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Transformation of 1-Aminonapththalene at the Surface of Smectite Clays

Published online by Cambridge University Press:  02 April 2024

Calvin C. Ainsworth ,
Bruce D. McVeety ,
Steven C. Smith  and
John M. Zachara
Calvin C. Ainsworth
Affiliation:
Pacific Northwest Laboratory, P.O. Box 999, MSN K3-61, Richland, Washington 99352
Bruce D. McVeety
Affiliation:
Pacific Northwest Laboratory, P.O. Box 999, MSN K3-61, Richland, Washington 99352
Steven C. Smith
Affiliation:
Pacific Northwest Laboratory, P.O. Box 999, MSN K3-61, Richland, Washington 99352
John M. Zachara
Affiliation:
Pacific Northwest Laboratory, P.O. Box 999, MSN K3-61, Richland, Washington 99352
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Abstract

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One-aminonaphthalene is sorbed onto the Na-saturated smectite clays, montmorillonite and hectorite, by cation exchange. In the presence of Fe3+, either in the clay structure or on the clay surface, sorption is followed by the formation of a blue-colored complex, with the continuous disappearance of aminonaphthalene from solution and the clay surface. The rate of aminonaphthalene disappearance decreases as pH increases. With time, four major products that appear to be structural isomers of N(4-aminonaphthyl)-l-naphthylamine are produced. A simplified model of this transformation is suggested to be the oxidation by Fe3+ of sorbed aminonaphthalene forming a radical cation-clay complex. A subsequent reaction between the radical-cation and a neutral aminonaphthalene molecule takes place, with the products being strongly sorbed to the clay surface.

Keywords

PolymerizationSmectiteSorptionSurface catalysis
Type
Research Article
Information
Clays and Clay Minerals , Volume 39 , Issue 4 , August 1991 , pp. 416 - 427
Copyright
Copyright © 1991, The Clay Minerals Society

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