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Zeolites in Mafic Pyroclastic Rocks from the Sandikli-Afyonkarahisar Region, Turkey

Published online by Cambridge University Press:  01 January 2024

Yahya Ozpinar ,
Baris Semiz  and
Paul A. Schroeder
Yahya Ozpinar
Affiliation:
Department of Geological Engineering, Pamukkale University, TR-20070, Denizli, Turkey
Baris Semiz*
Affiliation:
Department of Geological Engineering, Pamukkale University, TR-20070, Denizli, Turkey
Paul A. Schroeder
Affiliation:
Department of Geology, The University of Georgia, Athens, GA 30602-2501, USA
*
*E-mail address of corresponding author: [email protected]
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Abstract

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Geologic mapping and crystal-chemical analysis of Middle-Upper Miocene volcanics in the Sandıklı-Afyonkarahisar region of Turkey, coupled with published zeolite analyses has revealed that western Turkey hosts unique zeolitic mineral assemblages with distinct paragenetic sequences. The present investigation focused on pyroclastic deposits, including low to intermediate potassic trachytic/trachyandesitic tuffs (LPT) and high potassic tephriphonolitic, tephritic, and trachybasaltic tuffs (HPT), each of which contains various styles of zeolites. Optical petrography, X-ray powder diffraction, and chemical analyses have revealed varying degrees of lithification, probably related to differences in initial emplacement temperature, depositional mechanism and thickness, chilling rate, and extent of mafic composition. Zeolitization was further influenced by meteoric flushing in a hydrologically open system. Chabazite in the LPT from the Selçik area occurs extensively as coatings and infillings of pores. Phillipsite in the HPT found in the Ballık, Küfeke, and Ömerkuyu areas dominates the assemblage and is accompanied by chabazite and minor amounts of analcime. Analcime was probably generated by alteration of leucite which is found as a pyrogene mineral. Alkali zeolites or Ca-bearing zeolites formed as a consequence of the addition of Ca and/or the removal of Na (i.e. dissolution of analcime). The paragenetic sequence may be described as: analcime/phillipsite → chabazite → calcite. The characterization of these assemblages may lead to better exploitation strategies for natural zeolitic resources in the region.

Keywords

Alkaline Pyroclastic RocksChabazitePhillipsiteSandıklıWestern AnatoliaZeolites
Type
Research Article
Information
Clays and Clay Minerals , Volume 61 , Issue 3 , June 2013 , pp. 177 - 192
Copyright
Copyright © The Clay Minerals Society 2013

