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Smectites in Iron-Rich Calcareous Soil and Black Soils of Taiwan

Published online by Cambridge University Press:  28 February 2024

Chuang-Wen Pai ,
Ming-Kuang Wang ,
Wei-Min Wang  and
Kun-Huang Houng
Chuang-Wen Pai
Affiliation:
Department of Agriculture Chemistry, National Taiwan University, Taipei, Taiwan
Ming-Kuang Wang
Affiliation:
Department of Agriculture Chemistry, National Taiwan University, Taipei, Taiwan
Wei-Min Wang
Affiliation:
Department of Agriculture Chemistry, National Taiwan University, Taipei, Taiwan
Kun-Huang Houng
Affiliation:
Department of Agriculture Chemistry, National Taiwan University, Taipei, Taiwan
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Abstract

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The iron-rich calcareous soil (Typic Rhodustalf) from the Penghu island group represents a volcanic area. The black soils (Typic Haplustert, Vertic Endoaquoll, Typic Hapludolls) are typical of eastern Taiwan. Four A horizons and a pedon from the iron-rich calcareous soil and four pedons from the black soils were studied to analyze soil properties and clay compositions. The objective was to compare the properties of smectites developed from different parent materials. The materials were studied by using conventional X-ray diffraction (XRD) of K- and Mg-saturated clays and involved the alkylam-monium (C = 12) method and the Greene-Kelly test. The mean-layer charge of smectites (0.48–0.52 cmol(c)/O10(OH)2) in the iron-rich calcareous soil was found to be higher than the black soils (0.43–0.48 cmol(c)/O10(OH)2). A smectite of higher charge developed from the basalts. This smectite is enriched in Fe and Mg, and lacks Si, thereby forming beidellite and/or nontronite. In contrast, under high precipitation, elevated temperature, base saturation (e.g., Na, K, Ca, Mg), and about equal wet and dry cycles per year in the black soil environments, smectites developed from the complicated geologic site of eastern Taiwan. These smectites transformed to smectite-kaolinite mixed-layer clay and thus, resulted in lower-charge smectites. The K fixation capacity of the iron-rich calcareous soil was higher than the black soils.

Keywords

Black SoilsIron-Rich Calcareous SoilMollisolsSmectiteVermiculiteVertisols
Type
Research Article
Information
Clays and Clay Minerals , Volume 47 , Issue 4 , August 1999 , pp. 389 - 398
Copyright
Copyright © 1999, The Clay Minerals Society

