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Octahedral or Tetrahedral Isomorphous Substitution: How it Affects Water and Acetonitrile Interaction with a Clay, as Seen by NMR

Published online by Cambridge University Press:  28 February 2024

Jean Grandjean  and
Pierre Laszlo
Jean Grandjean
Affiliation:
Laboratoire de chimie fine aux interfaces, B6 Université Liège, Sart-Tilman par, B-4000 Liège, Belgium
Pierre Laszlo
Affiliation:
Laboratoire de chimie fine aux interfaces, B6 Université Liège, Sart-Tilman par, B-4000 Liège, Belgium
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Abstract

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Keywords

2H NMRHectoriteHydrationMontmorilloniteSaponite
Type
Brief Report
Information
Clays and Clay Minerals , Volume 42 , Issue 5 , October 1994 , pp. 652 - 654
Copyright
Copyright © 1994, Clay Minerals Society

References

Delville, A., Grandjean, J., and Laszlo, P.. 1991 . Order acquisition by clay platelets in a magnetic field. NMR study of the structure and microdynamics of the adsorbed water layer. J. Phys. Chem. 95: 1383–1392.CrossRefGoogle Scholar
Fripiat, J., Cases, J., Francois, M., and Letellier, M.. 1982 . Thermodynamic and microdynamic behaviour of water in clay suspensions and gels. J. Colloid Interface Sci. 89: 378–400.CrossRefGoogle Scholar
Grandjean, J., and Laszlo, P.. 1989 . Deuterium nuclear magnetic resonance studies of water molecules restrained by their proximity to a clay surface. Clays & Clay Miner. 37: 403–408.CrossRefGoogle Scholar
Grandjean, J., and Laszlo, P.. Multinuclear magnetic resonance studies of structure and dynamics at the interface of clay materials. In Spectroscopic Characterization of Minerals and Their Surfaces. Coyne, L. M., McKeever, S. W. S., and Blake, D. F., 1990 eds. ACS Symp. Ser. 415: 396–406.CrossRefGoogle Scholar
Grandjean, J., and Laszlo, P.. 1994a . Deuterium and oxygen-17 nuclear magnetic resonance of aqueous clay suspensions. Magn. Reson. Imaging 12: 375–377.CrossRefGoogle ScholarPubMed
Grandjean, J., and Laszlo, P.. 1994b . Multinuclear magnetic resonance study of saponite hydration and of acetonitrile-water competition. J. Am. Chem. Soc. 116: 3980–3987.CrossRefGoogle Scholar
Halle, B., and Wennerstrøm, H.. 1981 . Interpretation of magnetic resonance data from water nuclei in heterogeneous systems. J. Chem. Phys. 75: 1928–1943.CrossRefGoogle Scholar
Olis, A. C., and Douglas, L. A.. The classification of high charge expanding 2: 1 phyllosilicates. In Proc. Int. Clay Conf., Strasbourg, 1989. Farmer, V. C., and Tardy, V., 1990 eds. Sci. Geol. Mém. 86: 127–135.Google Scholar
Xu, S., and Harsh, J. B.. 1992 . Alkali cation selectivity and surface charge of 2: 1 clay minerals. Clays & Clay Miner. 40: 567–574.CrossRefGoogle Scholar