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Visible Spectroscopy of Cationic Dyes in Dispersions with Reduced-Charge Montmorillonites

Published online by Cambridge University Press:  01 January 2024

Juraj Bujdák  and
Nobuo Iyi
Juraj Bujdák*
Affiliation:
Institute of Inorganic Chemistry, Slovak Academy of Sciences, SK-842 36 Bratislava, Slovakia
Nobuo Iyi
Affiliation:
National Institute for Materials Science, Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan
*
*E-mail address of corresponding author: [email protected]
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Abstract

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The aggregation behavior of one azine and three triphenylmethane cationic dyes in dispersions of reduced-charge montmorillonites (RCMs) was investigated. The extent and types of dye aggregation were monitored using visible spectroscopy. Similar relationships between dye aggregation and layer charge were observed, independent of the structure of the dye cations. High charge-density surfaces induced the formation of H-aggregates, with a face-to-face association between the dye cations that then absorb light at relatively lower wavelengths. Moderate reductions in layer charge were reflected in the lowering of the H-aggregation in favor of monomers, dimers and less densely-packed J-aggregates, absorbing light at higher wavelengths. Dye spectra in the presence of the lowest-charge RCMs resembled those of dilute dye solutions, indicating the absence of dye aggregation of any type in this case. The relationship between dye spectral changes and layer-charge densities of smectites is a general phenomenon which can potentially be used to estimate the layer charge of smectites. However, applying this method to triphenylmethane dyes, which have structurally more complicated cations, may reduce the sensitivity of the probe.

Keywords

Cationic DyesDye AggregatesLayer-Charge DensityMontmorillonite
Type
Research Article
Information
Clays and Clay Minerals , Volume 50 , Issue 4 , August 2002 , pp. 446 - 454
Copyright
Copyright © 2002, The Clay Minerals Society