References

Ahmad, N., Ahmad, N. and Mermut, A., 1996 Occurrence and distribution of vertisols Vertisols and Technologies for Their Management. Developments in Soil Science 24 New York Elsevier 1–42.Google Scholar
Alexiades, C.A. and Jackson, M.L., 1965 Quantitative determination of vermiculite in soils Soil Science Society of America Proceedings 29 522–527 10.2136/sssaj1965.03615995002900050016x.CrossRefGoogle Scholar
Badraoui, M. and Bloom, P.R., 1990 Iron-rich high-charge beidellite in Vertisols and Mollisols of the high Chaouia region of Morocco Soil Science Society of America Journal 54 343–358 10.2136/sssaj1990.03615995005400010043x.CrossRefGoogle Scholar
Beckmann, G.G. Thompson, C.H. Hubble, G.D., McGarity, W. Hoult, E.H. and So, H.B., 1984 Relationships of soil layers below gilgai in black earth The Properties and Utilization of Cracking Clay Soils 64–72.Google Scholar
Borchardt, G., Dixon, J.B. and Weed, S.B., 1989 Smectite Minerals in Soil Environments Madison, Wisconsin Soil Science Society of America 675–727.Google Scholar
Borchardt, G. Hill, R.L. and Weide, D.L., 1985 Smectite pedogenesis and late Holocene tectonism along the Raymond fault, San Marino, California Soils and Quaternary Geology of the Southwestern United States 65–78 10.1130/SPE203-p65.CrossRefGoogle Scholar
Bouabid, R. Badraoui, M. and Bloom, P.R., 1991 Potassium fixation and charge characteristics of soil clays Soil Science Society of America Journal 55 1493–1498 10.2136/sssaj1991.03615995005500050049x.CrossRefGoogle Scholar
Bouabid, R. Badraoui, M. Bloom, P.R. and Daniane, M., 1996 The nature of smectites and associated interstratified minerals in soils of the Gharb plain of Morocco European Journal of Soil Science 47 165–174 10.1111/j.1365-2389.1996.tb01387.x.CrossRefGoogle Scholar
Brindley, G.W., Brindley, G.W. and Brown, G., 1980 Quantitative X-ray minerals analysis of clays Crystal Structures of Clay Minerals and Their X-ray Identification London Mineralogical Society Monograph No. 5, Mineralogical Society 411–438.CrossRefGoogle Scholar
Bühmann, C. and Grubb, P.L.G., 1991 A kaolin-smectite interstratification sequence from a red and black complex Clays and Clay Minerals 26 343–358 10.1180/claymin.1991.026.3.04.CrossRefGoogle Scholar
Burras, L. Smeck, N.E. and Bigham, J.M., 1996 Origin and properties of smectite in Loess-derived soils of western Ohio Soil Science Society of America Journal 60 1961–1968 10.2136/sssaj1996.03615995006000060049x.CrossRefGoogle Scholar
Coffman, C.B. and Fanning, D.S., 1974 Vermiculite determination on whole soils by cation-exchange capacity method Clays and Clay Minerals 22 271–283 10.1346/CCMN.1974.0220309.CrossRefGoogle Scholar
Dudal, R. Eswaran, H., Wilding, L.P. and Puentes, R., 1988 Distribution, properties and classification of vertisols Vertisols: Their Distribution, Classification and Management Printing Center, College Station, Texas Technical Monograph 18, Soil Management Support Service, Washington, D.C. and Texas A&M University 1–22.Google Scholar
Egashira, K. Dixon, J.B. Hossner, L.R., van Olphen, H. and Venial, F., 1981 High charge smectite from lignite overburden of east Texas 7th International Clay Conference, Bologna Amsterdam Elsevier 335–345.Google Scholar
Glasmann, J.R., 1982 Alternation of andesite in wet, unstable soils of Oregon’s western cascades Clays and Clay Minerals 30 253–263 10.1346/CCMN.1982.0300402.CrossRefGoogle Scholar
Graham, R.C. and Southard, A.R., 1983 Genesis of a Vertisol and an associated Mollisol in northern Utah Soil Science Society of America Journal 47 552–559 10.2136/sssaj1983.03615995004700030032x.CrossRefGoogle Scholar
Greene-Kelly, R., 1953 The identification of montmorillonite in clays Journal of Soil Science 4 233–237 10.1111/j.1365-2389.1953.tb00657.x.CrossRefGoogle Scholar
Herbillion, A. Frankart, J.R. and Vielvoye, L., 1981 An occurrence of interstratified kaolinite-smectite minerals in red-black soil toposequence Clay Minerals 16 195–201 10.1180/claymin.1981.016.2.07.CrossRefGoogle Scholar
Ho, C.S., 1988 An Introduction to the Geology of Taiwan-Explanation Text of the Geologic Map of Taiwan 2nd Taipei, Taiwan Central Geological Survey, Ministry of Economic Affairs.Google Scholar
International Committee on Vertisols., 1990 Draft Keys Washington, D.C. USDA-SMSS.Google Scholar
Jackson, M.L., 1968 Weathering of primary and secondary minerals in soils 9th Transaction International Congress, Soil Science (Adelaide, Australia) 4 281–292.Google Scholar
Jackson, M.L., 1979 Soil Chemical Analysis. Advanced Course, 2nd edition Madison, Wisconsin University of Wisconsin.Google Scholar
Kantor, K. and Schwertmann, U., 1974 Mineralogy and genesis of clays in red-black soil toposequences on basic igneous rocks in Kenya Journal of Soil Science 25 67–78 10.1111/j.1365-2389.1974.tb01104.x.CrossRefGoogle Scholar
Keith, T.E.C. and Staples, L.W., 1985 Zeolite in eocene basaltic pillow lavas of the siletz river vocanics central coast range, Oregan Clays and Clay Minerals 33 135–144 10.1346/CCMN.1985.0330208.CrossRefGoogle Scholar
