Hostname: page-component-78c5997874-s2hrs Total loading time: 0 Render date: 2024-11-14T17:22:20.397Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation of Organo-Montmorillonites and the Relationship Between Microstructure and Swellability

Published online by Cambridge University Press:  01 January 2024

Wei Hua Yu ,
Ting Ting Zhu ,
Dong Shen Tong ,
Min Wang ,
Qi Qi Wu  and
Chun Hui Zhou
Wei Hua Yu
Affiliation:
Zhijiang College, Zhejiang University of Technology, 312030, Shaoxing, China Research Group for Advanced Materials & Sustainable Catalysis (AMSC), State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China
Ting Ting Zhu
Affiliation:
Research Group for Advanced Materials & Sustainable Catalysis (AMSC), State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China
Dong Shen Tong
Affiliation:
Research Group for Advanced Materials & Sustainable Catalysis (AMSC), State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China
Min Wang
Affiliation:
Research Group for Advanced Materials & Sustainable Catalysis (AMSC), State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China
Qi Qi Wu
Affiliation:
Research Group for Advanced Materials & Sustainable Catalysis (AMSC), State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China
Chun Hui Zhou*
Affiliation:
Research Group for Advanced Materials & Sustainable Catalysis (AMSC), State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China Centre for Future Materials, University of Southern Queensland, 4350, Toowoomba, Queensland, Australia Engineering Research Center of Non-metallic Minerals of Zhejiang Province, Zhejiang Institute of Geology and Mineral Resource, 310007, Hangzhou, China Qing Yang Institute for Industrial Minerals (QYIM), Youhua Township, Qingyang County, 242804, Anhui, China
*
*E-mail address of corresponding author: [email protected][email protected]
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Hydrophobicity, swellability, and dispersion are important properties for organo-montmorillonites (OMnt) and have yet to be fully characterized for all OMnt configurations. The purpose of the present work was to examine the preparation of OMnt from the reaction of Ca2+-montmorillonite (Ca2+-Mnt) with a high concentration of surfactant and to reveal the relevant properties of hydrophobicity and dispersion of the resultant OMnt. A series of OMnt samples were prepared using a small amount of water and cetyltrimethylammonium bromide (CTAB) with a concentration more than the CTAB critical micelle concentration (CMC). The relationship between OMnt microstructure and the hydrophobicity and swellability properties was investigated in detail. The resulting OMnt samples were characterized using powder X-ray diffraction patterns (XRD), Fourier-transform infrared (FTIR) spectroscopy, thermogravimetric and differential thermogravimetry (TG-DTG), water contact angle tests, swelling indices, and transmission electron microscopy (TEM). The addition of CTAB and water in the OMnt preparation affected the OMnt microstructure and properties. An increase in CTAB concentration led to a more ordered arrangement of cetyltrimethylammonium (CTA+) cations in the interlayer space of the OMnt and a large amount of CTA+ cations on the outer surfaces of the OMnt. The swelling indices and the water contact angles of OMnt samples depended on the distribution of the CTAB surfactant on OMnt and the orientation of the surfactant hydrophilic groups on the inner and on the outer surfaces of OMnt. A maximum swelling index of 39 mL/g in xylene was achieved with an average water contact angle of 62.0° ± 2.0° when the amount of CTAB added was 2 times the cation exchange capacity (CEC) of Mnt and the lowest water to dry Mnt mass ratio was 3 during the preparation of OMnt samples. The platelets of OMnt aggregated together in xylene by electrostatic attraction and by hydrophobic interactions.

