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Shale Diagenesis: A Case Study from the Albian Harmon Member (Peace River Formation), Western Canada

Published online by Cambridge University Press:  28 February 2024

J. Bloch  and
I. E. Hutcheon
J. Bloch*
Affiliation:
Department of Geology and Geophysics, The University of Calgary, Calgary, Alberta, Canada T2N 1N4
I. E. Hutcheon
Affiliation:
Department of Geology and Geophysics, The University of Calgary, Calgary, Alberta, Canada T2N 1N4
*
1Present address: Geological Survey of Canada, Institute of Sedimentary and Petroleum Geology, 3303 33rd St. N.W., Calgary, Alberta, Canada T2L 2A7.
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Abstract

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Shales have often been cited as the source of authigenic material that occurs in coarser grained sediments, but there are few comprehensive studies of diagenesis in shales that rigorously attempt to determine if they are sources for potentially mobile constituents or if they retain those constituents within the shale body. The silicate diagenesis of a Lower Cretaceous marine mudstone, the Harmon Member, was investigated by determining the bulk chemistry, clay mineral compositions and mineral modes using standard analytical techniques and linear programming. Changes in mineralogy are observed in hemipelagic laminated mudstones (LM) that are attributable to diagenesis despite relatively constant bulk compositions. These include authigenic kaolinite formation and illitization of detrital muscovite, K-feld-spar and authigenic kaolinite. No diagenetic trends in mineralogy are observed in rapid and episodically deposited transition zone (TZ) sediments because of primary (depositional) mineralogical variability. Diagenetic changes in mineral modes for shales of the Harmon Member are small, suggesting that silicate diagenesis proceeds under relatively “closed system” conditions. The occurrence of authigenic quartz suggests that much of the Si released from the dissolution of quartz and chert is precipitated within the Harmon Member. Al, Ti, and K apparently are conserved. Burial induced increase in temperature is inferred to be the primary control on silicate diagenesis within the Harmon Member.

Keywords

Clay mineralogyQuantitative shale mineralogySilicate diagenesis
Type
Research Article
Information
Clays and Clay Minerals , Volume 40 , Issue 6 , December 1992 , pp. 682 - 699
Copyright
Copyright © 1992, The Clay Minerals Society

References

Abercrombie, H. J., 1988 Water-rock interaction during diagenesis and thermal recovery, Cold Lake, Alberta .Google Scholar
Austin, G. S., Glass, H. D. and Hughes, R. E., 1989 Resolution of the polytype structure of some illitic clay minerals that appear to be 1 Md Clays & Clay Minerals 37 128 – 134 10.1346/CCMN.1989.0370203.CrossRefGoogle Scholar
Baedecker, P. A., 1987 ed. () Methods for geochemical analysis: U.S. Geol. Surv. Bull. 1770.Google Scholar
Bjørlykke, K., 1974 Geochemical and mineralogical influence of Ordovician island arcs on epicontinental clastic sedimentation. A study of Lower Paleozoic sedimentation in the Oslo region, Norway Sedimentology 21 251 – 272 10.1111/j.1365-3091.1974.tb02058.x.CrossRefGoogle Scholar
Bloch, J., 1989 Diagenesis and rock-fluid interaction of Cretaceous Harmon Member (Fort St. John Group) mudstones, Alberta and British Columbia .Google Scholar
