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Randomly Interstratified Kaolinite-Smectite from Galicia (NW Spain): A New Procedure for Determination

Published online by Cambridge University Press:  28 February 2024

Giuseppe Corti
Affiliation:
Dipartimento di Scienza del Suolo e Nutrizione della Pianta, Piazzale delle Cascine 28, 50144 Firenze, Italy
Maria Jose Fernández Sanjurjo
Affiliation:
Departamento de Edafología y Química Agrícola, Facultad de Biología, 15706 Santiago de Compostela, Spain
Fiorenzo Cesare Ugolini
Affiliation:
Dipartimento di Scienza del Suolo e Nutrizione della Pianta, Piazzale delle Cascine 28, 50144 Firenze, Italy
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Abstract

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A new protocol was developed to examine an assemblage of kaolinite-smectite in a buried horizon of a paleosol developed on gabbro parent material. The new extraction procedure appears suitable for removing kaolinite and for ascertaining the nature of the smectite interstratified with kaolinite. Smectite was identified by X-ray diffraction (XRD) and infrared (IR) patterns, cation exchange capacity (CEC) and chemical analyses.

The results obtained provide for increased understanding of the process of transformation of smectite into kaolinite.

Type
Research Article
Copyright
Copyright © 1998, The Clay Minerals Society

References

Altschuler, Z.S. Dwornik, E.J. and Kramer, H., 1963 Transformation of montmorillonite to kaolinite during weathering Science 141 148152 10.1126/science.141.3576.148.CrossRefGoogle ScholarPubMed
Barnhisel, R.I. Bertsch, P.M., Dixon, J.B. and Weed, S.B., 1989 Chlorites and hydroxy-in-terlayered vermiculite and smectite Minerals in soil environment 2nd Madison, WI Soil Sci Soc Am 729788.Google Scholar
Carson, C.D. and Kunze, G.W., 1970 New occurrences of tubular halloysite Soil Sci Soc Am Proc 34 538540 10.2136/sssaj1970.03615995003400030049x.CrossRefGoogle Scholar
Corti, G. and Fernández Sanjurjo, M.J., 1993 Trasformazione pedogenetica di smectite in caolinite in un suolo acido della Galizia (Spagna) Quaderni di Scienza del Suolo 5 522.Google Scholar
Cuadros, J. Delgado, A. Cardenete, A. Reyes, E. and Linares, J., 1994 Kaolinite/montmorillonite resembles beidellite Clays Clay Miner 42 643651 10.1346/CCMN.1994.0420517.CrossRefGoogle Scholar
Delvaux, B. Herbillon, A.J. Vielvoye, L. and Mestdagh, M.M., 1990 Surface properties and clay mineralogy of hydrated halloy-sitic soil clays. II: Evidence for the presence of halloysite/smectite (H/Sm) mixed layer clays Clay Miner 25 141160 10.1180/claymin.1990.025.2.02.CrossRefGoogle Scholar
García-Rodeja, E. Silva, B.M. and Macías, V. F., 1987 An-dosols developed from non-volcanic materials in Galicia, NW Spain J Soil Sci 38 573591 10.1111/j.1365-2389.1987.tb02156.x.CrossRefGoogle Scholar
Herbillon, A.J. Frankart, R. and Vielvoye, L., 1981 An occurrence of interstratified kaolinite-smectite minerals in a red-black soil toposequence Clay Miner 16 195201 10.1180/claymin.1981.016.2.07.CrossRefGoogle Scholar
Jackson, M.L., 1962 Interlayering of expansible layer silicates in soils by chemical weathering Clays Clay Miner 11 2946 10.1346/CCMN.1962.0110104.CrossRefGoogle Scholar
Karathanasis, A.D. and Hajek, B.F., 1983 Transformation of smectite to kaolinite in naturally acid soil systems: Structural and thermodynamic consideration Soil Sci Soc Am J 47 158163 10.2136/sssaj1983.03615995004700010031x.CrossRefGoogle Scholar
Kukovsky, E.G., 1969 Alteration processes in clay minerals Clay Miner 8 19691970 10.1180/claymin.1969.008.2.12.CrossRefGoogle Scholar
Kunze, G.W. and Bradley, W.F., 1964 Occurrence of tubular halloy-site in a Texas soil Clays Clay Miner 12 523527 10.1346/CCMN.1963.0120145.CrossRefGoogle Scholar
Lavkulich, L.M. and Wiens, J.H., 1970 Comparison of organic matter destruction by hydrogen peroxide and sodium hypochlorite and its effect on selected mineral constituents Soil Sci Soc Am Proc 34 755758 10.2136/sssaj1970.03615995003400050025x.CrossRefGoogle Scholar
Macías Vázquez, F. Puga Pereira, M. and Guitián Ojea, F., 1978 Suelos de la zona hùmeda española Anales de Edafología y Agrobiología 37 117138.Google Scholar
Mehra, O.P. and Jackson, M.L., 1960 Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate Clays Clay Miner 7 317327 10.1346/CCMN.1958.0070122.CrossRefGoogle Scholar