Keywords

AdsorptionCetyltrimethylammonium BromideCTABHexadecyltrimethylammonium BromideMontmorilloniteOrganoclaySurfactant
Type
Article
Information
Clays and Clay Minerals , Volume 65 , Issue 6 , December 2017 , pp. 417 - 430
Copyright
Copyright © Clay Minerals Society 2017

References

Alghunaim, A. Kirdponpattara, S. and Newby, B.M.Z., 2016 Techniques for determining contact angle and wettability of powders Powder Technology 287 201–215.CrossRefGoogle Scholar
Ballah, J. Chamerois, M. Durand-Vidal, S. Malikova, N. Levitz, P. and Michot, L.J., 2016 Effect of chemical and geometrical parameters influencing the wettability of smectite clay films Colloids and Surfaces A: Physicochemical and Engineering Aspects 511 255–263.CrossRefGoogle Scholar
Burgentzlé, D. Duchet, J. Gérard, J.F. Jupin, A. and Fillon, B., 2004 Solvent-based nanocomposite coatings: I. Dispersion of organophilic montmorillonite in organic solvents Journal of Colloid and Interface Science 26–39.CrossRefGoogle Scholar
Chang, J.H. An, Y.U. Cho, D. and Giannelis, E.P., 2003 Poly(lactic acid) nanocomposites: Comparison of their properties with montmorillonite and synthetic mica (II) Polymer 44 3715–3720.CrossRefGoogle Scholar
Chen, H.F. Koopal, L.K. Xiong, J. Avena, M. and Tan, W.F., 2017 Mechanisms of soil humic acid adsorption onto montmorillonite and kaolinite Journal of Colloid and Interface Science 504 457–467.CrossRefGoogle Scholar
Cipriano, B.H. Raghavan, S.R. and McGuiggan, P.M., 2005 Surface tension and contact angle measurements of a hexadecyl imidazolium surfactant adsorbed on a clay surface Colloids and Surfaces A: Physicochemical and Engineering Aspects 262 8–13.CrossRefGoogle Scholar
De Santana, H. Toni, L.R.M. Benetoli, L.O.B. Zaia, CTBV Zaia, D.A.M. and Rosa, M., 2006 Effect in glyphosate adsorption on clays and soils heated and characterization by FT-IR spectroscopy Geoderma 136 738–750.CrossRefGoogle Scholar
Dultz, S. Riebe, B. and Bunnenberg, C., 2005 Temperature effects on iodine adsorption on organo-clay minerals: II Structural effects. Applied Clay Science 28 17–30.CrossRefGoogle Scholar
Ebrahimi, D. Pellenq, R.J.M. and Whittle, A.J., 2016 Mesoscale simulation of clay aggregate formation and mechanical properties Granular Matter 18 49.CrossRefGoogle Scholar
Feng, X. Hua, G. Meng, X. Ding, Y. Zhang, S. and Yang, M., 2009 Influence of ethanol addition on the modification of montmorillonite by hexadecyl trimethylammonium bromide Applied Clay Science 45 239–243.CrossRefGoogle Scholar
Greaves, M. P. and Wilson, M. J., 1969 The adsorption of nucleic acids by montmorillonite Soil Biology and Biochemistry 1 317–323.CrossRefGoogle Scholar
Grim, R.E., 1968 Clay Mineralogy New York McGraw Hill.Google Scholar
Hayakawa, T. Minase, M. Fujita, K.I. and Ogawa, M., 2016 Modified method for bentonite purification and characterization; A case study using bentonite from Tsunagi Mine, Niigata, Japan Clays and Clay Minerals 64 275–282.CrossRefGoogle Scholar
He, H.P. Frost, R.L. and Zhu, J.X., 2004 Infrared study of HDTMA+ intercalated montmorillonite Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 60 2853–2859.Google Scholar
He, H.P. Ding, Z. Zhu, J.X. Yuan, P. Xi, Y.F. Yang, D. and Frost, R.L., 2005 Thermal characterization of surfactantmodified montmorillonites Clays and Clay Minerals 53 287–293.CrossRefGoogle Scholar
