Hostname: page-component-cd9895bd7-gxg78 Total loading time: 0 Render date: 2024-12-18T10:11:34.209Z Has data issue: false hasContentIssue false
  • English
  • Français

X-Ray Photoelectron Spectroscopic Study of Cobalt(II) and Nickel(II) Sorbed on Hectorite and Montmorillonite

Published online by Cambridge University Press:  02 April 2024

Nigel Davison ,
William R. McWhinnie  and
Alan Hooper
Nigel Davison
Affiliation:
Department of Chemical Engineering and Applied Chemistry, Aston University, Aston Triangle, Birmingham B4 7ET, United Kingdom
William R. McWhinnie
Affiliation:
Department of Chemical Engineering and Applied Chemistry, Aston University, Aston Triangle, Birmingham B4 7ET, United Kingdom
Alan Hooper
Affiliation:
Central Electricity Generating Board Technology, Planning and Research Division, Berkley Nuclear Laboratories, Berkley, Gloucestershire GL13 9PB, United Kingdom
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The safe disposal of 60Co, 63Ni, and 59Ni has required considerable information on the interactions of Co2+ and Ni2+ with clay minerals in the geosphere. X-ray photoelectron spectroscopy (XPS) has been used to probe the sorption sites for Co2+ and Ni2+ on hectorite and montmorillonite. The spectra were measured for Co-hectorite, Ni-hectorite, and Ni-montmorillonite immediately following ion exchange and after washing the clay two and five times with distilled water. The spectra, recorded following etching of the surface with an argon ion beam, differentiate two sorption sites; a labile (to washing) fraction sorbed as ion pairs, and a non-labile fraction sorbed by ion exchange at broken bond and interlamellar sites. The data were consistent with the sorption of metal ions (Co2+, Ni2+) in a common “MO6” ligand environment.

Co2+ had a greater affinity for exchange on hectorite than did Ni2+; but Ni2+ had a greater affinity for the surface of montmorillonite than for hectorite. The argon ion etching of Ni-montmorillonite gave rise to a new photopeak of 853 eV, which was probably due to elemental Ni formed consequent to the chemical violation of the surface by ion etching.

Keywords

Cation exchangeCobaltHectoriteLigand exchangeMontmorilloniteNickelX-ray photoelectron spectroscopy
Type
Research Article
Information
Clays and Clay Minerals , Volume 39 , Issue 1 , February 1991 , pp. 22 - 27
Copyright
Copyright © 1991, The Clay Minerals Society