References

Antonov, L. Gerkov, G. Petrov, V. Kubista, M. and Nygren, J., (1999) UV-Vis spectroscopic and chemometric study on the aggregation of ionic dyes in water Talanta 49 99–106 10.1016/S0039-9140(98)00348-8.CrossRefGoogle Scholar
Bergman, K. and O’Konski, C.T., (1963) A spectroscopic study of methylene blue monomer, dimer and complexes with montmorillonite Journal of Physical Chemistry 67 2169–2177 10.1021/j100804a048.CrossRefGoogle Scholar
Bose, H., (1987) Environmental effects on dye aggregation/effect of electrolytes on metachromasy of thiazine dyes Indian Journal of Chemistry, Section A 26 652 655.Google Scholar
Braswell, E.H. and Lary, J., (1981) Equilibrium-sedimentation studies of some self-associating cationic dyes Journal of Physical Chemistry 85 1573–1578 10.1021/j150611a023.CrossRefGoogle Scholar
Breen, C. and Loughlin, H., (1994) The competitive adsorption of methylene blue onto Na-montmorillonite from binary solution with n-alkyltrimethylammonium surfactants Clay Minerals 29 775 783.CrossRefGoogle Scholar
Bujdak, J. and Komadel, P., (1997) Interaction of methylene blue with reduced charge montmorillonite Journal of Physical Chemistry, B 101 9065–9068 10.1021/jp9718515.CrossRefGoogle Scholar
Bujdak, J. Janek, M. Madejová, J. and Komadel, P., (1998) Influence of the layer charge density of smectites on the interaction with methylene blue Journal of the Chemical Society, Faraday Transaction 94 3487–3492 10.1039/a805341c.CrossRefGoogle Scholar
Bujdák, J. Hackett, E. and Giannelis, E.P., (2000) Effect of layer charge on the intercalation of poly (ethylene oxide) in layered silicates: Implications on nanocomposite polymer electrolytes Chemistry of Materials 12 2168–2174 10.1021/cm990677p.CrossRefGoogle Scholar
Bujdák, J. Janek, M. Madejová, J. and Komadel, P., (2001) Methylene blue interactions with reduced-charge smectites Clays and Clay Minerals 49 244–254 10.1346/CCMN.2001.0490307.CrossRefGoogle Scholar
Bujdák, J. Iyi, N. and Fujita, T., (2002) The aggregation of methylene blue in montmorillonite dispersions Clay Minerals 37 121–133 10.1180/0009855023710022.CrossRefGoogle Scholar
Campbell, D.J. Higgins, D.A. and Corn, R.M., (1990) Molecular second harmonic generation studies of methylene blue chemisorbed onto sulfur-modified polycrystalline platinum electrode Journal of Physical Chemistry 94 3681–3689 10.1021/j100372a060.CrossRefGoogle Scholar
Cenens, J. and Schoonheydt, R.A., (1988) Visible spectroscopy of methylene blue on hectorite, Laponite B and Barasym in aqueous suspensions Clays and Clay Minerals 36 214–224 10.1346/CCMN.1988.0360302.CrossRefGoogle Scholar
Chernia, Z. Gill, D. and Yariv, S., (1994) Electric dichroism. The effect of dialysis on the color of crystal violet adsorbed to montmorillonite Langmuir 10 3988–3993 10.1021/la00023a015.CrossRefGoogle Scholar
Clark, F.T. and Drickamer, H.G., (1984) The effect of pressure on the adsorption of crystal violet on oriented ZnO crystals Journal of Physical Chemistry 84 1024–1029 10.1063/1.447738.CrossRefGoogle Scholar
Cohen, R. and Yariv, S., (1984) Metachromasy in clay minerals Journal of the Chemical Society, Faraday Transaction 1 80 1705–1715 10.1039/f19848001705.CrossRefGoogle Scholar
Coine, A.P.P. Neumann, M.G. and Gessner, F., (1998) Time-dependent spectrophotometric study of the interaction of basic dyes with clays Journal of Colloid and Interface Science 198 106–112 10.1006/jcis.1997.5268.Google Scholar
del Monte, F. and Levy, D., (1999) Identification of oblique and coplanar inclined fluorescent J-dimers in rhodamine 110 doped sol-gel-glasses Journal of Physical Chemistry B 103 8080–8086 10.1021/jp991491g.CrossRefGoogle Scholar
Fischer, D. Caseri, W.R. and Hahner, G., (1998) Orientation and electronic structure of ion exchanged dye molecules on mica. An X-ray absorption study Journal of Colloid and Interface Science 198 337–346 10.1006/jcis.1997.5296.CrossRefGoogle Scholar
Garfinkel-Shweky, D. and Yariv, S., (1997) Metachromasy in clay-dye systems: the adsorption of acridine orange by Nasaponite Clay Minerals 32 653–663 10.1180/claymin.1997.032.4.15.CrossRefGoogle Scholar
Garfinkel-Shweky, D. and Yariv, S., (1997) The determination of surface basicity of the oxygen planes of expanding clay minerals by acridine orange Journal of Colloid and Interface Science 188 168–175 10.1006/jcis.1996.4712.CrossRefGoogle Scholar
Garfinkel-Shwenky, D. and Yariv, S., (1999) Metachromasy in clay-dye systems: the adsorption of acridine orange by Nabeidellite Clay Minerals 34 459–467 10.1180/000985599546361.CrossRefGoogle Scholar