He, H.P. Frost, R.L. Bostrom, T. Yuan, P. Duong, L. Yang, D. Xi, Y.F. and Kloprogge, J.T., 2006a Changes in the morphology of organoclays with HDTMA+ surfactant loading Applied Clay Science 31 262–271.CrossRefGoogle Scholar
He, H.P. Zhou, Q. Martens, W.N. Kloprogge, J.T. Yuan, P. Xi, Y.F. Zhu, J.X. and Frost, R.L., 2006b Microstructure of HDTMA+-modified montmorillonite and its influence on sorption characteristics Clays and Clay Minerals 54 691–698.CrossRefGoogle Scholar
Hu, Z. He, G. Liu, Y. Dong, C. Wu, X. and Zhao, W., 2013 Effects of surfactant concentration on alkyl chain arrangements in dry and swollen organic montmorillonite Applied Clay Science 75-76 134–140.CrossRefGoogle Scholar
Kahr, G. and Madsen, F.T., 1995 Determination of the cation exchange capacity and the surface area of bentonite, illite and kaolinite by methylene blue adsorption Applied Clay Science 9 327–336.CrossRefGoogle Scholar
Khenifi, A. Bouberka, Z. Sekrane, F. Kameche, M. and Derriche, Z., 2007 Adsorption study of an industrial dye by an organic clay Adsorption-Journal of the International Adsorption Society 13 149–158.CrossRefGoogle Scholar
Khajehpour, M. Gelves, G.A. and Sundararaj, U., 2015 Modification of montmorillonite with alkyl silanes and fluorosurfactant for clay/fluoroelastomer (FKM) nanocomposites Clay and Clay Minerals 63 1–14.CrossRefGoogle Scholar
Klebow, B. and Meleshyn, A., 2012 Monte Carlo study of the adsorption and aggregation of alkyltrimethylammonium chloride on the montmorilloni te-water interface Langmuir 28 13274–13283.CrossRefGoogle Scholar
Kooli, F., 2013 Effect of C16TMA contents on the thermal stability of organo-bentonites: In situ X-ray diffraction analysis Thermochimica Acta 551 7–13.CrossRefGoogle Scholar
Kraepiel, A.M.L. Keller, K. and Morel, F.M.M., 1998 On the acid-base chemistry of permanently charged minerals Environmental Science & Technology 32 2829–2838.CrossRefGoogle Scholar
Lagaly, G. Ogawa, M. Dékány, I., Bergaya, F. and Lagaly, G., 2013 Clay mineralorganic interaction Handbook of Clay Science: Part A, Fundamentals Amsterdam Elsevier 435–505.CrossRefGoogle Scholar
Lapides, I. Borisover, M. and Yariv, S., 2011 Thermal analysis of hexadecyltrimethylammonium-montmorillonites Journal of Thermal Analysis and Calorimetry 105 921–929.CrossRefGoogle Scholar
Li, Y. Q. and Ishida, H., 2003 Concentration-dependent conformation of alkyl tail in the nanoconfined space: Hexadecylamine in the silicate galleries Langmuir 19 2479–2484.CrossRefGoogle Scholar
Li, Z.H. Jiang, W.T. Chen, C.J. and Hong, H.L., 2010 Influence of chain lengths and loading levels on interlayer configurations of intercalated alkylammonium and their transitions in rectorite Langmuir 26 8289–8294.CrossRefGoogle ScholarPubMed
Lin, K.J. Jeng, U.S. and Lin, K.F., 2011 Adsorption and intercalation processes of ionic surfactants on montmorillonite associated with their ionic charge Materials Chemistry and Physics 131 120–126.CrossRefGoogle Scholar
Liu, B. Wang, X. Yang, B. and Sun, R., 2011 Rapid modification of montmorillonite with novel cationic Gemini surfactants and its adsorption for methyl orange Materials Chemistry and Physics 130 1220–1226.CrossRefGoogle Scholar