Bloch, J., 1990 Stable isotopic composition of authigenic carbonates from the Albian Harmon Member (Peace River Formation): Evidence of early diagenetic processes Bull. Can. Pet. Geol. 38 39 – 52.Google Scholar
Bloch, J. and Krouse, H. R., 1992 Sulfide diagenesis and sedimentation in the Harmon Member, western Canada Jour. Sed. Pet. 62 235 – 249.Google Scholar
Boles, J. R., 1984 Secondary porosity reactions in the Stevens Sandstone, San Joachin Valley, California Clastic Diagenesis 37 217 – 234.Google Scholar
Boles, J. R. and Franks, S. G., 1979 Clay diagenesis in Wilcox sandstones of southwest Texas: Implications of smectite diagenesis on sandstone cementation Jour. Sed. Pet. 49 55 – 70.Google Scholar
Brimhall, G. H. and Dietrich, W. E., 1987 Constitutive mass balance relations between chemical composition, volume, density, porosity, and strain in metasomatic hydrochemical systems: Results on weathering and pedogenesis Geochim. Cosmochim. Acta 51 567 – 587 10.1016/0016-7037(87)90070-6.CrossRefGoogle Scholar
Brown, T. H., Berman, R. G. and Perkins, E. H., 1988 GEO-CALC: Software package for calculation and display of pressure-temperature-composition phase diagrams using an IBM or compatible personal computer Computers and Geosciences 14 279 – 289 10.1016/0098-3004(88)90061-1.CrossRefGoogle Scholar
Burtner, R. L. and Warner, M. A., 1986 Relationship between illite/smectite diagenesis and hydrocarbon generation in Lower Cretaceous Mowry and Skull Creek shales of the Northern Rocky Mountain Area Clays & Clay Minerals 34 390 – 402 10.1346/CCMN.1986.0340406.CrossRefGoogle Scholar
Crossey, L. J., 1985 The origin and role of water-soluble organic compounds in clastic diagenetic systems .Google Scholar
Englund, J. O. and Jorgensen, P., 1973 A chemical classification system for argillaceous sediments and factors affecting their composition Geol. fören Stockholm Förh. 95 87 – 97 10.1080/11035897309455428.CrossRefGoogle Scholar
Espitalié, J., Laporte, J. L., Madec, M., Marquis, F., Leplat, P., Paulet, J. and Boutefeu, A., 1977 Méthode rapide de caractérisation des roches méres de leur potentiel pétrolier et de leur degré d’évolution Rev. de Inst. Francais Pét. 32 23 – 42 10.2516/ogst:1977002.CrossRefGoogle Scholar
Evans, I. J. and Miles, D. L., 1989 Geochemical fluxes during shale diagenesis, an example from the Ordovician of Morocco Water-Rock Interaction WRI-6, Proceedings of the 6th Inter-nation Symposium on Water-Rock Interaction, Malvern, 3–8 August 1989 219 – 222.Google Scholar
Foscolos, A. E., Powell, T. G. and Gunther, P. R., 1976 The use of clay minerals and inorganic and organic geochemical indicators for evaluating the degree of diagenesis and oil generating potential of shales Geochim. Cosmochim. Acta 40 953 – 966 10.1016/0016-7037(76)90144-7.CrossRefGoogle Scholar
Foster, M. D., (1962) Interpretation of the composition and a classification of the chlorites: U.S. Geol. Surv. Prof. Pap. 414–A, 33 pp.Google Scholar
Gautier, D. L., 1986 Cretaceous shales from the western interior of North America: Sulfur/carbon ratios and sulfur-isotope composition Geology 14 225 – 228 10.1130/0091-7613(1986)14<225:CSFTWI>2.0.CO;2.2.0.CO;2>CrossRefGoogle Scholar
Gieskes, J. M., Blanc, G., Vrolijk, P., Elderfield, H. and Bames, R., 1990 Interstitial water chemistry—Major constituents Proc. Ocean Drill. Prog., Sci. Results 110 155 – 177.Google Scholar
