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Weathering sequences of clay minerals in soils along a serpentinitic toposequence

Published online by Cambridge University Press:  01 January 2024

Z. Y. Hseu ,
H. Tsai ,
H. C. Hsi  and
Y. C. Chen
Z. Y. Hseu*
Affiliation:
Department of Environmental Science and Engineering, National Pingtung University of Science and Technology, Nei-Pu, Pingtung 912-01, Taiwan
H. Tsai
Affiliation:
Department of Geography, National Changhua University of Education, Changhua 50018, Taiwan
H. C. Hsi
Affiliation:
Department of Safety, Health and Environmental Engineering, National Kaohsiung University of Science and Technology, Kaohsiung 811, Taiwan
Y. C. Chen
Affiliation:
Department of Environmental Science and Engineering, National Pingtung University of Science and Technology, Nei-Pu, Pingtung 912-01, Taiwan
*
*E-mail address of corresponding author: [email protected]
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Abstract

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There has been limited research on clay mineral transformation in serpentinitic soils under humid tropical conditions. In this study, four soil pedons were selected along a toposequence from the summit (Entisol), shoulder (Vertisol), backslope (Alfisol) to footslope (Ultisol) positions to explore the contributions and the significance of landscape and weathering status of serpentinitic rock with regard to clay mineral transformations in eastern Taiwan. Experimental results indicated that the large amount of dithionite-citrate-bicarbonate-extractable Fe (Fed) and clay in the subsurface horizon were mainly caused by the strong leaching potential from intensive rainfall and weathering of the fine-grained parent rocks. The clay mineralogy reflected the clear weathering trend of the soils along the toposequence: (1) the soils on the summit and shoulder contained smectite and serpentine, which are predominant in the young soils derived from serpentinitic rocks; and (2) vermiculite gradually increased in the relatively old soils on backslope and footslope. The mineralogical transformations observed along the toposequence indicated that chlorite and serpentine, initially present in the Entisol on the summit, weather into smectite and interstratified chlorite-vermiculite in the intermediate soil on the shoulder under strong leaching and oxidizing conditions. Furthermore, vermiculite formed as the major weathering product of chlorite and smectite in the soil developed on the backslope. In addition to vermiculite, kaolinite and quartz formed in the soils on the footslope with the greatest concentration of Fed along the toposequence.

Keywords

ChloriteSerpentineSmectiteSoil TaxonomyTaiwanToposequenceWeathering Sequence
Type
Research Article
Information
Clays and Clay Minerals , Volume 55 , Issue 4 , August 2007 , pp. 389 - 401
Copyright
Copyright © 2007, The Clay Minerals Society

