of silica. The proposed mechanism is belived to be of general applicability to micrite-rich carbonate sediments.

Type
Articles
Information
Geological Magazine , Volume 119 , Issue 4 , July 1982 , pp. 371 - 382
Copyright
Copyright © Cambridge University Press 1982

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