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Nordstrandite in Bauxite Derived from Phonolite, Lages, Santa Catarina, Brazil

Published online by Cambridge University Press:  28 February 2024

Norberto Dani ,
Milton Luiz Laquintinie Formoso ,
Alain Decarreau  and
Alain Meunier
Norberto Dani
Affiliation:
Universidade Federal do Rio Grande do Sul, Institute de Geociências, Avenida Bento Gonçalves 9500, CEP 91501-970, Caixa Postal 15001, Porto Alegre, Brazil
Milton Luiz Laquintinie Formoso
Affiliation:
Universidade Federal do Rio Grande do Sul, Institute de Geociências, Avenida Bento Gonçalves 9500, CEP 91501-970, Caixa Postal 15001, Porto Alegre, Brazil
Alain Decarreau
Affiliation:
Hydrasa UMR 6532 CNRS, University of Poitiers, 40 Avenue du Recteur Pineau, 86022 Poitiers Cedex, France
Alain Meunier
Affiliation:
Hydrasa UMR 6532 CNRS, University of Poitiers, 40 Avenue du Recteur Pineau, 86022 Poitiers Cedex, France
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Abstract

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Nordstrandite from Lages represents the first occurrence of this mineral in an oxisoil that does not involve the influence of a calcareous substrate. This is also the first reported occurrence in Brazil. Nordstrandite occurs near the city of Lages only in the weathered bedrock facies, mostly where the circulation of meteoric water is restricted. There is also a close association between nordstrandite and the weathering of modified pseudoleucite structures. The interaction of meteoric water and feldspathic alkaline country rock with uncommon texture and mineralogy (rich in nepheline, sodalite, nosean, analcime and natrolite) promotes the development of solutions enriched in alkaline ions with basic pH, necessary to form nordstrandite. A detailed study by X-ray diffraction (XRD) and infrared (IR) spectroscopy in natural or chemically leached samples was performed to identify the Al(OH)3 polymorphs of gibbsite and nordstrandite.

Keywords

BauxiteBoehmiteGibbsiteNordstranditeParaná BasinPhonoliteWeathering
Type
Research Article
Information
Clays and Clay Minerals , Volume 49 , Issue 3 , June 2001 , pp. 216 - 226
Copyright
Copyright © 2001, The Clay Minerals Society

