XIV. On Water as a Constituent of Salts. 1. In the case of Sulphates

Extract

It may be useful to distinguish some of the functions which water is already admitted to discharge in the constitution of hydrated salts.

Every amphigene ammoniacal salt contains an atom of water, and cannot exist without it. The state of combination of the water is peculiar, and has been represented by supposing that the elements of ammonia unite with the hydrogen of the water, and form a new compound radicle, to which the name Ammonium is given, while the oxygen of the water unites with this radicle, and produces oxide of ammonium. Hence nitrate of ammonia, in which there exist the elements of one atom of nitric acid, of ammonia, and of water, is viewed as anhydrous nitrate of the oxide of ammonium, and corresponds with nitre or the nitrate of the oxide of potassium. But it is not the object of this paper to discuss particularly the state of water in the ammoniacal salts.