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Reaction Scheme for the Oxidation of as(III) to as(V) by Birnessite

Published online by Cambridge University Press:  02 April 2024

Johnnie N. Moore ,
Jeffrey R. Walker  and
Thomas H. Hayes
Johnnie N. Moore
Affiliation:
Department of Geology, University of Montana, Missoula, Montana 59812
Jeffrey R. Walker
Affiliation:
Department of Geology, Vassar College, Poughkeepsie, New York 12601
Thomas H. Hayes
Affiliation:
Department of Chemistry, University of Montana, Missoula, Montana 59812
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Abstract

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The oxidation of As(III) to As(V) by K-birnessite was examined at different temperatures, pHs, and birnessite/As(III) ratios. Experiments ranged in duration from 5 to 64 hr, and solution and solid products were determined at several intervals. All experiments showed that the reaction produced large amounts of K+ to solution and very little Mn2+. As(V) was released to solution and incorporated into the K-birnessite. The oxidation was initially rapid and then slowed. The oxidation of As(III) was probably facilitated initially by autocatalytic Mn-As(V) reactions occurring mostly in the interlayer, in which large amounts of As(V) and K+ could be easily released to solution. The reaction also slowed when interlayer Mn was exhausted by forming Mn-As(V) complexes. Mn(IV) could only be acquired from the octahedral sheets of the birnessite. The two-stage reaction process proposed here depended on the layered structure of birnessite, the specific surface, and presence of exchangeable cations in K-birnessite.

Keywords

ArsenicBirnessiteOxidationPotassiumSolution
Type
Research Article
Information
Clays and Clay Minerals , Volume 38 , Issue 5 , October 1990 , pp. 549 - 555
Copyright
Copyright © 1990, The Clay Minerals Society

References

Burns, R. G. and Bums, V. M., 1977 The mineralogy and crystal chemistry of deep-sea manganese nodules, a poly-metallic resource of the twenty-first century Phil. Trans. R. Soc. Lond. A. 286 283 – 301.Google Scholar
Catti, M. M. and Franchini-Angela, M., 1979 Krautite, Mn(H2O)(As03OH): Crystal structure, hydrogen bonding and relations with haidingerite and pharmacolite Amer. Mineral. 64 1248 – 1254.Google Scholar
Coddington, K., 1986 A review of arsenals in biology Tox. Environ. Chem. 11 281 – 290.CrossRefGoogle Scholar
Crowther, D. L., Dillard, J. G. and Murray, J. W., 1983 The mechanism of Co(II) oxidation on synthetic birnessite Geochim. Cosmochim. Acta 47 1399 – 1403.CrossRefGoogle Scholar
Ferguson, J. F. and Gavis, J., 1972 A review of the arsenic cycle in natural waters Water Research 6 1259 – 1274.CrossRefGoogle Scholar
Ficklin, W. H., 1983 Separation of arsenic(III) and arse-nic(V) in ground waters by ion-exchange Talanta 5 371 – 373.CrossRefGoogle Scholar
Giovanoli, R., Stähl, E. and Feitknecht, W., 1970 Über Oxidhydroxide des vierwertigen Mangans mit Schichtengitter, 2. Mitteilung: Mangan(III)-manganat(IV) Heb. Chitn. Acta 53 453 – 464.CrossRefGoogle Scholar
Giovanoli, R., Stähl, E. and Feitknecht, W., 1970 Über Oxidhydroxide des vierwertigen Mangans mit Schichtengitter, 1. Mitteilung: Natriummangan(II, Hl)manganat(IV) Heb. Chim. Acta 53 209 – 220.CrossRefGoogle Scholar
Golden, D. C., Dixon, J. B. and Chen, C. C., 1986 Ion exchange, thermal transformations, and oxidizing properties of birnessite Clays & Clay Minerals 34 511 – 520.CrossRefGoogle Scholar
Healy, T. W., Herring, A. P. and Fuerstenau, D. W., 1966 Effect of crystal structure on the surface properties of a series of manganese dioxides J. Colloid Interface Sci. 21 435 – 444.CrossRefGoogle Scholar
Hem, J. D., 1979 Redox processes at surfaces of manganese oxide and their effects on aqueous metal ions Chemical Geol. 21 199 – 218.CrossRefGoogle Scholar
Hem, J. D., 1980 Redox coprecipitation mechanisms of maganese oxides Particulates in Water 189 45 – 72.CrossRefGoogle Scholar
Hem, J.D., 1981 Rates ofmanganese oxidation in aqueous systems Geochim. Cosmochim. Acta 45 1369 – 1374.CrossRefGoogle Scholar
Jenne, E. A., 1968 Controls on Mn, Fe, Co, Ni, Cu, and Zn concentrations in soils and waters: American Chemical Society, Washington, D.C. Adv. Chem. Ser. 73 337 – 387.CrossRefGoogle Scholar
Jones, H. L. P. and Milne, A. A., 1956 Birnessite, a new manganese oxide mineral from Aberdeenshire, Scotland Mineral. Mag. 31 283 – 288.Google Scholar
Krishnamurti, G. S. R. and Huang, P. M., 1987 The catalytic role of birnessite in the transformation of iron Can. J. Soil Sci. 67 533 – 543.CrossRefGoogle Scholar
Lind, C. J., 1988 Hausmanite (Mn3O4) conversion to manganile (7-MnOOH) in dilute oxalate solution Envir. Sci. Tech. 22 62 – 70.CrossRefGoogle Scholar
Martin, J. M. and Meybeck, M., 1979 Elemental mass balance of material carried by major world rivers Mar. Chem. 7 173 – 206.CrossRefGoogle Scholar
McKenzie, R. M., 1971 The synthesis of birnessite, cryp-tomelene, and some other oxides and hydroxides of manganese Mineral. Mag. 38 493 – 502.CrossRefGoogle Scholar
Murray, J. W., 1975 The interaction of cobalt with hydrous manganese dioxide Geochim. Cosmochim. Acta 39 635 – 647.CrossRefGoogle Scholar
Oscarson, D. W., Huang, P. M., Defosse, C. and Herbillo, A., 1981 Oxidative power of Mn(IV) and Fe(III) oxides with respect to As(III) in terrestrial and aquatic environments Nature 291 50 – 51.CrossRefGoogle Scholar
Oscarson, D. W., Huang, P. M. and Liaw, W. K., 1980 The oxidation of arsenite by aquatic sediments J. Envir. Qual. 9 700 – 703.CrossRefGoogle Scholar
Oscarson, D. W., Huang, P. M. and Liaw, W. K., 1981 The role ofmanganese in the oxidation of arsenite by freshwater lake sediments Clays & Clay Minerals 29 219 – 225.CrossRefGoogle Scholar
Oscarson, D. W., Huang, P. M., Liaw, W. K. and Hammer, U. T., 1983 Kinetics of oxidation of arsenite by various manganese dioxides Soil Sci. Amer. J. 47 644 – 648.CrossRefGoogle Scholar
Pascal, P., 1966 Nouveau Traité de Chimie Minerale, Vol. 26 Paris Masson.Google Scholar
Stouff, P. and Boulegue, J., 1988 Synthetic 10Â and 7Â phyllomanganates: Their structures determined by EXAFS Amer. Mineral. 73 1162 – 1169.Google Scholar
Turner, S. and Buseck, P. R., 1981 Todorokites: A new family of naturally occurring manganese oxides Science 212 1024 – 1027.CrossRefGoogle ScholarPubMed
Wangersky, P. J., 1986 Biological control of trace metal residence time and speciation: A review and synthesis Mar. Chem. 18 269 – 297.CrossRefGoogle Scholar