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Studies on the Adsorption of Dyes to Kaolinite

Published online by Cambridge University Press:  01 January 2024

Rodney G. Harris ,
Bruce B. Johnson  and
John D. Wells
Rodney G. Harris*
Affiliation:
Colloid and Environmental Chemistry Laboratory, La Trobe University, PO Box 199, Bendigo, Victoria 3552, Australia
Bruce B. Johnson
Affiliation:
Colloid and Environmental Chemistry Laboratory, La Trobe University, PO Box 199, Bendigo, Victoria 3552, Australia
John D. Wells*
Affiliation:
Colloid and Environmental Chemistry Laboratory, La Trobe University, PO Box 199, Bendigo, Victoria 3552, Australia
*
†Present address: Brewing Research International, Lyttel Hall, Nutfield, Surrey RH1 4HY, UK
*E-mail address of corresponding author: [email protected]
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Abstract

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The strong adsorption to kaolinite of four polyaromatic, cationic dyes (9-aminoacridine, 3,6-diaminoacridine, azure A and safranin O), which adsorb much less to alumina or silica, was investigated by means of acid-base titrations, measurements of adsorption at varying pH and dye concentration, and by ATR-FTIR spectroscopy. The four dyes adsorb to kaolinite to similar extents, with little change over the pH range 3–10, but at higher pH (above the pKas of the dyes) the adsorption of 9-aminoacridine and 3,6-diaminoacridine decreases, that of azure A increases, and that of safranin O stays approximately constant. Although the dyes adsorb to kaolinite much more strongly than metal ions do, titration and spectroscopic data show that there is only limited chemical interaction between the adsorbed dyes and the kaolinite surface. The results indicate that electrostatic interaction between the dye molecules and the kaolinite surface is necessary for adsorption, but that hydrophobic interactions also contribute. It is proposed that the relatively hydrophobic silica faces of kaolinite, which carry low-density permanent negative charge, facilitate aggregation and adsorption of the positively charged, flat, aromatic dye molecules.

Keywords

9-aminoacridine3,6-diaminoacridineATRAzure AClayDyeIsothermKaolinpKaPreferential AdsorptionSafranin O
Type
Research Article
Information
Clays and Clay Minerals , Volume 54 , Issue 4 , August 2006 , pp. 435 - 448
Copyright
Copyright © 2006, The Clay Minerals Society