Norrish, K. and Pickering, J.G., 1983 Clay minerals Soils: An Australia viewpoint. Melbourne: CSIRO London Academic Pr 281308.Google Scholar
Oberlin, A. and Couty, R., 1970 Conditions of kaolinite formation during alteration of some silicates by water at 200°C Clays Clay Miner 18 347356 10.1346/CCMN.1970.0180607.CrossRefGoogle Scholar
Oinuma, K. and Hayashi, H., 1965 Infrared study of mixed-layer clay minerals Am Mineral 50 12131227.Google Scholar
Pal, D.K. Deshpande, S.B. Venugopal, K.R. and Kaibande, A.R., 1989 Formation of di- and trioctahedral smectite as evidence for paleoclimatic changes in southern and central peninsular India Geoderma 45 175184 10.1016/0016-7061(89)90049-9.CrossRefGoogle Scholar
Poncelet, G.M. and Brindley, G.W., 1967 Experimental formation of kaolinite from montmorillonite at low temperatures Am Mineral 52 11611173.Google Scholar
Quantin, P. Herbillon, A.J. Janot, C. and Siefferman, G., 1984 L’“halloysite” blanche riche en fer de Vate (Vanuatu). Hypothèse d’un edifice interstratifié halloysite-hisingerite Clay Miner 19 629643 10.1180/claymin.1984.019.4.09.CrossRefGoogle Scholar
Rich, C.I., 1968 Hydroxy interlayers in expansible layer silicates Clays Clay Miner 16 1530 10.1346/CCMN.1968.0160104.CrossRefGoogle Scholar
Rich, C.I. and Obenshain, S.S., 1955 Chemical and clay mineral properties of a red-yellow podzolic soil derived from mus-covite schist Soil Sci Soc Am Proc 19 334339 10.2136/sssaj1955.03615995001900030021x.CrossRefGoogle Scholar
Robinson, D. and Wright, V.P., 1987 Ordered illite-smectite and kaolinite-smectite: Pedogenic mineral in a Low Carboniferous paleosol sequence, South Wales Clay Miner 22 109118 10.1180/claymin.1987.022.1.09.CrossRefGoogle Scholar
Sahkarov, B.A. and Drits, V.A., 1973 Mixed-layer kaolinite-mont-morillonite: A comparison of observed and calculated diffraction patterns Clays Clay Miner 21 1517 10.1346/CCMN.1973.0210104.CrossRefGoogle Scholar
Sawhney, B.L., Dixon, J.B. and Weed, S.B., 1989 Interstratification in layer silicates Minerals in soil environment 2nd Madison, WI Soil Sci Soc Am 789828.Google Scholar
Serratosa, J.M. Hidalgo, A. and Vinas, J.M., 1962 Orientation of OH bands in kaolinite Nature 195 486487 10.1038/195486a0.CrossRefGoogle Scholar
Shultz, L.G. Shepard, A.O. Blackmon, P.D. and Starkey, H.C., 1971 Mixed-layer kaolinite-montmorillonite from the Yucatan peninsula, Mexico Clays Clay Miner 19 137150 10.1346/CCMN.1971.0190302.CrossRefGoogle Scholar
Soil Survey Staff., 1996 Keys to soil taxonomy 7th Washington, DC USDA, NRCS, USGPO.Google Scholar
Sudo, T. and Hayashi, H., 1956 A randomly interstratified kaolin-montmorillonite in acid clay deposits in Japan Nature 178 11151116 10.1038/1781115b0.CrossRefGoogle Scholar
Tessier, D., 1984 Etude expérimentale de l’organisation des matériaux argileux. Hydratation, gonflement et structuration au cours de la dessiccation et de la réhumectation [Ph.D. thesis] Paris, France Univ de Paris VIL.Google Scholar
Thiry, M., 1982 Les kaolinites de Provins: Géologie et cris-tallinité Bull Mineral 105 521526.Google Scholar
Thiry, M. and Weber, F., 1977 Convergence de comportement entre les interstratifiés kaolinite-smectite et les fire-clays Clay Miner 12 8391 10.1180/claymin.1977.012.1.08.CrossRefGoogle Scholar
Wada, K. and Kakuto, Y., 1983 Intergradient vermiculite-kaolin mineral in a Korean Ultisol Clays Clay Miner 31 183190 10.1346/CCMN.1983.0310303.CrossRefGoogle Scholar
Watanabe, T. Sawada, Y. Russell, J.D. McHardy, W.J. and Wilson, M.J., 1992 The conversion of montmorillonite to interstratified halloysite-smectite by weathering in the Orni Acid Clay Deposit, Japan Clay Miner 27 159173 10.1180/claymin.1992.027.2.02.CrossRefGoogle Scholar
Wiewióra, A., 1971 A mixed layer kaolinite-smectite from Lower Silesia, Poland Clays Clay Miner 19 415416 10.1346/CCMN.1971.0190610.CrossRefGoogle Scholar
Wiewióra, A. and Serratosa, J.M., 1973 Mixed-layer kaolinite-smectite from Lower Silesia, Poland: Final report Proc Int Clay Conf; 1972; Madrid Spain. Madrid Division de Ciencias, CSIC 7588.Google Scholar
Wilson, M.J. and Cradwick, P.D., 1972 Occurrence of interstratified kaolinite-montmorillonite in some Scottish soils Clay Miner 9 435437 10.1180/claymin.1972.009.4.08.CrossRefGoogle Scholar
Yerima, B.P.K. Calhoun, F.G. Senkayi, A.L. and Dixon, J.B., 1985 Occurrence of interstratified kaolinite-smectite in El Salvador vertisols Soil Sci Soc Am J 49 462466 10.2136/sssaj1985.03615995004900020038x.CrossRefGoogle Scholar