Griffin, G. M., 1962 Regional clay-mineral facies—Products of weathering intensity and current distribution in the northeastern Gulf of Mexico Geol. Soc. Amer. Bull. 73 737 – 768 10.1130/0016-7606(1962)73[737:RCFOWI]2.0.CO;2.CrossRefGoogle Scholar
Hamilton, E. L., 1976 Variations of density and porosity with depth in deep-sea sediments Jour. Sed. Pet. 46 280 – 300.Google Scholar
Hart, B. S. and Plint, A. G., 1990 Upper Cretaceous warping and fault movement on the southern flank of the Peace River Arch, Alberta Bull. Can. Pet. Geol. 38A 190 – 195.Google Scholar
Hodgson, M. and Dudeney, A. W., 1984 Estimation of clay proportions in mixtures by X-ray diffraction and computerized mass balance Clays & Clay Minerals 32 19 – 28 10.1346/CCMN.1984.0320103.CrossRefGoogle Scholar
Hower, J. and Mowatt, T. C., 1966 The mineralogy of illites and mixed-layer illite/montmorillonites Amer. Mineral. 51 825 – 854.Google Scholar
Hower, J., Eslinger, E. V., Hower, M. E. and Perry, E. A., 1976 Mechanism of burial metamorphism of argillaceous sediment—1. Mineralogical and chemical evidence Bull. Geol. Soc. Amer. 87 725 – 737 10.1130/0016-7606(1976)87<725:MOBMOA>2.0.CO;2.2.0.CO;2>CrossRefGoogle Scholar
Huggett, J. M., 1986 An SEM study of phyllosilicate diagenesis in sandstones and mudstones in the Westphalian Coal Measures using back-scattered electron microscopy Clay Min. 21 603 – 616 10.1180/claymin.1986.021.4.11.CrossRefGoogle Scholar
Huggett, J. M. and White, S. H., 1982 High-voltage electron microscopy of authigenic clay minerals in sandstones Clays & Clay Minerals 30 232 – 236 10.1346/CCMN.1982.0300310.CrossRefGoogle Scholar
Ireland, B. J., Curtis, C. D. and Whiteman, J. A., 1983 Compositional variation within some glauconites and illites and implications for their stability and origins Sedimentology 30 769 – 786 10.1111/j.1365-3091.1983.tb00710.x.CrossRefGoogle Scholar
Johnson, L. J., Chu, C. H. and Hussey, G. A., 1985 Quantitative clay mineral analysis using simultaneous linear equations Clays & Clay Minerals 33 107 – 117 10.1346/CCMN.1985.0330204.CrossRefGoogle Scholar
Kalkreuth, W. and McMechan, M. E., 1984 Regional pattern of thermal maturation as determined from coal-rank studies, Rocky Mountain foothills and front ranges north of Grande Cache, Alberta—Implications for petroleum exploration Bull. Can. Pet. Geol. 32 249 – 271.Google Scholar
Kalkreuth, W. and McMechan, M. E., 1988 Burial history and thermal maturity, Rocky Mountain front ranges, foothills, and foreland, east-central British Columbia and adjacent Alberta, Canada Amer. Assoc. Pet. Geol. Bull. 72 1395 – 1410.Google Scholar
Kastner, M., Elderfield, H., Martin, J. B., Suess, E., Kven-volden, K. A. and Garrison, R. E., 1990 Diagenesis and interstitial-water chemistry at the Peruvian continental margin—major constituents and strontium isotopes Proc. Ocean Drill. Prog., Sci. Results 112 413 – 417.Google Scholar
Land, L. S., 1984 Frio Sandstone diagenesis, Texas Gulf Coast: A regional isotopic study Clastic Diagenesis 37 47 – 62.Google Scholar
Land, L. S. and Dutton, S. P., 1978 Cementation of a Pennsylvanian deltaic sandstone: Isotopic data Jour. Sed. Pet. 48 1167 – 1176.Google Scholar
Leckie, D. A., Kalkreuth, W. D. and Snowdon, L. R., 1988 Results of Rock-Eval/TOC analysis of a core through the Lower Cretaceous: Monkman Pass Area, northeastern British Columbia Amer. Assoc. Pet. Geol. Bull. 72 820 – 838.Google Scholar