Hachisako, H. Yamazaki, T. Ihara, H. Hirayama, C.h. and Yamada, K., (1994) Recognition of molecular planarity of cationic dyes by anionic, crystalline bilayer aggregates. Evidence using metachromic and solvatochromic properties Journal of the Chemical Society, Perkin Transactions 2 7 1681–1690 10.1039/p29940001681.CrossRefGoogle Scholar
Hähner, G. Marti, A. Spencer, N.D. and Caseri, W.R., (1996) Orientation and electronic structure of methylene blue on mica: A near edge X-ray absorption structure spectroscopic study Journal of Chemical Physics 19 7749–7757 10.1063/1.471451.CrossRefGoogle Scholar
Herz, A.H., (1977) Aggregation of sensitizing dyes in solution and their adsorption onto silver halides Advances in Colloid and Interface Science 8 237–298 10.1016/0001-8686(77)80011-0.CrossRefGoogle Scholar
Higgins, D.A. Byerly, S.K. Abrams, M.B. and Corn, R.M., (1991) Second harmonic generation studies of methylene blue orientation at silica surfaces Journal of Physical Chemistry 95 6984–6990 10.1021/j100171a048.CrossRefGoogle Scholar
Hoppe, R. Alberti, G. Constantino, U. Dionigi, C. Schulz-Ekloff, G. and Vivani, R., (1997) Intercalation of dyes in layered zirconium phosphates. 1. Preparation and spectroscopic characterization of α-zirconium phosphate crystal violet compounds Langmuir 13 7252–7257 10.1021/la970551b.CrossRefGoogle Scholar
Karukstis, K.K. and Gulledge, A.V., (1998) Analysis of the solvatochromic behavior of the substituted triphenylmethane dye brilliant green Analytical Chemistry 70 4212–4217 10.1021/ac980318y.CrossRefGoogle Scholar
Kobayashi, M. Tokunaga, H. Okubo, J. Hoshi, T. and Tanizaki, Y., (1988) Measurements of the polarized ATR spectra for adsorbed dye layers by using a stack of thin glass plates Bulletin of the Chemical Society of Japan 61 4171–4176 10.1246/bcsj.61.4171.CrossRefGoogle Scholar
Kobayashi, T., (1996) J-aggregates Singapore World Scientific Publishing Co. Pte. Ltd. 10.1142/3168.CrossRefGoogle Scholar
Korppi-Tommola, J. and Yip, R.W., (1981) Solvent effect on the visible absorption spectrum of crystal violet Canadian Journal of Chemistry 59 191–194 10.1139/v81-030.CrossRefGoogle Scholar
Lueck, H.B. Rice, B.L. and McHale, J.L., (1992) Aggregation of triphenylmethane dyes in aqueous solution: dimerization and trimerization of crystal violet and ethyl violet Spectrochimica Acta, Part A 48 819–828 10.1016/0584-8539(92)80076-9.CrossRefGoogle Scholar
Marakami, K. Mizuguchi, K. Kubota, Y. and Fujisaki, Y., (1986) Equilibrium and kinetic studies of the dimerization of acridine orange and its 10-alkyl derivatives Bulletin of the Chemical Society of Japan 59 3393–3398 10.1246/bcsj.59.3393.CrossRefGoogle Scholar
Margulies, L. Rozen, H. and Nir, S., (1988) Model for competitive adsorption of organic cation on clay Clays and Clay Minerals 36 270–276 10.1346/CCMN.1988.0360309.CrossRefGoogle Scholar
Miyata, A. Unuma, Y. and Higishigaki, Y., (1991) H-aggregate of a long-chain crystal violet dye in Langmuir-Blodgett films Bulletin of the Chemical Society of Japan 64 2786–2791 10.1246/bcsj.64.2786.CrossRefGoogle Scholar
Möbius, D., (1995) Scheibe aggregates Advanced Materials 7 437–444 10.1002/adma.19950070503.CrossRefGoogle Scholar
Nickel, U. Halbig, P. Gliemann, H. and Schneider, S., (1997) Charge transfer like complexes of organic dyes adsorbed at colloidal silver studied by cyclic voltammetry, UV-vis and SERS spectros copy Berichte der Bunsen-Gesellschaft-Physical Chemistry Chemical Physics 101 41–49 10.1002/bbpc.19971010105.CrossRefGoogle Scholar
Pal, M.K. and Ghosh, J.K., (1994) Circular dichroic and spectrophotometric probes of the competetive binding between DNA and other anionic polymers Spectrochimica Acta, Part A 50 119–126 10.1016/0584-8539(94)80119-3.CrossRefGoogle Scholar
Schoonheydt, R.A. and Heughebaert, L., (1992) Clay adsorbed dyes: methylene blue on Laponite Clay Minerals 27 91–100 10.1180/claymin.1992.027.1.09.CrossRefGoogle Scholar
Takatsuki, M., (1980) Multiequilibrium system by the Principal Component Analysis method Bulletin of the Chemical Society of Japan 53 1922–1930 10.1246/bcsj.53.1922.CrossRefGoogle Scholar
Yamaoka, K. and Sasai, R., (2000) Pulsed electric linear dichroism of triphenylmethane dyes adsorbed on montmorillonite K10 in aqueous media Journal of Colloid and Interface Science 225 82–93 10.1006/jcis.2000.6738.CrossRefGoogle ScholarPubMed
Yao, H. Inoue, Y. Ikeda, H. Nakatani, K. Kim, H.B. and Kitamura, N., (1996) Micrometre size effect on dye association in single laser-trapped water Journal of Physical Chemistry 100 1494–1497 10.1021/jp952351j.CrossRefGoogle Scholar
Yu, C.H. Newton, S.Q. Norman, M.A. Miller, D.M. Schafer, L. and Teppen, B.J., (2000) Molecular dynamics simulations of the adsorption of methylene blue at clay mineral surfaces Clays and Clay Minerals 48 665–681 10.1346/CCMN.2000.0480608.CrossRefGoogle Scholar