References

Alexander, E.B., (1988) Morphology, fertility and classification of productive soils on serpentinised peridotite in California, U.S.A Geoderma 41 337–351 10.1016/0016-7061(88)90069-9.CrossRefGoogle Scholar
Alexander, E.B. Adamson, C. Graham, R.C. and Zinke, P.J., (1989) Soils and conifer forest productivity on serpentinized peridotite of the trinity ophiolite, California Soil Science 148 412–423 10.1097/00010694-198912000-00003.CrossRefGoogle Scholar
Aspandiar, M.F. and Eggleton, R.A., (2002) Weathering of chlorite: I. Reactions and products in microsystems controlled by the primary mineral Clays and Clay Minerals 50 685–698 10.1346/000986002762090227.CrossRefGoogle Scholar
Aspandiar, M.F. and Eggleton, R.A., (2002) Weathering of chlorite: II. Reactions and products in microsystems controlled by solution avenues Clays and Clay Minerals 50 699–709 10.1346/000986002762090100.CrossRefGoogle Scholar
Becquer, T. Rotte-Capet, S. Ghanbaja, J. Mustin, C. and Herbillon, A.J., (2006) Sources of trace metals in Ferralsols in New Caledonia European Journal of Soil Science 57 200–213 10.1111/j.1365-2389.2005.00730.x.CrossRefGoogle Scholar
Bonifacio, E. Zanini, E. Boero, V. and Franchini-Angela, M., (1997) Pedogenesis in a soil catena on serpentinite in northwestern Italy Geoderma 75 33–51 10.1016/S0016-7061(96)00076-6.CrossRefGoogle Scholar
Borchardt, G., Dixon, J.B. and Weed, S.B., (1989) Smectites Minerals in Soil Environments 2nd Madison, Wisconsin Soil Science Society of America 675–727.Google Scholar
Bullock, P. Fedoroff, N. Jongerius, A. Stoops, G. and Tursina, T., (1985) Handbook for Thin Section Description Albrighton, England Waine Research Publishers 152 pp.Google Scholar
Bulmer, C.E. and Lavkulich, L.M., (1994) Pedogenic and geochemical processes of ultramafic soils along a climatic gradient in southwestern British Columbia Canadian Journal of Soil Science 74 165–177 10.4141/cjss94-024.CrossRefGoogle Scholar
Burt, R. Fillmore, M. Wilson, M.A. Gross, E.R. Langridge, R.W. and Lammers, D.A., (2001) Soil properties of selected pedons on ultramafic rocks in Klamath Mountains, Oregon Communications in Soil Science and Plant Analysis 32 2145–2175 10.1081/CSS-120000275.CrossRefGoogle Scholar
Caillaud, J. Proust, D. Righi, D. and Martin, F., (2004) Fe-rich clays in a weathering profile developed from serpentinite Clays and Clay Minerals 52 779–791 10.1346/CCMN.2004.05206013.CrossRefGoogle Scholar
Caillaud, J. Proust, D. and Righi, D., (2006) Weathering sequences of rock-forming minerals in a serpentinite: influence of microsystems on clay mineralogy Clays and Clay Minerals 54 87–100 10.1346/CCMN.2006.0540111.CrossRefGoogle Scholar
Cheshire, M. and Güven, N., (2005) Conversion of chrysotile to a magnesian smectite Clays and Clay Minerals 53 155–161 10.1346/CCMN.2005.0530205.CrossRefGoogle Scholar
Dirven, J.M.C. van Schuylenborch, J. and van Breemen, N., (1976) Weathering of serpentinite in Matanzas Province, Cuba: Mass transfer calculations and irreversible reaction pathways Soil Science Society of America Journal 40 901–907 10.2136/sssaj1976.03615995004000060029x.CrossRefGoogle Scholar
Dixon, J.B., Dixon, J.B. and Weed, S.B., (1989) Kaolin and serpentine group minerals Minerals in Soil Environments Madision, Wisconsin Soil Science Society of America 467–526.CrossRefGoogle Scholar
Garnier, J. Quantin, C. Martins, E.s. and Becquer, T., (2006) Solid speciation and availability of chromium in ultramafic soils from Niquelândia, Brazil Journal of Geochemical Exploration 88 206–209 10.1016/j.gexplo.2005.08.040.CrossRefGoogle Scholar
Gee, G.W. Bauder, J.W., Page, A.L. Miller, R.H. and Keeney, D.R., (1986) Particle-size analysis Methods of Soil Analysis 2nd Madison, Wisconsin American Society of Agronomy and Soil Science Society of America 383–411 Part 1.Google Scholar
Golighty, J.P., (1981) Nickeliferous laterite deposits Economic Geology 75 710–735.Google Scholar
Graham, R.C. Diallo, M.M. and Lund, L.J., (1990) Soils and mineral weathering on phyllite colluviun and serpentinite in northwestern California Soil Science Society of America Journal 54 1682–1690 10.2136/sssaj1990.03615995005400060030x.CrossRefGoogle Scholar
Gunal, H. and Ransom, M.D., (2006) Genesis and micromorphology of loess-derived soils from central Kansas Catena 65 222–236 10.1016/j.catena.2005.11.018.CrossRefGoogle Scholar
Hamblin, W.K., (1992) Earth’s Dynamic Systems 6 New York Macmillan Publishers 647 pp.Google Scholar
Heystek, H., (1956) Vermiculite as a member in mixed-layer minerals Clays and Clay Minerals 4 429–434 10.1346/CCMN.1955.0040148.CrossRefGoogle Scholar
Ho, C.S., (1988) An Introduction to the Gof Taiwan: Explanatory Text of the Geologic Map of Taiwan 2nd Taipei, Taiwan Centenary Geological Survey 192 pp.Google Scholar