References

Acheson, R.M., (1973) Acridines New York Interscience Publishers.Google Scholar
Albert, A., (1966) The Acridines: Their Preparation, Physical, Chemical and Biological Properties and Uses 2 London E. Arnold.Google Scholar
Albert, A., (1968) Heterocyclic Chemistry: An Introduction 2 London Athlone Pr..Google Scholar
Albert, A. and Serjeant, P.E., (1971) The Determination of Ionization Constants: A Laboratory Manual London Chapman & Hall.Google Scholar
Angove, M.J. Johnson, B.B. and Wells, J.D., (1997) Adsorption of cadmium(II) on kaolinite Colloids and Surfaces A: Physicochemical and Engineering Aspects 126 137–147 10.1016/S0927-7757(96)03990-8.CrossRefGoogle Scholar
Angove, M.J. Johnson, B.B. and Wells, J.D., (1998) The influence of temperature on the adsorption of cadmium(II) and cobalt(II) on kaolinite Journal of Colloid and Interface Science 204 93–103 10.1006/jcis.1998.5549.CrossRefGoogle ScholarPubMed
Angove, M.J. Wells, J.D. and Johnson, B.B., (1999) Adsorption of cadmium(II) onto goethite and kaolinite in the presence of benzene carboxylic acids Colloids and Surfaces A: Physicochemical and Engineering Aspects 146 243–251 10.1016/S0927-7757(98)00799-7.CrossRefGoogle Scholar
Atun, G. Hisarlt, G. and Tuncay, M., (1998) Adsorption of safranine-O on hydrophilic and hydrophobic glass surfaces Colloids and Surfaces A: Physicochemical and Engineering Aspects 143 27–33 10.1016/S0927-7757(98)00494-4.CrossRefGoogle Scholar
Awal, K.P., (1988) Studies on the interaction of acid dyes with some local clay minerals Journal of Nepal Chemical Society 8 1–5.Google Scholar
Awal, K.P. and Ghimire, K.N., (1992) Studies on the interactions of indigocarmine and safranine with H+, Na+, Ca+2-kaolinite Journal of Nepal Chemical Society 11 31–35.Google Scholar
Axe, K. and Persson, P., (2001) Time-dependent surface speciation of oxalate at the water-boehmite (γ-AlOOH) interface: implications for dissolution Geochimica et Cosmochimica Acta 65 4481–4492 10.1016/S0016-7037(01)00750-5.CrossRefGoogle Scholar
Axe, K. and Persson, P., (2005) Adsorption of oxalate and malonate at the water-goethite interface: molecular surface speciation from IR spectroscopy Geochimica et Cosmochimica Acta 69 541–552 10.1016/j.gca.2004.07.009.Google Scholar
Boily, J.-F. Persson, P. and Sjöberg, S., (2000) Benzenecarboxylate surface complexation at the goethite (α-FeOOH)/water interface: II. Linking IR spectroscopic observations to mechanistic surface complexation models for phthalate, trimellitate and pyromellitate Geochimica et Cosmochimica Acta 64 3453–3470 10.1016/S0016-7037(00)00453-1.CrossRefGoogle Scholar
Bradley, D.F. and Wolf, M.K., (1959) Aggregation of dyes bound to polyanions Proceedings of the National Academy of Sciences of the United States of America 45 944–952 10.1073/pnas.45.7.944.CrossRefGoogle ScholarPubMed
Breen, C. and Rock, B., (1994) The competitive adsorption of methylene blue on to montmorillonite from binary solution with thioflavin T, proflavine and acridine yellow. Steady-state and dynamic studies Clay Minerals 29 179–189 10.1180/claymin.1994.029.2.04.CrossRefGoogle Scholar
Cenens, J. and Schoonheydt, R.A., (1988) Visible spectroscopy of methylene blue on hectorite, laponite B, and barasym in aqueous suspension Clays and Clay Minerals 36 214–224 10.1346/CCMN.1988.0360302.CrossRefGoogle Scholar
Coates, E., (1969) Aggregation of dyes in aqueous solutions Journal of the Society of Dyers and Colourists 85 355–368 10.1111/j.1478-4408.1969.tb02909.x.CrossRefGoogle Scholar
De, D.K. Chakravarti, S.K. and Mukherjee, S.K., (1968) Effect of temperature on the adsorption of some dyes on kaolinite Journal of the Indian Chemical Society 45 566–570.Google Scholar
De, D.K. Das Kanungo, J.L. and Chakravarti, S.K., (1974) Adsorption of methylene blue, crystal violet and malachite green on bentonite, vermiculite, kaolinite, asbestos and feldspar Indian Journal of Chemistry 12 1187–1189.Google Scholar
Fischer, D. Caseri, W.R. and Hähner, G., (1998) Orientation and electronic structure of ion exchanged dye molecules on mica: An X-ray absorption study Journal of Colloid and Interface Science 198 337–346 10.1006/jcis.1997.5296.CrossRefGoogle Scholar
Giles, C.H. D’Silva, A.P. Trivedi, A.S. et al. ,Everett, D.H. (1969) et al. , Use of dyes for specific surface measurement Proceedings of the International Symposium on Surface Area Determination held at the School of Chemistry, University of Bristol, UK, 16–18 July, 1969 London Butterworths 317–329.Google Scholar
Grim, R.E., (1962) Applied Clay Mineralogy New York McGraw-Hill Book Company, Inc. 10.1080/11035896209447314.CrossRefGoogle Scholar
Hang, P.T. and Brindley, G.W., (1970) Clay organic studies XVIII. Methylene blue absorption by clay minerals. Determination of surface areas and cation exchange capacities Clays and Clay Minerals 18 203–212 10.1346/CCMN.1970.0180404.CrossRefGoogle Scholar
Harris, R.G. Wells, J.D. and Johnson, B.B., (2001) Selective adsorption of dyes and other organic molecules to kaolinite and oxide surfaces Colloids and Surfaces A: Physicochemical and Engineering Aspects 180 131–140 10.1016/S0927-7757(00)00747-0.CrossRefGoogle Scholar