References

Bárdossy, G.Y., Melfi, A.J. and Carvalho, A., 1983 A comparison of the main lateritic bauxite regions of our globe Proceedings of the 11th International Seminar on Lateritisation Processes 15–51.Google Scholar
Barnhisel, R.I. and Rich, C.I., 1965 Gibbsite, bayerite, and nordstrandite formation as affected by anions, pH and mineral surfaces Soil Science Society American Proceedings 29 531–534 10.2136/sssaj1965.03615995002900050018x.CrossRefGoogle Scholar
Berry, L.G., 1974 Selected Powder Diffraction Data for Minerals .Google Scholar
Chao, G.Y. and Baker, J., 1982 Nordstrandite from Mont St-Hilaire, Quebec Canadian Mineralogist 20 77–85.Google Scholar
Chao, G.Y. Baker, J. Sabina, A.P. and Roberts, A.C., 1985 Doyleite, a new polymorph of Al(OH)3, and its relationship to bayerite, gibbsite and nordstrandite Canadian Mineralogist 23 21–28.Google Scholar
Davis, C.E. and Hill, V.G., 1973 Occurrence of nordstrandite and its possible significance in Jamaica bauxites Travaux de la Commission Internationale pour l’Étude de Bauxites, Oxydes, Hydroxydes Alumineux 11 61–70.Google Scholar
Delvigne, J. Soubies, E. and Sardela, I., 1987 Micromorphologie des altérations supergènes de la lujaurite du massif alcalin de Poços de Caldas, Minas Gérais, Brésil Micromorphologie des Sols 1 97–103.Google Scholar
Elderfield, H. and Hem, J.D., 1973 The development of crystalline structure in aluminum hydroxide polymorphs on ageing Mineralogical Magazine 39 89–96 10.1180/minmag.1973.039.301.14.CrossRefGoogle Scholar
Edgar, A.D., Fitton, J.G. and Upton, B.G.J., 1987 The genesis of alkaline magmas with emphasis on their source regions: inferences from experimental studies Alkaline Igneous Rocks London Geological Society 29–52.Google Scholar
Farmer, V.C., 1974 The Infrared Spectra of Minerals London Mineralogical Society 10.1180/mono-4.CrossRefGoogle Scholar
Goldberry, R. and Loughnan, E.C., 1970 Dawsonite and nordstrandite in the Permian Berry Formation of the Sydney Basin, New South Wales American Mineralogist 55 477–490.Google Scholar
Hathaway, J.C. and Schlanger, S.O., 1962 Nordstrandite from Guam Nature 196 265–266 10.1038/196265a0.CrossRefGoogle Scholar
Hemingway, B.S. and Saxena, K.S., 1982 Gibbs free energies of formation for bayerite, nordstrandite, Al(OH)2+, and Al(OH)2 +, aluminum mobility, and the formation of bauxites and latentes Advances in Physical Geochemistry New York Springer-Verlag 285–314 10.1007/978-1-4612-5683-0_9.CrossRefGoogle Scholar
Hsu, P.H., 1967 Effect of salts on the formation of bayerite versus pseudoboehmite Soil Science 103 101–110 10.1097/00010694-196702000-00003.CrossRefGoogle Scholar
Hsu, P.H., 1988 Mechanisms of gibbsite crystallization from partially neutralized aluminum chloride solutions Clays and Clay Minerals 36 25–30 10.1346/CCMN.1988.0360104.Google Scholar
Jamet, R. Trichet, J. and Millot, G., 1991 Conditions d’apparition de la nordstrandite dans les sols de la Polynésie française Comptes Rendus des Séances de L’Académie des Sciences de Paris 312 1655–1660.Google Scholar
Kämpf, N. and Schwertmann, U., 1982 The 5-M-NaOH concentration treatment for iron oxides in soils Clays and Clay Minerals 30 401–408 10.1346/CCMN.1982.0300601.CrossRefGoogle Scholar
Kretz, R., 1983 Symbols for rock-forming minerals American Mineralogist 68 277–279.Google Scholar
Krumbein, W.C. and Pettijohn, E.J., 1938 Manual of Sedimentary Petrography New York Appleton-Century-Crofts, Inc..Google Scholar
Kulikova, G.V. Tsekhovol’skaya, D.I. and Shitov, V.A., 1974 First find of nordstrandite in the USSR Doklady Akademii nauk SSSR 217 190–193.Google Scholar
Le Maitre, R.W. Bateman, R. Dudek, A. Keller, J. Lameyre, J. Le Bas, M.J. Sabine, R.A. Schmid, R. Sörensen, H. Streikeisen, A. Woolley, A.R. and Zanettin, B., 1989 A Classification of Igneous Rocks and Glossary of Terms: Recommendations of the International Union of Geological Sciences Subcommission on the Systematics of Igneous Rocks Oxford, UK Blackwell Scientific Publications.Google Scholar
Lee, D.H. and Condrate, RA Sr, 1995 An FTIR spectral investigation of the structural species found on alumina surfaces Material Letters 23 241–246 10.1016/0167-577X(95)00039-9.CrossRefGoogle Scholar
Marie, L., 1968 Nordstrandite and gibbsite in the terrarossa of Dinarides karst Geoloski Vjesnik 21 281–291.Google Scholar
McHardy, W.J. and Thomson, A.R., 1971 Conditions for the formation of bayerite and gibbsite Mineralogical Magazine 38 358–368 10.1180/minmag.1971.038.295.11.CrossRefGoogle Scholar
