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The Synthesis of a Platy Chabazite Analog From Delaminated Metakaolin with the Ability to Surface Template Nanosilver Particulates

Published online by Cambridge University Press:  01 January 2024

Steven M. Kuznicki ,
Christopher C. H. Lin ,
Lan Wu ,
Haiyan Yin ,
Mohsen Danaie  and
David Mitlin
Steven M. Kuznicki*
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
Christopher C. H. Lin
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
Lan Wu
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
Haiyan Yin
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
Mohsen Danaie
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
David Mitlin
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
*
* E-mail address of corresponding author: [email protected]
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Abstract

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Mineral chabazite has shown the unusual ability to surface template nanometal particles, especially Ag. A chabazite analog was synthesized from delaminated metakaolin. The chabazite formed retained the platy morphology of the base clay. This morphology is ideal for displaying surface-supported nanometal particles. The synthetic chabazite analog demonstrated the ability to form and support large concentrations of Ag nanoparticles, as observed in the related natural mineral. Due to greater Al content, the synthetic chabazite manifests significantly improved capacity for the formation of such Ag nanoparticles. As in the case of the mineral chabazite, surface Ag nanoparticles of high uniformity were observed in the range of 5–6 nm.

Keywords

ChabaziteMetakaolinNanoSilverZeolite
Type
Article
Information
Clays and Clay Minerals , Volume 56 , Issue 6 , December 2008 , pp. 655 - 659
Copyright
Copyright © 2008, The Clay Minerals Society

References

Anson, A. Kuznicki, S.M. Kuznicki, T. Haastrup, T. Wang, Y. Lin, C.C.H. Sawada, J.A. Eyring, E.M. and Hunter, D., 2008 Adsorption of argon, oxygen, and nitrogen on silver exchanged ETS-10 molecular sieve Microporous and Mesoporous Materials 109 577–580 10.1016/j.micromeso.2007.04.026.CrossRefGoogle Scholar
Bedrij, C., 2005 Nanotechnology Industry Review New York Griffin Securities Inc.Google Scholar
Breck, D.W., 1974 Zeolite Molecular Sieves: Structure, Chemistry and Use New York Wiley-Interscience Publication 771 pp.Google Scholar
Chandra, R. Taneja, P. John, J. Ayyub, P. Dey, G.K. and Kulshreshtha, S.K., 1999 Synthesis and TEM study of nanoparticles and nanocrystalline thin films of silver high-pressure sputtering Nanostructured Materials 11 1171–1179 10.1016/S0965-9773(99)00408-0.CrossRefGoogle Scholar
Elechiguerra, J.L. Burt, J.L. Morones, J.R. Camacho-Bragado, A. Gao, X. Lara, H.H. and Yacaman, M.J., 2005 Interaction of silver nanoparticles with HIV-1 Journal of Nanobiotechnology 3 1–10 10.1186/1477-3155-3-6.CrossRefGoogle ScholarPubMed
Eyde, T.H., Sheppard, R.A., and Barclay, C.S.V. (1987) Geology, Mineralogy, and Mining of the Bowie Zeolite Deposit Graham and Cochise Counties, Arizona. ZeoTrip’ 87, International Committee on Natural Zeolites.Google Scholar
Hilfenhaus, P., Heike, J., and Buettner, H. (2007) Antimicrobial wound dressing. US Patent 7,270,721.Google Scholar
Kim, N.S. Amert, A.K. Woessner, S.M. Decker, S. Kang, S.M. and Han, K.N., 2007 Effect of metal powder packing on the conductivity of nanometal ink Journal of Nanoscience and Nanotechnology 7 3902–3905 10.1166/jnn.2007.071.CrossRefGoogle ScholarPubMed
Kolbe, J. Arp, A. Calderone, F. Meyer, E.M. Meyer, W. Schaefer, H. and Stuve, M., 2007 Inkjettable conductive adhesive for use in microelectronics and microsystems technology Microelectronics Reliability 47 331–334 10.1016/j.microrel.2006.02.017.CrossRefGoogle Scholar
Kuznicki, S.M. and Whyte, J.R. Jr. (1988) Ion-exchange agent and use thereof in extracting heavy metals from aqueous solutions. US Patent 5,071,804, filed Sep 8, 1988, and issued Dec 10, 1991.Google Scholar
Kuznicki, S.M. Kelly, D.J.A. Bian, J. Lin, C.C.H. Chen, J. Liu, Y. Mitlin, D. and Xu, Z., 2007 Metal nanodots formed and supported on chabazite and chabazite-like surfaces Microporous and Mesoporous Materials 103 309–315 10.1016/j.micromeso.2007.01.057.CrossRefGoogle Scholar
Kuznicki, S.M. Anson, A. Koenig, A. Kuznicki, T.M. and Haastrup, T., 2007 Xenon adsorption on modified ETS-10 Journal of Physical Chemistry C 111 1560–1562 10.1021/jp067630t.CrossRefGoogle Scholar
Kuznicki, S.M. Lin, C.C.H. Bian, J. and Anson, A., 2007 Chemical upgrading of Bowie, Arizona sedimentary Na-chabazite Clays and Clay Minerals 55 235–238 10.1346/CCMN.2007.0550301.CrossRefGoogle Scholar
Lin, C.C.H., Danaie, M., Liu, Y., Mitlin, D., Kuznicki, S.M., and Eyring, E.M. (2009) Thermally stable silver nanoparticles formed on a zeolite surface show multiple crystal twinning (in press).CrossRefGoogle Scholar
Liu, Y. and Pinnavaia, T.J., 2004 Metakaolin as a reagent for the assembly of mesoporous aluminosilicates with hexagonal, cubic and wormhole framework structures from protofaujasitic nanoclusters Journal of Materials Chemistry 14 3416–3420 10.1039/b410337h.CrossRefGoogle Scholar
Liu, Y., Chen, F., Kuznicki, S.M., Wasylishen, R.E. and Xu, Z. (2009) A novel method to control the size of silver nanoparticles formed on silver chabazite. Journal of Nanoscience and Nanotechnology, (in press).CrossRefGoogle Scholar
Nepijko, S.A. Ievlev, D.N. Schulze, W. Urban, J. and Ertl, G., 2000 Growth of rodlike silver nanoparticles by vapor deposition of small clusters ChemPhysChem 1 140–142 10.1002/1439-7641(20001103)1:3<140::AID-CPHC140>3.0.CO;2-L.3.0.CO;2-L>CrossRefGoogle ScholarPubMed
Rasband, W. (2008) ImageJ: Image processing and analysis in Java. .Google Scholar
Sun, T. and Seff, K., 1994 Silver clusters and chemistry in zeolites Chemical Reviews 94 857–870 10.1021/cr00028a001.CrossRefGoogle Scholar