Leckie, D. A., Staniland, M. R. and Hayes, B. J., 1990 Regional maps of the Albian Peace River and lower Shaftesbury formations on the Peace River Arch, northwestern Alberta and northeastern British Columbia Bull. Can. Pet. Geol. 38A 176 – 189.Google Scholar
Longstaffe, F. J., 1984 The role of meteoric diagenesis of shallow sandstones: Stable isotope studies of the Milk River aquifer and gas pool, southeastern Alberta Clastic Diagenesis 37 81 – 98.Google Scholar
Longstaffe, F. J., 1986 Oxygen isotope studies of diagenesis in the basal Belly River Sandstone, Pembina I-pool, Alberta Jour. Sed. Pet. 56 78 – 88.Google Scholar
Lundegard, P. D. and Land, L. S., 1986 Carbon dioxide and organic acids: Their role in porosity enhancement and diagenesis, Paleogene of the Texas Gulf Coast Soc. Econ. Paleon. Mineral. Spec. Pub. 38 129 – 146.Google Scholar
Mattes, B. W. and Mountjoy, E. W., 1980 Burial dolomitization of the Upper Miette buildup, Jasper National Park Concepts and Models of Dolomitization 28 259 – 297 10.2110/pec.80.28.0259.CrossRefGoogle Scholar
Maxwell, D. T. and Hower, J., 1967 High-grade diagenesis and low-grade metamorphism of illite in the Precambrian Belt Series Amer. Mineral. 52 843 – 857.Google Scholar
Milliken, K. L., McBride, E. F. and Land, L. S., 1989 Numerical assessment of dissolution vs replacement in the subsurface destruction of detrital feldspars, Oligocene Frio Formation, south Texas Jour. Sed. Pet. 59 740 – 757.Google Scholar
Morton, J. P., 1985 Rb-Sr evidence for punctuated illite/smectite diagenesis in the Oligocene Frio Formation, Texas Gulf Coast Geol. Soc. Amer. Bull. 96 114 – 122 10.1130/0016-7606(1985)96<114:REFPID>2.0.CO;2.2.0.CO;2>CrossRefGoogle Scholar
Norrish, K. and Hutton, J. T., 1969 An accurate X-ray spectrographic method for the analysis of a wide range of geological samples Geochim. Cosmochim. Acta 33 431 – 453 10.1016/0016-7037(69)90126-4.CrossRefGoogle Scholar
Pearson, M. J., 1978 Quantitative clay mineralogical analyses from the bulk chemistry of sedimentary rocks Clays & Clay Minerals 26 423 – 433 10.1346/CCMN.1978.0260606.CrossRefGoogle Scholar
Perry, E. and Hower, J., 1970 Burial diagenesis in Gulf Coast pelitic sediments Clays & Clay Minerals 18 165 – 177 10.1346/CCMN.1970.0180306.CrossRefGoogle Scholar
Petruk, W., 1964 Determination of the heavy atom content in chlorite by means of the X-ray diffractometer Amer. Mineral. 49 61 – 71.Google Scholar
Pollastro, R. M., 1985 Mineralogical and morphological evidence for the formation of illite at the expense of illite/smectite Clays & Clay Minerals 33 265 – 274 10.1346/CCMN.1985.0330401.CrossRefGoogle Scholar
Potter, P. E., Maynard, J. B. and Pryor, W. A., 1980 Sedimentology of Shale New York Springer-Verlag 10.1007/978-1-4612-9981-3.CrossRefGoogle Scholar
Powell, T. G., Foscolos, A. E., Gunther, P. R. and Snowdon, L. R., 1978 Diagenesis of organic matter and fine clay minerals: A comparative study Geochim. Cosmochim. Acta 42 1181 – 1197 10.1016/0016-7037(78)90113-8.CrossRefGoogle Scholar
Pye, K. and Krinsley, D. H., 1984 Petrographic examination of sedimentary rocks in the SEM using backscattered electron detectors Jour. Sed. Pet. 54 877 – 888.Google Scholar
Ross, C. S. and Hendricks, S. B., 1945 Minerals of the montmorillonite group, their origin and relation to soils and clays U.S. Geol. Sum. Prof. Pap. 23 – 72.CrossRefGoogle Scholar