Harris, R.G. Johnson, B.B. and Wells, J.D., (2006) Modeling the adsorption of organic dye molecules to kaolinite Clays and Clay Minerals 54 456–465 10.1346/CCMN.2006.0540406.CrossRefGoogle Scholar
Harris, R.G. Wells, J.D. and Johnson, B.B., (2006) Competitive adsorption of Cd and dyes to kaolinite Clays and Clay Minerals 54 449–455 10.1346/CCMN.2006.0540405.CrossRefGoogle Scholar
Ikhsan, J. Johnson, B.B. and Wells, J.D., (1999) A comparative study of the adsorption of transition metals on kaolinite Journal of Colloid and Interface Science 217 403–410 10.1006/jcis.1999.6377.CrossRefGoogle ScholarPubMed
Johnson, B.B. Sjöberg, S. and Persson, P., (2004) Surface complexation of mellitic acid to goethite: An ATR-FTIR spectroscopic study Langmuir 20 823–828 10.1021/la035471o.CrossRefGoogle Scholar
Kamel, M.M. Youssef, B.M. and Kamel, M.M., (1991) Adsorption of anionic dyes by kaolinites Dyes and Pigments 15 175–182 10.1016/0143-7208(91)80002-Q.CrossRefGoogle Scholar
Lackovic, K. Angove, M.J. Wells, J.D. and Johnson, B.B., (2003) Modeling the adsorption of Cd(II) onto Muloorina illite and related clay minerals Journal of Colloid and Interface Science 257 31–40 10.1016/S0021-9797(02)00031-0.CrossRefGoogle ScholarPubMed
Lackovic, K. Johnson, B.B. Angove, M.J. and Wells, J.D., (2003) Modeling the adsorption of citric acid onto Muloorina illite and related clay minerals Journal of Colloid and Interface Science 267 49–59 10.1016/S0021-9797(03)00693-3.CrossRefGoogle ScholarPubMed
Lewis, D., (2000) Adsorbing colloid flotation of an industrial dye Melbourne Swinburne University of Technology.Google Scholar
Ludwig, C., (1996) GrFit — A Computer Program for Solving Speciation Problems: Evaluation of Equilibrium Constants, Concentrations and other Physical Parameters Switzerland University of Berne.Google Scholar
Nikolenko, N.V. Taran, I.B. Plaksienko, I.L. Vorob’ev, N.K. and Oleinik, T.A., (1997) Adsorption of organic compounds from aqueous solutions on a silica gel and α-alumina Colloid Journal (Translation of Kolloidnyi Zhurnal) 59 476–481.Google Scholar
Persson, P. Karlsson, M. and Öhman, L.-O., (1998) Coordination of acetate to Al(III) in aqueous solution and at the water-aluminum hydroxide interface: A Potentiometric and attenuated total reflectance FTIR study Geochimica et Cosmochimica Acta 62 3657–3668 10.1016/S0016-7037(98)00260-9.CrossRefGoogle Scholar
Persson, P. Nordin, J. Rosenqvist, J. Lövgren, L. Öhman, L.-O. and Sjöberg, S., (1998) Comparison of the adsorption of o-phthalate on boehmite (γ-AlOOH), aged γ-Al2O3, and goethite (α-FeOOH) Journal of Colloid and Interface Science 206 252–266 10.1006/jcis.1998.5668.CrossRefGoogle ScholarPubMed
Ramachandran, V.S. Kacker, K.P. and Patwardhan, N.K., (1962) Adsorption of dyes by clay minerals American Mineralogist 47 165–169.Google Scholar
Roddick-Lanzilotta, A. and McQuillan, A.J., (2000) An in situ spectroscopic study of glutamic acid and of aspartic acid adsorbed on TiO2: Implications for the biocompatibility of titanium Journal of Colloid and Interface Science 227 48–54 10.1006/jcis.2000.6864.CrossRefGoogle Scholar
Rytwo, G. Nir, S. and Margulies, L., (1995) Interactions of monovalent organic cations with montmorillonite: Adsorption studies and model calculations Soil Science Society of America Journal 59 554–564 10.2136/sssaj1995.03615995005900020041x.CrossRefGoogle Scholar
Serratosa, J.M., (1966) Infrared analysis of the orientation of pyridine molecules in clay complexes Clays and Clay Minerals 14 385–391 10.1346/CCMN.1966.0140133.CrossRefGoogle Scholar
Sheals, J. Sjöberg, S. and Persson, P., (2002) Adsorption of glyphosate on goethite: Molecular characterisation of surface complexes Environmental Science and Technology 36 3090–3095 10.1021/es010295w.CrossRefGoogle ScholarPubMed
Specht, C.H. and Frimmel, F.H., (2001) An in situ ATR-FTIR study on the adsorption of dicarboxylic acids onto kaolinite in aqueous suspensions Physical Chemistry Chemical Physics 3 5444–5449 10.1039/b105712j.CrossRefGoogle Scholar
Sukhishvili, S.A. and Granick, S., (1999) Orientation and order of aqueous organic ions adsorbed to a solid surface Journal of Physical Chemistry B 103 472–479 10.1021/jp982565b.CrossRefGoogle Scholar
Tunega, D. Gerzabek, M.H. and Lischka, H., (2004) Ab initio molecular dynamics study of a monomolecular water layer on octahedral and tetrahedral kaolinite surfaces Journal of Physical Chemistry B 108 5930–5936 10.1021/jp037121g.CrossRefGoogle Scholar
Wang, J.C., (2000) A review of dye aggregation and its characterisation Advances in Colour Science and Technology 3 20–31.Google Scholar
Yariv, S. Ghosh, D.K. and Hepler, L.G., (1991) Metachromasy in clay-mineral systems: Adsorption of cationic dyes crystal violet and ethyl violet by kaolinite from aqueous and organic solutions Journal of the Chemical Society. Faraday Transactions 87 1201–1207 10.1039/ft9918701201.CrossRefGoogle Scholar