Lagaly, G., 1979 The “layer charge” of regular interstratified 2:1 clay minerals Clays and Clay Minerals 27 1–10 10.1346/CCMN.1979.0270101.CrossRefGoogle Scholar
Lagaly, G., 1982 Layer charge heterogeneity in vermiculites Clays and Clay Minerals 3 215–222 10.1346/CCMN.1982.0300308.CrossRefGoogle Scholar
Lagaly, G., 1992 Layer charge determination by alkyammon-ium ions Layer Charge Characteristics of Clays. CMS Workshop On Layer Charge of Clays, Minneapolis, October, 1992 Saskatoon University of Saskatchewan.Google Scholar
Laird, D.A., 1987 Layer charge and crystalline swelling of expanding 2:1 phyllosilicates Ames, Iowa Iowa State University.Google Scholar
Laird, D.A. Scott, A.D. and Fenton, T.E., 1989 Evaluation of the alkylammonium method of determining layer charge Clays and Clay Minerals 37 41–46 10.1346/CCMN.1989.0370105.CrossRefGoogle Scholar
Leung, K.W. and Lai, C.Y., 1965 Soil development study of the reddish brown lateritic soils in Penghu county, Taiwan, China Journal of Taiwan Agricultural Resources 14 1–14.Google Scholar
Malla, P.B. Robert, M. Douglas, L.A. Tessier, D. and Komarneni, S., 1993 Charge heterogeneity and nanostructure of 2:1 layer silicates by high-resolution transmission electron microscopy Clays and Clay Minerals 41 412–422 10.1346/CCMN.1993.0410402.CrossRefGoogle Scholar
Matsue, N. and Wada, K., 1988 Interlayer materials of partially interlayered vermiculites in Dystrochrepts derived from Tertiary sediments Journal of Soil Science 39 155–162 10.1111/j.1365-2389.1988.tb01202.x.CrossRefGoogle Scholar
McKeague, J.A. Brydon, J.E. and Miles, N.M., 1971 Differentiation of form of extractable iron and aluminum in soils Soil Science Society of America Proceedings 35 33–38 10.2136/sssaj1971.03615995003500010016x.CrossRefGoogle Scholar
Mehra, O.P. and Jackson, M.L., 1960 Iron oxides removed from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate Clays and Clay Minerals 7 317–327 10.1346/CCMN.1958.0070122.CrossRefGoogle Scholar
Olis, A.C. Malla, P.B. and Douglas, L.A., 1990 The rapid estimation of the layer charges of 2:1 expandable clays from a single alkylammonium ion expansion Clay Minerals 24 39–50 10.1180/claymin.1990.025.1.05.CrossRefGoogle Scholar
Pai, C.W., 1997 Soil properties and clay minerals in black soil of eastern Taiwan Taipei, Taiwan National Taiwan University.Google Scholar
Reid, D.A. Graham, R.C. Douglas, L.A. and Amrheim, C., 1996 Smectite mineralogy and charge characterizations along an arid geomorphic transect Soil Science Society of America Journal 60 1602–1611 10.2136/sssaj1996.03615995006000050046x.CrossRefGoogle Scholar
Senkayi, A.L. Dixon, J.B. and Viani, B.E., 1985 Mineralogical transformation during weathering of lignite overburden in east Texas Clays and Clay Minerals 31 49–56 10.1346/CCMN.1983.0310108.CrossRefGoogle Scholar
Soil Survey Staff., 1996 Key to Soil Taxonomy, 6th edition Washington, D.C. United States Department of Agricultural and Soil Conservation Service.Google Scholar
Stul, M.S. and Mortier, W.J., 1974 The heterogeneity of the charge density in montmorillonite Clays and Clay Minerals 22 391–396 10.1346/CCMN.1974.0220505.CrossRefGoogle Scholar
Tamura, T., 1958 Identification of clay minerals from acid soils Journal of Soil Science 9 141–147 10.1111/j.1365-2389.1958.tb01906.x.CrossRefGoogle Scholar
Van Slyke, D.D. and Folch, J., 1940 Monometric carbon determination Journal of Biological Chemistry 136 509–541.CrossRefGoogle Scholar
Walkley, A. and Black, C.A., 1934 An experimentation of Detjareff method and a proposed modification of the chromic acid titration method Soil Science 37 29–39 10.1097/00010694-193401000-00003.CrossRefGoogle Scholar
Wang, W.M., 1997 The comparative study of the geochemistry and weathering chemistry of the modern soils and the Late Miocene palesols in the Penghu islands (Pescadores), Taiwan Taipei, Taiwan National Taiwan University.Google Scholar
Wang, M.K. Houng, K.H. and Lim, K.K., 1988 Maghemite in Tatun and Penghu red soils Journal of the Chinese Agricultural Chemical Society 26 256–263.Google Scholar
Wang, M.K. Lim, K.K. and Houng, K.H., 1988 Montmorillonite in Penghu red soils Journal of the Chinese Agricultural Chemical Society 26 597–606.Google Scholar
Wang, W.M. Yeh, H.W. Chen, P.Y. and Wang, M.K., 1998 Kaolin mineralogy of clays in paleosol profiles on the Late-Miocene sediments in Penghu islands (Pescadores), Taiwan Clays and Clay Minerals 46 1–9 10.1346/CCMN.1998.0460101.Google Scholar
Wildman, W.E. Jackson, M.L. and Whittig, I.L.D., 1968 Iron-rich montmorillonite in soils derived from serpentine Soil Science Society of America Proceeding 32 787–794 10.2136/sssaj1968.03615995003200060025x.CrossRefGoogle Scholar
Xing, B. and Dudas, M.J., 1994 Characterization of clay minerals in white clay soils. People’s Republic China Soil Science Society of America Journal 58 1253–1259 10.2136/sssaj1994.03615995005800040037x.CrossRefGoogle Scholar