References

Abdioğlu, E., 2012 Mineralogy and chemistry of zeolites and associated minerals in Tertiary alkaline volcanics from the Eastern Pontides, NE Turkey Neues Jahrbuch für Mineralogie 189 35–47.CrossRefGoogle Scholar
Armstrong, J.T., 1988 Quantitative analysis of silicate and oxide materials: comparison of Monte Carlo, ZAF, and phirho-z procedures Microbeam Analysis 23 239–246.Google Scholar
Bernhard, F. and Barth-Wirsching, U., 2002 Zeolitization of a phonolitic ash flow by groundwater in the Laach volcanic area, Eifel, Germany Clays and Clay Minerals 50 710–725.CrossRefGoogle Scholar
Besang, C. Eckahtrdt, F.J. Harre, W. Kreuzer, H. and Müller, P., 1977 Radiometricshe Altersbesttimmungen der Türkei Jahrbuch der Geologischen Bundesanstalt 25 3–5.Google Scholar
Bish, D.L. and Carey, J.W., 2001 Thermal behavior of natural zeolites Natural Zeolites: Occurrence, Properties, Applications 45 403–452.CrossRefGoogle Scholar
Cappelletti, P. Cerri, G. Colella, A. de’ Gennaro, M. Langella, A. Perrotta, A. and Scarpati, C., 2003 Posteruptive processes in the Campanian Ignimbrite Mineralogy and Petrology 79 79–97.CrossRefGoogle Scholar
Chipera, S.J. and Apps, J.A., 2001 Geochemical stability of natural zeolites Natural Zeolites: Occurrence, Properties, Applications 45 117–161.CrossRefGoogle Scholar
de’Gennaro, M. Langella, A. Cappelletti, P. and Colella, C., 1999 Hydrothermal conversion of trachytic glass to zeolite. 3. Monocationic Model Glasses Clays and Clay Minerals 47 348–357.CrossRefGoogle Scholar
de’Gennaro, M. Cappelletti, P. Alangella, A. Perrotta, A. and Scarpati, C., 2000 Genesis of zeolites in the Neapolitan Yellow Tuff: Geological, volcanological and mineralogical evidence Contributions to Mineralogy and Petrology 139 17–35.CrossRefGoogle Scholar
Ercan, T., 1986 Orta Anadolu’daki Senozoyik Volkanizması MTA Dergisi 107 119–141.Google Scholar
Esenli, F. and Sirkecioglu, A., 2005 The relationship between zeolite (heulandite-clinoptilolite) content and the ammonium — exchange capacity of pyroclastic rocks in Gördes, Turkey Clay Minerals 40 557–564.CrossRefGoogle Scholar
Folk, 1962 Classification of carbonate rocks American Association of Petroleum Geologists Memoirs 1 62–82.Google Scholar
Francis, P.W. Roobol, M.J. Walker, G.P.I. Cobbold, P.R. and Coward, M., 1974 The San Pedro and San Pablo Volcanoes and their hot avalanche deposits Geologische Rundschau 63 357–388.CrossRefGoogle Scholar
Gottardi, G., 1989 The genesis of zeolites European Journal of Mineralogy 1 479–487.CrossRefGoogle Scholar
Gundogdu, M.N. Yalcin, H. Temel, A. and Clauer, N., 1996 Geological, mineralogical and geochemical characteristics of zeolite deposits associated with borates in the Bigadic Emet and Kirka Neogene lacustrine basins, western Turkey Mineralium Deposita 31 492–513.CrossRefGoogle Scholar
Hay, R.L., 1986 Geologic occurrence of zeolites and some associated minerals Pure and Applied Chemistry 58 1339–1342.CrossRefGoogle Scholar
Helvacı, C. Stamatakis, M.G. Zagouroglou, C. and Kanaris, J., 1993 Borate minerals and related authigenic silicates in northeastern Mediterranean late Miocene continental basins Exploration and Mining Geology 2 171–178.Google Scholar
Hernandez, J.E.G. Notario del Pino, J.S. Gonzalez Martin, M.M. Hernan Reguera, F. and Rodriguez Losada, J.A., 1993 Zeolites in pyroclastic deposits in southeastern Tenerife (Canary Islands) Clays and Clay Minerals 41 521–526.CrossRefGoogle Scholar
Ibrahim, K., 2004 Mineralogy and chemistry of natrolite from Jordan Clay Minerals 39 47–55.CrossRefGoogle Scholar
Iıjima, A. and Harada, K., 1969 Authigenic zeolites in zeolitic palagonite tuffs on Oahu, Hawaii American Mineralogist 54 182–198.Google Scholar