Mehra, O.P. Jackson, M.L. and Seinefored, A., 1960 Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate Clays and Clay Minerals, Proceedings of the 7th National Conference on Clays and Clay Minerals New York Pergamon Press, Elmsford 317–342.Google Scholar
Milton, C. Dwornik, E.J. and Finkerman, R.B., 1975 Nordstrandite, Al(OH)3, from the Green River Formation in Rio Branco County, Colorado American Mineralogist 60 285–291.Google Scholar
Naray-Szabó, I. and Péter, , 1967 Nachweis von Nords-trandit und Bayerit in Ungarischen Ziegeltonen Acta Geologica Academiae Scientiarum Hungaricae 11 375–377.Google Scholar
Norrish, K. and Taylor, R.M., 1961 The isomorphous replacement of iron by aluminium in soil goethites Journal of Soil Science 12 294–306 10.1111/j.1365-2389.1961.tb00919.x.CrossRefGoogle Scholar
Palmieri, E. Violante, A. and Violante, P., 1985 Infrared spectra of nordstrandite Mineralogica et Petrographica Acta 29 391–397.Google Scholar
Papee, D. Tertian, R. and Biais, R., 1958 Recherches sur la constituition des gels et des hydrates cristallins d’alumine Bulletin de la Société Chimique de France 81 1301–1310.Google Scholar
Petersen, O.V. Johnsen, O. and Leonardsen, E.S., 1976 Nordstrandite from Narssârssuk, Greenland The Mineralogical Record 7 78–82.Google Scholar
Righi, D. Meunier, A. and Velde, B., 1995 Origin of clays by rock weathering and soil formation Origin and Mineralogy of Clays. Clays and the Environment Berlin Springer-Verlag 43–157 10.1007/978-3-662-12648-6_3.CrossRefGoogle Scholar
Rodgers, K.A. Gregory, M.R. and Barton, R., 1991 Bayerite, nordstrandite, gibbsite, brucite, and pseudoboehmite in discharged caustic waste from Campbell Island, Southwest Pacific Clays and Clay Minerals 39 103–107 10.1346/CCMN.1991.0390114.CrossRefGoogle Scholar
Ryskin, Y.I. and Farmer, V. C., 1974 The vibration or protons in minerals; hy-droxyl, water and ammonium Infrared Spectra of Minerals London Mineralogical Society 137–181 10.1180/mono-4.9.CrossRefGoogle Scholar
Scheibe, L.F. Kawashita, K. and Gomes, C.B., 1985 Contribuiçâo à geocronologia do complexo alcalino de Lages, SC Simpòsio Sul Brasileìro de Geologia, Florianópolis, Brazil, SBG 299–307.Google Scholar
Schoen, R. and Roberson, C.E., 1970 Structures of aluminum hydroxides and geochemical implications American Mineralogist 55 43–77.Google Scholar
Singer, A. and Huang, P.M., 1990 Effects of humic acid on the crystallization of aluminum hydroxides Clays and Clay Minerals 38 47–52 10.1346/CCMN.1990.0380106.CrossRefGoogle Scholar
Tardy, Y. (1994) Programme interdisciplinaire de recherche de biogéodynamique intertropicale périatlantique—PIRAT. Sciences Géologiques, Mémoire, 96, 101 pp.Google Scholar
Tertian, R., 1966 Etude d’un échantillon de bauxite blanche recueilli à Vonji Do (Montenegro) Travaux Comité International pour l’Étude des Bauxites, Oxydes, et Hydroxides d’Aluminium 3 51–64.Google Scholar
Turner, S. Regelous, M. Kelley, S.P. Hawkesworth, C.J. and Mantovani, M., 1994 Magmatism and continental breakup in the South Atlantic: high precision Ar/Ar geochronology Earth and Planetary Science Letters 121 333–348 10.1016/0012-821X(94)90076-0.CrossRefGoogle Scholar
Van Nordstrand, R.A. Hettinger, W.P. and Keith, C.D., 1956 A new aluminum trihydrate Nature 177 713–714 10.1038/177713a0.CrossRefGoogle Scholar
Violante, A. and Huang, P.M., 1985 Influence of inorganic and organic ligands on the formation of aluminum hydroxides and oxyhydroxides Clays and Clay Minerals 33 181–192 10.1346/CCMN.1985.0330303.CrossRefGoogle Scholar
Violante, A. and Jackson, M.L., 1981 Clay influence on the crystallization of aluminum hydroxide polymorphs in the presence of citrate, sulfate or chloride Geoderma 25 199–214 10.1016/0016-7061(81)90036-7.CrossRefGoogle Scholar
Violante, A. and Violante, P., 1980 Influence of pH, concentration and chelating power of organic anions on the synthesis of aluminum hydroxide and oxyhydroxides Clays and Clay Minerals 28 425–434 10.1346/CCMN.1980.0280604.CrossRefGoogle Scholar
Violante, P. Violante, A. and Tait, J.M., 1982 Morphology of nordstrandite Clays and Clay Minerals 30 431–437 10.1346/CCMN.1982.0300605.CrossRefGoogle Scholar
Wall, J.R.D. Wolfenden, E.B. Beard, E.H. and Deans, T., 1962 Nordstrandite in soil from West Sarawak, Borneo Nature 196 264–265 10.1038/196264b0.CrossRefGoogle Scholar