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Note on the Intercalation of Kaolinite, Dickite and Halloysite by Dimethyl-Sulfoxide

Published online by Cambridge University Press:  01 July 2024

Octavian Anton  and
Paul G. Rouxhet
Octavian Anton
Affiliation:
Groupe de Physico-Chimie Minérale et de Catalyse, Université Catholique de Louvain, Place Croix du Sud 1, 1348, Louvain-la-Neuve, Belgium
Paul G. Rouxhet
Affiliation:
Groupe de Physico-Chimie Minérale et de Catalyse, Université Catholique de Louvain, Place Croix du Sud 1, 1348, Louvain-la-Neuve, Belgium
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Abstract

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Various kaolinites, a dickite and halloysites have been treated by DMSO in presence of D2O and subsequently washed by D2O. This procedure allowed to record OD stretching bands which are due specifically to the intercalated fraction and, for the washed samples, to the fraction of the solid which has been intercalated and has subsequently collapsed.

No structural difference is found between the intercalated materials prepared from the various minerals. Washing usually restores the starting mineral; however, for a non-tubular halloysite, DMSO intercalation and subsequent washing gave a product similar to kaolinite.

Type
Research Article
Information
Clays and Clay Minerals , Volume 25 , Issue 4 , August 1977 , pp. 259 - 263
Copyright
Copyright © Clay Minerals Society 1977

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