Sayles, F. L., 1979 The composition and diagenesis of interstitial solutions— 1: Fluxes across the seawater-sediment interface in the Atlantic Ocean Geochim. Cosmochim. Acta 43 527 – 545 10.1016/0016-7037(79)90163-7.CrossRefGoogle Scholar
Schultz, L. G., 1978 Mixed-layer clay in the Pierre Shale and equivalent rocks, Northern Great Plains Region U.S. Geol. Surv. Prof. Pap. .CrossRefGoogle Scholar
Schultz, L. G., Tourtelot, H. A., Gill, J. R., and Boerngen, J. G., (1980) Composition and properties of the Pierre Shale and equivalent rocks, Northern Great Plains region: U.S. Geol. Surv. Prof. Pap. 1064–B, 114 pp.Google Scholar
Shaw, D. B. and Weaver, C. E., 1965 The mineralogical composition of shales Jour. Sed. Pet. 35 213 – 222.Google Scholar
Shaw, H. F. and Primmer, T. J., 1989 Diagenesis in shales from a partly overpressured sequence in the Gulf Coast, Texas, USA Mar. Pet. Geol. 6 121 – 128 10.1016/0264-8172(89)90015-9.CrossRefGoogle Scholar
Sibley, D. F. and Blatt, H., 1976 Intergranular pressure solution and cementation of the Tuscarora orthoquartzite Jour. Sed. Pet. 46 881 – 896.Google Scholar
Slaughter, M., 1989 Quantitative determination of clays and other minerals in rocks Quantitative Mineral Analysis of Clays 1 120 – 153.Google Scholar
Srodon, J., 1984 X-ray powder diffraction identification of illitic materials Clays & Clay Minerals 32 337 – 349 10.1346/CCMN.1984.0320501.CrossRefGoogle Scholar
Stelck, C. R. and Leckie, D., 1988 Foraminiferal inventory and lithologic description of the Lower Cretaceous (Albian) Hulcross shale, Monkman area, northeastern British Columbia Can. Jour. Ear. Sci. 25 793 – 798 10.1139/e88-076.CrossRefGoogle Scholar
Stott, D. F., (1968) Lower Cretaceous Bullhead and Fort St. John Groups, between Smoky and Peace rivers, Rocky Mountain foothills, Alberta and British Columbia: Geol. Surv. Can. Bull. 152, 279 pp.Google Scholar
Sullivan, K. B. and McBride, E. F., 1991 Diagenesis of sandstones at shale contacts and diagenetic heterogeneity, Frio Formation, Texas Amer. Assoc. Pet. Geol. Bull. 75 121 – 138.Google Scholar
Teichmüller, M. and Durand, B., 1983 Fluorescence microscopical rank studies on liptinites and vitrinites in peat and coals and comparison with the results of the Rock-Eval pyrolysis Inter. Jour. Coal Geol. 2 197 – 230 10.1016/0166-5162(83)90001-0.CrossRefGoogle Scholar
Tilley, B. J. and Longstaffe, F. J., 1989 Diagenesis and isotopic evolution of porewaters in the Alberta Deep Basin: The Falher Member and Cadomin Formation Geochim. Cosmochim. Acta 53 2529 – 2546 10.1016/0016-7037(89)90126-9.CrossRefGoogle Scholar
Weaver, C. E. and Pollard, L. D., 1973 The Chemistry of Clay Minerals: Developments in Sedimentology 15 New York Elsevier.Google Scholar
Whittle, C. K., 1986 Comparison of sedimentary chlorite compositions by X-ray diffraction and analytical TEM Clay Miner. 21 937 – 947 10.1180/claymin.1986.021.5.07.CrossRefGoogle Scholar
Yanagi, T., Baadsgaard, H., Stelck, C. R. and McDougall, I., 1988 Radiometric dating of a tuff bed in the middle Albian Hulcross Formation at Hudson’s Hope, British Columbia Can. Jour. Earth Sci. 25 1123 – 1127 10.1139/e88-109.CrossRefGoogle Scholar
Zachos, J. C. and Cederburg, T., 1989 Interstitial Water Chemistry: Sites 645, 646, and 647, Baffin Bay and Labrador Sea Proc. Ocean Drill. Prog. Sci. Results 115 171 – 183.Google Scholar