Hseu, Z.Y., (2006) Concentration and distribution of chromium and nickel fractions along a serpentinitic toposequence Soil Science 171 341–353 10.1097/01.ss.0000209354.68783.f3.CrossRefGoogle Scholar
Istok, J.D. and Harward, M.E., (1982) Influence of soil moisture on smectite formation in soils derived from serpentinite Soil Science Society of America Journal 46 1106–1108 10.2136/sssaj1982.03615995004600050046x.CrossRefGoogle Scholar
Johns, W.D. Grim, R.E. and Bradley, W.F., (1954) Quantitative estimations of clay minerals by diffraction methods Journal of Sedimentary Petrology 24 242–251.Google Scholar
Kahle, M. Kleber, M. and Jahn, R., (2002) Review of XRD-based quantitative analyses of clay minerals in soils: the suitability of mineral intensity factors Geoderma 109 191–205 10.1016/S0016-7061(02)00175-1.CrossRefGoogle Scholar
Langley-Turnbaugh, S.J. and Bockheim, J.G., (1997) Time-dependent changes in pedogenic processes on marine terraces in coastal Oregon Soil Science Society of America Journal 61 1428–1440 10.2136/sssaj1997.03615995006100050022x.CrossRefGoogle Scholar
Lee, B.D. Sears, S.K. Graham, R.C. Amrhein, C. and Vali, H., (2003) Secondary mineral genesis from chlorite and serpentine in an ultramafic soil toposequence Soil Science Society of America Journal 67 1309–1317 10.2136/sssaj2003.1309.CrossRefGoogle Scholar
Lee, B.D. Graham, R.C. Laurent, T.E. and Amrhein, C., (2004) Pedogenesis in a wetland meadow and surrounding serpentinitic landslide terrain, northern California, USA Geoderma 118 303–320 10.1016/S0016-7061(03)00214-3.CrossRefGoogle Scholar
Massoura, S.T. Echevarria, G. Becquer, T. Ghanbaja, J. Leclerc-Cessac, E. and Morel, J., (2006) Control of nickel availability by nickel bearing minerals in natural and anthropogenic soils Geoderma 136 28–37 10.1016/j.geoderma.2006.01.008.CrossRefGoogle Scholar
McLean, E.O., Page, A.L. Miller, R.H. and Keeney, D.R., (1982) Soil pH and lime requirement Methods of Soil Analysis, Part 2, Chemical and Microbiological Properties 2nd Madison, Wisconsin American Society of Agronomy and Soil Science Society of America 199–224.Google Scholar
Mehra, O.P. and Jackson, M.J., (1960) Iron oxides removed from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate Clays and Clay Minerals 7 317–327 10.1346/CCMN.1958.0070122.CrossRefGoogle Scholar
Nelson, D.W. Sommers, L.E., Page, A.L. Miller, R.H. and Keeney, D.R., (1982) Total carbon, OC and organic matter Methods of Soil Analysis, Part 2, Chemical and Microbiological Properties 2nd Madison, Wisconsin American Society of Agronomy and Soil Science Society of America 539–557.Google Scholar
Nesse, W.D., (2000) Sheet silicates Introduction to Mineralogy New York Oxford University Press 235–260.Google Scholar
Rabenhorst, M.C. Foss, J.E. and Fanning, D.S., (1982) Genesis of Maryland soils formed from serpentinite Soil Science Society of America Journal 46 607–616 10.2136/sssaj1982.03615995004600030032x.CrossRefGoogle Scholar
Rhoades, J.D., Page, A.L. Miller, R.H. and Keeney, D.R., (1982) Cation exchange capacity Methods of Soil Analysis, Part 2, Chemical and Microbiological Properties 2nd Madison, Wisconsin American Society of Agronomy and Soil Science Society of America 149–157.Google Scholar
Sawhney, B.L., Dixon, J.B. and Weed, S.B., (1989) Interstratification in layer silicates Minerals in Soil Environments 2nd Madision, Wisconsin Soil Science Society of America 789–828.Google Scholar
Schreier, H. Omueti, J.A. and Lavkulich, L.M., (1987) Weathering processes of asbestos-rich serpentinitic sediments Soil Science Society of America Journal 51 993–999 10.2136/sssaj1987.03615995005100040032x.CrossRefGoogle Scholar
Simonson, R.W., (1995) Airborne dust and its significance to soils Geoderma 65 1–43 10.1016/0016-7061(94)00031-5.CrossRefGoogle Scholar
Soil Survey Staff, Keys to Soil Taxonomy (2006) 10 Washington, D.C. Natural Resources Conversation Services, United States Department of Agriculture 332 pp.Google Scholar
Weaver, C.E., (1956) The distribution and identification of mixed-layer clays in sedimentary rocks American Mineralogists 41 202–221.Google Scholar
Whittaker, R.H., (1954) The ecology of serpentine soils. IV. The vegetation response to serpentine soils Ecology 35 275–288 10.2307/1931126.Google Scholar
Wildman, W.E. Jackson, M.L. and Whittig, L.D., (1968) Iron-rich montmorillonite formation in soils derived from serpentinite Soil Science Society of America Proceedings 32 787–794 10.2136/sssaj1968.03615995003200060025x.CrossRefGoogle Scholar
Wilson, M.J. and Berrow, M.L., (1978) The mineralogy and heavy metal content of some serpentinite soils in northeast Scotland Chemie der Erde 37 181–205.Google Scholar