Ma, L. Zhu, J. Xi, Y. Zhu, R. He, H. Liang, X. and Ayoko, G.A., 2016 Adsorption of phenol, phosphate and Cd(II) by inorganic-organic montmorillonites: A comparative study of single and multiple solute Colloids and Surfaces A-Physicochemical and Engineering Aspects 497 63–71.Google Scholar
Meleshyn, A. and Bunnenberg, C., 2006 Interlayer expansion and mechanisms of anion sorption of Na-montmorillonite modified by cetylpyridinium chloride: A Monte Carlo study The Journal of Physical Chemistry B 110 2271–2277.CrossRefGoogle ScholarPubMed
Moslemizadeh, A. Aghdam, S.K. Shahbazi, K. Aghdam, H.K. and Alboghobeish, F., 2016 Assessment of swelling inhibitive effect of CTAB adsorption on montmorillonite in aqueous phase Applied Clay Science 127-128 111–122.CrossRefGoogle Scholar
Mouzon, J. Bhuiyan, I.U. and Hedlund, J., 2016 The structure of montmorillonite gels revealed by sequential cryo-XHR-SEM imaging Journal of Colloid and Interface Science 465 58–66.CrossRefGoogle ScholarPubMed
Paget, E. and Simonet, P., 1994 On the track of natural transformation in soil FEMS Microbiology Ecology 15 109–117.CrossRefGoogle Scholar
Pluart, L. Duchet, J. Sautereau, H. Halley, P. and Gerard, J.F., 2004 Rheological properties of organoclay suspensions in epoxy network precursors Applied Clay Science 25 207–219.CrossRefGoogle Scholar
Scholtzová, E. Madejová, J. Jankovič, L.U. and Tunega, D., 2016 Structural and spectroscopic characterization of montmorillonite intercalated with N-butylammonium cations (N = 1−4) - Modeling and experimental study Clays and Clay Minerals 64 401–412.CrossRefGoogle Scholar
Szczerba, M. and Kalinichev, A.G., 2016 Intercalation of ethylene glycol in smectites: Several molecular simulation models verified by X-ray diffraction data Clays and Clay Minerals 64 488–502.CrossRefGoogle Scholar
Tiwari, R.R. Khilar, K.C. and Natarajan, U., 2008 Synthesis and characterization of novel organo-montmorillonites Applied Clay Science 38 203–208.CrossRefGoogle Scholar
van Olphen, H., 1963 Introduction to Clay Colloid Chemistry New York Interscience Publishers.Google Scholar
Veiskarami, M. Sarvi, M.N. and Mokhtari, A.R., 2016 Influence of the purity of montmorillonite on its surface modification with an alkyl-ammonium salt Applied Clay Science 120 111–120.CrossRefGoogle Scholar
Wang, L. and Wang, A., 2008 Adsorption properties of Congo red from aqueous solution onto surfactant-modified montmorillonite Journal of Hazardous Materials 160 173–180.CrossRefGoogle ScholarPubMed
Xi, Y.F. Frost, R.L. He, H.P. Kloprogge, J.T. and Bostrom, T., 2005 Modification of Wyoming montmorillonite surfaces using a cationic surfactant Langmuir 21 8675–8680.CrossRefGoogle ScholarPubMed
Xi, YF Z hou, Q. Frost, R.L. and He, H.P., 2007 Thermal stability of octadecyltrimethylammonium bromide modified montmorillonite organoclay Journal of Colloid and Interface Science 311 347–353.CrossRefGoogle ScholarPubMed
Xi, Y.F. Mallavarapu, M. and Naidu, R., 2010 Preparation, characterization of surfactants modified clay minerals and nitrate adsorption Applied Clay Science 48 92–96.CrossRefGoogle Scholar
Yapar, S. Özbudak, V. Dias, A. and Lopes, A., 2005 Effect of adsorbent concentration to the adsorption of phenol on hexadecyltrimethyl ammonium-bentonite Journal of Hazardous Materials 121 135–139.CrossRefGoogle Scholar
