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Significance of the Formation of Calcium Carbonate Minerals in the Pedogenesis and Management of Cracking Clay Soils (Vertisols) of India

Published online by Cambridge University Press:  01 January 2024

Pankaj Srivastava ,
Tapas Bhattacharyya  and
Dilip Kumar Pal
Pankaj Srivastava
Affiliation:
Division of Soil Resource Studies, National Bureau of Soil Survey and Land Use Planning, Amravati Road, Nagpur 440 010, India
Tapas Bhattacharyya
Affiliation:
Division of Soil Resource Studies, National Bureau of Soil Survey and Land Use Planning, Amravati Road, Nagpur 440 010, India
Dilip Kumar Pal*
Affiliation:
Division of Soil Resource Studies, National Bureau of Soil Survey and Land Use Planning, Amravati Road, Nagpur 440 010, India
*
*E-mail address of corresponding author: [email protected]
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Abstract

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Micromorphological studies were performed in order to understand the factors and processes involved in the formation of calcium carbonate (CaCO3) in twenty three soil series of Vertisols representing sub-humid, semi-arid and arid climatic regions of Peninsular India. The study indicates that Vertisols contain both pedogenic calcium carbonate (PC) and non-pedogenic calcium carbonate (NPC) irrespective of the ecosystems to which they belong. The NPCs are part of the parent material of Vertisols. Dissolution of NPCs and recrystallization of dissolved Ca2+ ions are responsible for the formation of PCs. Vertisols of arid and semi-arid climates contain more PC in their soil control section (SCS) than those of sub-humid climates. Formation of PC is the prime chemical reaction responsible for the increase in pH, the decrease in the Ca/Mg ratio of exchange site with depth and in the development of subsoil sodicity. Petrographic and scanning electron microscopic (SEM) examination of quartz, feldspars and micas indicate little or no alteration, discounting the possibile formation of smectite during Vertisol formation. X-ray diffraction (XRD) analysis of clays indicates that smectites of Vertisols are fairly well crystallized and do not show any sign of transformation except for hydroxy interlayering. The preservation of the crystallinity of smectite and the lack of transformation of primary minerals thus validate the hypothesis of positive entropy change during the formation of Vertisols.

The precise cause-effect relationship between CaCO3 of pedogenic and non-pedogenic origin, and exchangeable Mg, Na and Ca percentages (EMP, ESP and ECP) has been established in the study. This indicates that impoverishment of Ca2+ ions on the exchange sites of Vertisols needs to be controlled by rehabilitation methods that can replenish Ca2+ ions, and thus the study provides relevant information for future land resource management programmes not only on Vertisols of India but also on similar soils occurring elsewhere.

Keywords

Calcium CarbonatesMineral AlterationPedogenesisSoil MicromorphologyVertisols
Type
Research Article
Information
Clays and Clay Minerals , Volume 50 , Issue 1 , February 2002 , pp. 111 - 126
Copyright
Copyright © 2002, The Clay Minerals Society

