Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-29T18:27:23.307Z Has data issue: false hasContentIssue false
  • English
  • Français

The Near-Infrared Combination Band Frequencies of Dioctahedral Smectites, Micas, and Illites

Published online by Cambridge University Press:  28 February 2024

James L. Post  and
Paul N. Noble
James L. Post
Affiliation:
Department of Civil Engineering and Chemistry Department, California State University, Sacramento, California 95819
Paul N. Noble
Affiliation:
Department of Civil Engineering and Chemistry Department, California State University, Sacramento, California 95819
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The highest frequency near-infrared (NIR) combination bands for specimens of four species of mica—montmorillonite-beidellite, illite, chlorite, and kaolinite—were correlated with respect to Al2O3 content. A direct linear correlation was found between the combination band positions and the Al2O3 contents of the montmorillonite-beidellite series, which may be given as: ν̄ cm−1 = (5.38 ± 0.04) (% Al2O3) + (4412.8 ± 0.9). A similar linear correlation for muscovite is: ν̄ cm−1 = (6.10 ± 0.25) (% Al2O3) + (4434.1 ± 8.3).

Possible NIR band interferences are shown for different mineral mixtures, along with the correlation of different illites with muscovite. No combination bands were found in the frequency region 4425 cm−1 to 4625 cm−1 for specimens in which the Al2O3 content was only in the tetrahedral layer sites.

Keywords

Al contentDioctahedral smectitesMicasNIR spectra
Type
Research Article
Information
Clays and Clay Minerals , Volume 41 , Issue 6 , December 1993 , pp. 639 - 644
Copyright
Copyright © 1993, The Clay Minerals Society

References

Cariati, F., Erre, L., Piu, P. and Gessa, C., 1981 Water molecules and hydroxyl groups in raontmorillonites as studied by near-infrared spectroscopy Clays & Clay Minerals 29 157 – 159 10.1346/CCMN.1981.0290211.CrossRefGoogle Scholar
Cariati, F., Erre, L., Micera, G., Piu, P. and Gessa, C., 1983a Polarization of water molecules in phylosilicates in relation to exchange cations as studied by near-infrared spectroscopy Clays & Clay Minerals 31 155 – 157 10.1346/CCMN.1983.0310211.CrossRefGoogle Scholar
Cariati, F., Erre, L., Micera, G., Piu, P. and Gessa, C., 1983b Effects of layer charge on the near-infrared spectra of water molecules in smectites and vermiculites Clays & Clay Minerals 31 447 – 449 10.1346/CCMN.1983.0310606.CrossRefGoogle Scholar
Clark, R. N., King, T V V Klejwa, M., Swayze, G. A. and Vergo, N., 1990 High spectral resolution reflectance spectroscopy of minerals Jour. Geophys. Research 95 138 653 12.Google Scholar
Deer, W. A., Howie, R. A. and Zussman, J., 1962 Rock-Forming Minerals S New York, New York John Wiley & Sons 226 – 228.Google Scholar
Farmer, V. C., 1974 The larger silicates The Infrared Spectra of Minerals London Mineralogical Society 331 – 353 10.1180/mono-4.15.CrossRefGoogle Scholar
Higgins, C. T. and Streitz, R., 1988 Application of remote sensing to California’s geology California Geology 41 123 – 133.Google Scholar
Hunt, G. R. and Salisbury, J. W., 1970 Visible and near-infrared spectra of minerals and rocks. I. Silicate minerals Modern Geol. 1 283 – 300.Google Scholar
Hunt, G. R., Salisbury, J. W. and Lenhoff, C. J., 1973 Visible and near-infrared spectra of minerals and rocks. VI. Additional silicates Modern Geol. 4 96 – 101.Google Scholar
Hunt, G. R., 1977 Spectral signatures of particulate minérals in the visible and near-infrared Geophysics 42 501 – 513 10.1190/1.1440721.CrossRefGoogle Scholar
Jepson, W. B. and Rowse, J. B., 1975 The composition of kaolinite—An electron microscope micro probe study Clays & Clay Minerals 23 310 – 317 10.1346/CCMN.1975.0230407.CrossRefGoogle Scholar
Kral, S., 1990 Advances in exploration technology are crucial for gold companies in the 1990s Mining Engr. 42 255 – 263.Google Scholar
Lin, F.-C. and Clemency, C. V., 1981 Dissolution kinetics of phlogopite. I. Closed system Clays & Clay Minerals 29 101 – 106 10.1346/CCMN.1981.0290203.Google Scholar
Lindgren, W., (1899) The gold and sil ver veins of Sil ver City, DeLamar and other mining districts of Idaho: 20th Annual Report, Part III, USGS, 135–140.Google Scholar
Logan, L. M., Hunt, G. R., Salisbury, J. W. and Balsamo, S. R., 1973 Compositional implications of Christiansen frequency maximum for infrared remote sensing applications J. Geophys. Res. 78 4983 10.1029/JB078i023p04983.CrossRefGoogle Scholar
MacEwan, D. M. C. and Brindley, G. W., 1951 The montmorillonite minerals (montmorillonoids) X-ray Identification and Crystal Structures of Clay Minerals London Mineralogical Society 104 – 107.Google Scholar
MacEwan, D. M. C. and Brown, G., 1961 Montmorillonite minerals The X-ray Identification and Crystal Structures of Clay Minerals 2 London Mineralogical Society 167 – 169.Google Scholar
Pietracaprina, A., Novelli, G. and Rinaldi, A., 1972 Notes—Bentonite deposit at Uri, Sardinia, Italy Clay Minerals 9 351 – 355 10.1180/claymin.1972.009.3.10.CrossRefGoogle Scholar
Piper, A. M., and Laney, F. B., (1926) Geology and metal-liferrous resources of the region about Silver City, Idaho: Idaho Bureau of Mines and Geology Bull. 11, 145 pp.Google Scholar
Post, J. L., 1981 Expansive soils. Volume change and expansion pressure of smectites California Geology 34 197 – 203.Google Scholar
Post, J. L. and Burnett, J. L., 1985 Roscoelite type locality California Geology 38 99 – 103.Google Scholar
Post, J. L., 1988 Elemental analyses of mica resources in California California Geology 41 3 – 13.Google Scholar
Post, J. L. and Austin, G. S., 1993 Geochemistry of micas from Precambrian rocks of Northern New Mexico: N.M. Bureau of Mines & Mineral Resources Circular 202 1 – 20.Google Scholar
Shannon, E. V., 1923 Notes on the mineralogy of three gouge clays from precious metal veins Proceedings of the United States National Museum 62 1 – 4.Google Scholar
Stubican, V. and Roy, R., 1961 Isomorphous substitution and infrared spectra of the layer-lattice silicates Amer. Mineral. 46 33 – 50.Google Scholar
Vedder, W., 1964 Correlations between infrared spectrum and chemical compositions of mica Amer. Mineral 49 736 – 768.Google Scholar
Weaver, C. E. and Pollard, L. D., 1973 The Chemistry of Clay Minerals Amsterdam Elsevier.Google Scholar
Weir, A. H. and Greene-Kelly, R., 1962 Beidellite Amer. Mineral. 47 137 – 146.Google Scholar