Kaçmaz, H. and Koktürk, U., 2004 Geochemistry and mineralogy of zeolitic tuffs from the Alacat. (Ceşme) area, Turkey Clays and Clay Minerals 52 705–713.CrossRefGoogle Scholar
Langella, A. Cappeletti, P. and de’Gennaro, M., 2001 Zeolites in closed hydrologic systems Natural Zeolites: Occurrence, Properties, Applications 45 235–260.CrossRefGoogle Scholar
Line, C.M.B. Putnis, A. Putnis, C. and Giampaolo, C., 1995 The dehydration kinetics and microtexture of analcime from two paragenesis American Mineralogist 80 268–279.CrossRefGoogle Scholar
Minato, H., No. 111 Committee, 1992 Investigation methods of zeolite Natural Zeolite and its Utilization Tokyo JSPS, Tokyo University Press 281–376.Google Scholar
Oba, T. and Yoshikawa, K., 1994 Note on rock-forming minerals in the Joetsu district, Niigata Prefecture, Japan. (7) Phillipsite from Yoneyama Bulletin Joetsu University of Education 13 399–406.Google Scholar
Özen, S. and Göncüoğlu, M.C., 2011 Origin of analcime in the Neogene Arıklı tuffs, Biga Peninsula, NW Turkey Neues Jahrbuch für Mineralogie 189/1 21–34.Google Scholar
Özpınar, Y., Çobanoğlu, I., and Bozkurt, R. (2002) Sandıklızeolitik tüflerin petrografik ve petrokimyasal ve teknolojik özelliklerinin incelenmesi, TÜBİTAK-YDABÇAĞ.-198Y102, Ankara, pp 268 (in Turkish).Google Scholar
Özpınar, Y., 2008 The mineralogic, petrographic and ion exchange capacity features of tuffs containing chabazite and phillipsite in Sandıklı (Afyon) region and their usage in agriculture (southwest Anatolia, Turkey) Bulletin of the Mineral Research and Exploration 137 29–48.Google Scholar
Özpınar, Y., 2011 Use of zeolitic tuffs as cement additives, building stone and removal of heavy metal cations Carpathian Journal of Earth and Environmental Science 6/1 147–158.Google Scholar
Putnis, A. Putnis, C. and Giampolo, C., 1994 The microtexture of analcime phenocrysts in igneous rocks European Journal of Mineralogy 6 627–632.CrossRefGoogle Scholar
Putnis, C.V. Geisler, T. Schmid-Beuermann, P. Stephan, T. and Giampaolo, C., 2007 An experimental study of the replacement of leucite by analcime American Mineralogist 92 19–26.CrossRefGoogle Scholar
Schmid, R., 1981 Descriptive nomenclature and classification of pyroclastic deposits and fragments: Recommendations of the IUGS Sub-commission on the Systematics of Igneous Rocks Geology 9 41–44.2.0.CO;2>CrossRefGoogle Scholar
Semiz, B. Schroeder, P.A. and Özpınar, Y., 2011 Zeolitization of Miocene tuffs the Saphane-Gediz-Hisarcık regions, Kutahya-western Anatolia, (Turkey) Euroclay 2011, Antalya, Turkey 232 pp..Google Scholar
Sheppard, R.A. and Hay, R.L., 2001 Formation of zeolites in open hydrologic systems Natural Zeolites: Occurrence, Properties, Applications 45 261–271.CrossRefGoogle Scholar
Sheppard, R.A. Gude, A.J.3rd Griffin, J.J., 1970 Chemical composition and physical properties of phillipsite from the Pacific and Indian Oceans American Mineralogist 55 2053–2062.Google Scholar
Snellings, R. van Haten, T. Machiels, L. Mertens, G. Vandenberghe, N. and Elsen, J., 2008 Mineralogy, geochemistry and diagenesis of clinoptilolite tuffs (Miocene) in the central Simav graben, Western Turkey Clays and Clay Minerals 56 622–632.CrossRefGoogle Scholar
Tschernich, R.W., 1992 Zeolites of the World Phoenix, Arizona, USA Geoscience Press.Google Scholar
Weisenberger, T. and Spürgın, S., 2009 Zeolites in alkaline rocks of the Kaiserstuhl volcanic complex, SW Germany, new microprobe investigation and the relationship of zeolite mineralogy to the host rock Geologica Belgica 12 75–91.Google Scholar
Winchester, J.A. and Floyd, P.A., 1977 Geochemical magma type discrimination: application to altered and metamorphosed basic igneous rocks Earth and Planetary Science Letters 28 257–272.Google Scholar