References

Arkley, R.J., (1963) Calculation of carbonate and water measurement in soil from climatic data Soil Science 96 239–248 10.1097/00010694-196310000-00003.Google Scholar
Balpande, S.S. Deshpande, S.B. and Pal, D.K., (1996) Factors and processes of soil degradation in Vertisols of the Purna Valley, Maharashtra, India Land Degradation and Development 7 313–324 10.1002/(SICI)1099-145X(199612)7:4<313::AID-LDR236>3.0.CO;2-#.Google Scholar
Balpande, S.S. Deshpande, S.B. and Pal, D.K., (1997) Plasmic fabric of Vertisols of the Purna Valley of India in relation to their cracking Journal of the Indian Society of Soil Science 45 553 562.Google Scholar
Bhattacharyya, T. Pal, D.K. and Deshpande, S.B., (1993) Genesis and transformation of minerals in the formation of red (Alfisols) and black (Inceptisols and Vertisols) soils on Deccan basalt in the Western Ghats, India Journal of Soil Science 44 159–171 10.1111/j.1365-2389.1993.tb00442.x.Google Scholar
Brewer, R. (1976) Fabric and Mineral Analysis of Soils. Robert, E. Krieger Publishing Co., Huntington, New York.Google Scholar
Bullock, P. Fedoroff, N. Jongerius, A. Stoops, G. and Tursina, T., (1985) Handbook for Soil Thin Section Description Wolverhampton, UK Waine Research Publications, Waine Research Publications.Google Scholar
Deshmukh, S.S., (1980) Geology, Petrography and Petrochemistry of the Deccan basalts in Parts of Maharashtra State Nagpur Regional Petrological Laboratory, Geological Survey of India, Central Region 71 pp.Google Scholar
Dudal, R. (1965) Dark Clay Soils of Tropical and Sub-tropical Regions. FAO Agriculture Development Paper, 83, 161 pp.Google Scholar
Gabhane, V.V. (1996) Occurrence of shallow to deep black soils on the basaltic plateau of Malegaon — their genesis and land use potential. Ph.D. thesis, Dr. Panjabrao Deshmukh Krishi Vidyapeeth, Akola (M.S.), India.Google Scholar
Gupta, R.K. Abrol, I.P. and Stewart, B.A., (1990) Salt-affected soils: their reclamation and management for crop production Advances in Soil Science, Vol. II Berlin Springer-Verlag 223–288 10.1007/978-1-4612-3322-0_7.Google Scholar
Jackson, M.L., (1963) Interlayering of expansible clay minerals in soils by chemical weathering Clays and Clay Minerals 11 29–46 10.1346/CCMN.1962.0110104.Google Scholar
Jackson, M.L., (1979) Soil Chemical Analysis — Advanced Course 2nd Madison, WI, USA University of Wisconsin Published by the author.Google Scholar
Jongerius, A. and Heintzberger, G., (1975) Methods in Soil Micromorphology. A Technique for the Preparation of Large Thin Sections Wageningen, The Netherlands Netherlands Soil Survey Institute Soil Survey Paper No. 10 .Google Scholar
Kadu, P. R. (1997) Soils of Adasa watershed: their geomorphology, formation, characterization and land evaluation for rational use. Ph.D. thesis. Dr. Panjabrao Deshmukh Krishi Vidyapeeth, Akola (M.S.) India.Google Scholar
Kalbande, A.R. Pal, D.K. and Deshpande, S.B., (1992) b-fabric of some benchmark Vertisols of India in relation to their mineralogy Journal of Soil Science 43 375–385 10.1111/j.1365-2389.1992.tb00144.x.Google Scholar
Lal, S. Deshpande, S.B. and Sehgal, J., (1994) Soil Series of India Nagpur, India NBSS&LUP 684 pp.Google Scholar
Levine, S.J. Hendricks, D.M. and Douglas, L.A., (1990) Carbonate forms in residual horizons of limestone derived soils in northern Arizona Soil Micromorphology: A Basic and Applied Science Amsterdam Elsevier 373 380.Google Scholar
Mandal, C. Mandal, D.K. Srinivas, C.V. Sehgal, J.L. and Velayutham, M., (1999) Soil Climatic Database for Crop Planning in India Nagpur NBSS&LUP NBSS Publication No. 53 .Google Scholar
Mermut, A.R. and Dasog, G.S., (1986) Nature and micro-morphology of carbonate glaebules in some Vertisols of India Soil Science Society of America Journal 50 382–391 10.2136/sssaj1986.03615995005000020026x.Google Scholar
NBSS&LUP-ICRISAT, The Suitabilities of Vertisols and Associated Soils for Improved Cropping Systems in Central India (1991) Patancheru, India NBSS&LUP, Nagpur and ICRISAT 61 pp.Google Scholar
Pacharne, T. Pal, D.K. and Deshpande, S.B., (1996) Genesis and transformation of clay minerals in the formation of ferruginous (Inceptisols) and Black (Vertisols) soils in the Saptadhara Watershed of Nagpur district, Maharashtra Journal of the Indian Society of Soil Science 44 300 309.Google Scholar
Pal, D.K. and Deshpande, S.B., (1987) Characteristics and genesis of minerals in some benchmark Vertisols of India Pedologie 37 259 275.Google Scholar
Pal, D.K. and Deshpande, S.B., (1987) Genesis of clay minerals in a red and black complex soils of southern India Clay Research 6 6 13.Google Scholar