References

Adams, J. M., Thomas, J. M. and Walters, M. J., 1975 The surface and intercalate chemistry of the layered silicates. Part IV. Crystallographic, electron-spectroscopic and kinetic studies of the sodium montmorillonite-pyridine system J. Chem. Soc. Dalton Trans. 112 – 115.CrossRefGoogle Scholar
Adams, J. M., Evans, S., Reid, P. I., Thomas, J. M. and Walters, M. J., 1977 Quantitative analysis of alumino-silicates and other solids by X-ray photoelectron spectroscopy Anal. Chem. 49 2001 – 2008.CrossRefGoogle Scholar
Baes, C. F. and Messmer, R. E., 1976 The Hydrolysis of Cations 96.Google Scholar
Banin, A., 1968 Ion exchange isotherms of montmorillonite and structural factors affecting them Israel J. Chem. 6 27 – 36.CrossRefGoogle Scholar
Brown, G., Brindley, G. W., Brindley, G. W. and Brown, G., 1980 X-ray identification procedures for clay mineral identification Crystal Structures of Clay Minerals and their X-ray Identification London Mineralogical Society 305 – 360.CrossRefGoogle Scholar
Davison, N., 1987 The geochemistry of radioactive waste disposal Birmingham, United Kingdom Aston University.Google Scholar
Davison, N. and McWhinnie, W. R., 1990 The formation of cobalt and nickel complexes on clay surfaces Polyhedron 9 2273 – 2283.CrossRefGoogle Scholar
Defosse, C. and Rouxhet, P. G., 1980 Advanced chemical methods for soil and clay minerals research. Introduction to X-ray photo electron spectroscopy NATO Adv. Study Int. Ser. Ser. C. 63 169 – 203.Google Scholar
Dillard, J. G. and Koppleman, M. H., 1982 X-ray photoelectron spectroscopic surface characterisation of cobalt on the surface of kaolinite J. Coll. Int. Sci. 87 46 – 55.CrossRefGoogle Scholar
Dillard, J. G., Koppelman, M. H., Crowther, D. L., Schenk, C. V., Murray, J. W. and Ballisteri, L., 1980 X-ray photoelectron spectroscopic studies on the chemical nature of metal ions adsorbed on clays and minerals Adsorpt. Aqueous Solutions, Proc. Symp. Houston 227 – 240.CrossRefGoogle Scholar
Egozy, Y., 1980 Adsorption of cadmium and cobalt on montmorillonite as a function of solution composition Clays & Clay Minerals 28 311 – 318.CrossRefGoogle Scholar
Evans, S., Pritchard, R. G. and Thomas, J. M., 1977 Escape depths of X-ray (MgKα)-induced photo electrons and negative photoionization cross sections for the 3p sub-shell of elements of the first long period J. Phys. C., Solid State Phys. 10 2483 – 2498.CrossRefGoogle Scholar
Hall, P. L. and Astill, D. M., 1989 Adsorption of water by homoionic exchange forms of Wyoming montmorillonite (SWy-1) Clays & Clay Minerals 37 355 – 363.CrossRefGoogle Scholar
Kim, K. S., Baitinger, W. E., Amy, J. W. and Winograd, N., 1974 ESCA studies of metal oxygen surfaces using argon and oxygen ion bombardment J. Electron Spectrosc. Related Phenom. 351 – 367.CrossRefGoogle Scholar
Koppelman, M.H. Dillard, J. G. and Church, T. M., 1975 An ESCA study of sorbed metal ions on clay minerals Marine Chemistry in the Coastal Environment 186 – 201.CrossRefGoogle Scholar
Koppelmann, M. H. and Dillard, J. G., 1977 A study of the adsorption of Cu(II) and Ni(II) by clay minerals Clays & Clay Minerals 25 457 – 462.CrossRefGoogle Scholar
Koppelmann, M. H. and Dillard, J. G., 1978 An XPS study of Co adsorbed on the clay mineral chlorite J. Coll. Int. Sci. 66 345 – 351.CrossRefGoogle Scholar
Maes, A. and Cremers, A., 1975 Cation-exchange hysteresis in montmorillonite: a pH dependent effect Soil Sci. 119 198 – 202.CrossRefGoogle Scholar
Mackenzie, R. C. and Mackenzie, R. C., 1957 Thermal Methods The Investigation of Clays London Mineralogical Society 1 – 22.Google Scholar
Mandair, A-P S Michael, P. J. and McWhinnie, W. R., 1990 29Si MASNMR investigations of the thermo-chemistry of Laponite and hectorite Polyhedron 9 517 – 525.CrossRefGoogle Scholar
Matienzo, L. J., Yiu, L. T., Grim, S. O. and Schwartz, W. E. Jr., 1973 X-ray photoelectron spectroscopy of nickel compounds Inorg. Chem. 12 2762 – 2769.CrossRefGoogle Scholar
McFeely, F. R., Kowalczyk, S. P., Ley, L., Pollack, R. A. and Shirley, D. A., 1973 High-resolution X-ray photo emission spectra of PbS, PbSe and PbTe valence bands Phys. Rev. 137 5228 – 5237.CrossRefGoogle Scholar
McIntyre, N. S. and Cook, M. G., 1975 Cation exchange hysteresis in montmorillonite: A pH dependent effect Soil Sci. 119 198 – 202.Google Scholar
Michael, P. J. and McWhinnie, W. R., 1989 Mössbauer and ESR studies of the thermochemistry of illite and montmorillonite Polyhedron 8 2709 – 2718.CrossRefGoogle Scholar
Monsef-Mirzai, P., 1980 Geochemical aspects of waste disposal Birmingham, United Kingdom Aston University 96 – 131.Google Scholar
Nicholls, D., 1983 Complexes of First Row Transmission Elements London Macmillan 73 – 99.Google Scholar
Peigneur, P., Maes, A. and Grimes, A., 1975 Heterogeneity of charge distribution in montmorillonite as inferred from cobalt adsorption Clays & Clay Minerals 23 71 – 75.CrossRefGoogle Scholar
Posner, A. M. and Quirk, J. P., 1964 Adsorption of water from concentrated electrolyte solutions by montmorillonite and illite Proc. Roy. Soc. London, Ser. A. 278 35 – 56.Google Scholar
Seyama, H. and Soma, M., 1984 XPS study of montmorillonite containing exchangeable divalent cations J. Chem. Soc. Faraday Trans. I 80 237 – 248.CrossRefGoogle Scholar
Tolman, C. A., Riggs, W. H., Lin, W. J., King, C. M. and Wendt, R. C., 1973 Electron spectroscopy for chemical analysis of nickel compounds Inorg. Chem. 12 2770 – 2777.CrossRefGoogle Scholar