Yu, W. H. Li, N. Tong, D.S. Zhou, C.H. Lin, C.X. and Xu, C.Y., 2013 Adsorption of proteins and nucleic acids on clay minerals and their interactions: A review Applied Clay Science 80-81 443–452.CrossRefGoogle Scholar
Yu, W.H. Ren, Q.Q. Tong, D.S. Zhou, C.H. and Wang, H., 2014 Clean production of CTAB-montmorillonite: Formation mechanism and swelling behavior in xylene Applied Clay Science 97-98 222–234.CrossRefGoogle Scholar
Zheng, Y. and Zaoui, A., 2017 Wetting and nanodroplet contact angle of the clay 2:1 surface: The case of Namontmorillonite (001) Applied Surface Science 396 717–722.CrossRefGoogle Scholar
Zhou, C.H. and Keeling, J., 2013 Fundamental and applied research on clay minerals: From climate and environment to nanotechnology Applied Clay Science 74 3–9.CrossRefGoogle Scholar
Zhou, C.H. Zhang, D. Tong, D.S. Wu, L.M. Yu, W.H. and Ismadji, S., 2012 Paper-like composites of cellulose acetate-montmorillonite for removal of hazardous anionic dye in water Chemical Engineering Journal 209 223–234.CrossRefGoogle Scholar
Zhou, C.H. Zhao, L.Z. Wang, A.Q. Chen, T.H. and He, H.P., 2016a Current fundamental and applied research into clay minerals in China Applied Clay Science 119 3–7.CrossRefGoogle Scholar
Zhou, D. Zhang, Z. Tang, J. Wang, F. and Liao, L., 2016b Applied properties of oil-based drilling fluids with montmorillonites modified by cationic and anionic surfactants Applied Clay Science 1-8 121–122.Google Scholar
Zhuang, G. Zhang, Z. Fu, M. Ye, X. and Liao, L., 2015 Comparative study on the use of cationic-nonionic-organomontmorillonite in oil-based drilling fluids Applied Clay Science 116-117 257–262.CrossRefGoogle Scholar
Zhuang, G. Zhang, Z. Sun, J. and Liao, L., 2016 The structure and rheology of organo-montmorillonite in oilbased system aged under different temperatures Applied Clay Science 124 21–30.CrossRefGoogle Scholar
Zhu, L.Z. Zhu, R.L. Xu, L.H. and Ruan, X.X., 2007 Influence of clay charge densities and surfactant loading amount on the microstructure of CTMA-montmorillonite hybrids Colloids and Surfaces A: Physicochemical and Engineering Aspects 304 41–48.CrossRefGoogle Scholar
Zhu, J.X. He, H.P. Guo, J.G. Yang, D. and Xie, X.D., 2003 Arrangement models of alkylammonium cations in the interlayer of HDTMA+ pillared montmorillonites Chinese Science Bulletin 48 368–372.Google Scholar
Zhu, J.X. He, H.P. Zhu, L.Z. Wen, X.Y. and Deng, F., 2005 Characterization of organic phases in the interlayer of montmorillonite using FTIR and 13C NMR Journal of Colloid and Interface Science 286 239–244.CrossRefGoogle ScholarPubMed
Zhu, J.X. Wang, T. Zhu, R.L. Ge, F. Yuan, P. and He, H.P., 2011 Expansion characteristics of organo montmorillonites during the intercalation, aging, drying and rehydration processes: Effect of surfactant/CEC ratio Colloids and Surfaces A: Physicochemical and Engineering Aspects 384 401–407.CrossRefGoogle Scholar
Zhu, R.L. Zhu, L.H. Zhu, J.X. and Xu, L.H., 2008 Structure of cetyltrimethylammonium intercalated hydrobiotite Applied Clay Science 42 224–231.CrossRefGoogle Scholar
Zhu, R. Zhou, Q. Zhu, J. Xi, Y. and He, H., 2015 Organoclays as sorbents of hydrophobic organic contaminants: sorptive characteristics and approaches to enhancing sorption capacity Clays and Clay Minerals 63 199–221.CrossRefGoogle Scholar