Pal, D.K. Deshpande, S.B. Venugopal, K.R. and Kalbande, A.R., (1989) Formation of di- and trioctahedral smectite as evidence for paleoclimatic changes in southern and central Peninsular India Geoderma 45 175–184 10.1016/0016-7061(89)90049-9.Google Scholar
Pal, D.K. Dasog, G.S. Vadivelu, S. Ahuja, R.L. Bhattacharyya, T., Lal, R. Kimble, J.M. Eswaran, H. and Stewart, B.A., (2000) Secondary calcium carbonate in soils of arid and semi-arid regions of India Global Change and Pedogenic Carbonates Boca Raton, Florida, USA Lewis Publishers 149 185.Google Scholar
Pal, D.K. Deshpande, S.B. Velayutham, M. Srivastava, P. and Durge, S.L., (2000) Climate Change and Polygenesis in Vertisols of the Purna Valley (Maharashtra) and their Management Nagpur NBSS&LUP NBSS Research Bulletin 83.Google Scholar
Pal, D.K. Balpande, S.S. and Srivastava, P., (2001) Polygenetic Vertisols of the Purna Valley of central India Catena 43 231–249 10.1016/S0341-8162(00)00166-1.Google Scholar
Paranjape, M.V. Pal, D.K. and Deshpande, S.B., (1997) Genesis of non-vertic deep black soils in a basaltic landform of Maharashtra Journal of the Indian Society of Soil Science 45 174 180.Google Scholar
Piper, C.S., (1966) Soil and Plant Analysis Bombay, India Hans Publishers.Google Scholar
Rabenhorst, M.C. Wilding, L.P. and West, L.T., (1984) Identification of pedogenic carbonates using stable carbon isotope and microfabric analyses Soil Science Society of America Journal 48 125–135 10.2136/sssaj1984.03615995004800010023x.Google Scholar
Richards, L.A., (1954) Diagnosis and Improvement of Saline and Alkali Soils Washington, D.C. US Government Printing Office 10.1097/00010694-195408000-00012 USDA Agricultural Handbook No. 60 .Google Scholar
Scholz, H., (1971) Calcretes and their formation — a survey based on observations in South West Africa Pedologie 21 170 180.Google Scholar
Sehgal, J.L. and Stoops, G., (1972) Pedogenic calcite accumulation in arid and semi-arid regions of the Indo-Gangetic alluvial plains of erstwhile Punjab (India) — their morphology and origin Geoderma 8 59–72 10.1016/0016-7061(72)90032-8.Google Scholar
Shainberg, J. Sumner, M.E. Miller, W.P. Farina, M.P.W. Pavan, M.A. Fey, M.V. and Stewart, B.A., (1989) Use of gypsum on soils: a review Advances in Soil Science, Vol. 9 New York Springer 1 111.Google Scholar
Shirsath, S.K. Bhattacharyya, T. and Pal, D.K., (2000) Minimum threshold value of smectite for Vertic properties Australian Journal of Soil Research 38 189–201 10.1071/SR99051.Google Scholar
Smeck, N.E. Runge, E.C.A. Mackintosh, E.E., Wilding, L.P. Smeck, N.E. and Hall, G.F., (1983) Dynamics and genetic modelling of soil system Pedogenesis and Soil Taxonomy. 1. Concepts and Interactions New York Elsevier 51–81 10.1016/S0166-2481(08)70598-1.Google Scholar
Soil Survey Staff, Soil Survey Manual. Handbook 18 (1951) Washington, D.C. US Department of Agriculture.Google Scholar
Soil Survey Staff (1999) Soil Taxonomy: A Basic System of Soil Classification of Making and Interpreting Soil Surveys. US Department of Agriculture, 436, 869 pp.Google Scholar
Tardy, Y. Bocquier, G. Paquet, H. and Millot, G., (1973) Formation of clay from granite and its distribution in relation to climate and topography Geoderma 10 271–284 10.1016/0016-7061(73)90002-5.Google Scholar
Velayutham, M. Mandal, D.K. Mandal, C. and Sehgal, J.L., (1999) Agro-Ecological Subregions of India for Development Planning Nagpur, India NBSS&LUP NBSS Bulletin No. 35 .Google Scholar
Velayutham, M. Pal, D.K. Bhattacharyya, T., Lal, R. Kimble, J.M. and Stewart, B.A., (2000) Organic carbon stock in soils of India Global Climate Change and Tropical Ecosystems Boca Raton, Florida, USA Lewis Publishers 71 95.Google Scholar
West, L.T. Drees, L.R. Wilding, L.P. and Rabenhorst, M.C., (1988) Differentiation of pedogenic and lithogenic carbonate forms in Texas Geoderma 43 271–287 10.1016/0016-7061(88)90047-X.Google Scholar
Wieder, M. and Yaalon, D.H., (1974) Effect of matrix composition on carbonate nodule crystallization Geoderma 11 95–121 10.1016/0016-7061(74)90010-X.Google Scholar
Wright, V.P. and Douglas, L.A., (1990) A micromorphological classification of fossil and recent calcic and petrocalcic microstructures Soil Micromorphology: A Basic and Applied Science Amsterdam Elsevier 401 407.Google Scholar
Yaalon, D.H., Wilding, L.P. Smeck, N.E. and Hall, G.F., (1983) Climate, time and soil development Pedogenesis and Taxonomy. I. Concepts and Interactions Amsterdam Elsevier 233–251 10.1016/S0166-2481(08)70603-2.Google Scholar