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Melt synthesis and characterization of synthetic Mn-rich tainiolite

Published online by Cambridge University Press:  01 January 2024

Alexander Baumgartner ,
Christian Butterhof ,
Sebastian Koch ,
Ruslan Mariychuk  and
Josef Breu
Alexander Baumgartner
Affiliation:
Department of Inorganic Chemistry I, University of Bayreuth, 95447 Bayreuth, Germany
Christian Butterhof
Affiliation:
Department of Inorganic Chemistry I, University of Bayreuth, 95447 Bayreuth, Germany
Sebastian Koch
Affiliation:
Department of Inorganic Chemistry I, University of Bayreuth, 95447 Bayreuth, Germany
Ruslan Mariychuk
Affiliation:
Department of Inorganic Chemistry I, University of Bayreuth, 95447 Bayreuth, Germany
Josef Breu*
Affiliation:
Department of Inorganic Chemistry I, University of Bayreuth, 95447 Bayreuth, Germany
*
* E-mail address of corresponding author: [email protected]
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Abstract

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Large transition-metal contents add desirable physical properties, such as redox reactivity, magnetism, and electric or ionic conductivity to micas and make them interesting for a variety of materials-science applications. A Mn- and F-rich tainiolite mica, , was synthesized by a high-temperature melt-synthesis technique. Subsequent annealing for 10 days led to a single-phase and coarsegrained material. Single-crystal X-ray diffraction studies were performed and characteristic geometric parameters were compared to the analogous ferrous compound, synthetic Fe-rich tainiolite, . Both tainiolite structures are outside the compositional stability limits for the 2:1 layer structure, and incorporating the relatively large cation Mn2+ requires significant structural adjustments in both the octahedral and tetrahedral sheets. As expected, increasing the ionic radius of the octahedral cation from 0.78 Å (VIFe2+) to 0.83 Å (VIMn2+) reduces the octahedral flattening angle from <Ψ> = 57.05° to <Ψ> = 56.4°, the smallest value ever observed for a tetrasilicic mica. However, even this small <Ψ> value is insufficient to match the lateral sizes of the tetrahedral and octahedral sheets and, in addition, unusual structural adjustments in the tetrahedral sheet are required. The average tetrahedral bond length <T-O> is much greater (1.643 Å) than the average value observed for tetrasilicic micas (1.607 Å,) and a significant difference between the <T-O>apical (1.605 Å) and the <T-O>basal bond lengths (1.656 Å) and an enlarged basal flattening angle (τbas = 106.29°) are noted. These parameters indicate: (1) that the 2:1 layer might be more flexible than previously thought, to allow matching of the lateral dimensions of the tetrahedral and octahedral sheets; and (2) that many other compositions that appear interesting from a materials-science point of view might be accessible.

Keywords

Crystal ChemistryManganeseMicaSynthetic ClaysTainiolite
Type
Article
Information
Clays and Clay Minerals , Volume 57 , Issue 2 , April 2009 , pp. 271 - 277
Copyright
Copyright © The Clay Minerals Society 2009

References

Baumgartner, A. Sattler, K. Thun, J. and Breu, J., 2008 A route to microporous materials through oxidative pillaring of micas Angewandte Chemie-International Edition 47 1640–1644 10.1002/anie.200704790.CrossRefGoogle ScholarPubMed
Breu, J. Seidl, W. Stoll, A.J. Lange, K.G. and Probst, T.U., 2001 Charge homogeneity in synthetic fluorohectorite Chemistry of Materials 13 4213–4220 10.1021/cm011014m.CrossRefGoogle Scholar
Brigatti, M.F. Guggenheim, S., Mottana, A. Sassi, F.P. Thompson, J.B. Jr. and Guggenheim, S., 2002 Mica crystal chemistry and the influence of pressure, temperature, and solid solution on atomistic models Micas: Crystal Chemistry & Metamorphic Petrology Washington, DC Mineralogical Society of America and the Geochemical Society 1–97.Google Scholar
Coelho, A.A., 2003 TOPAS User’s Manual Karlsruhe, Germany Version 3.1, Bruker AXS, GmbH.Google Scholar
Comodi, P. Zanazzi, P.F. Weiss, Z. Rieder, M. and Drabek, M., 1999 “Cs-tetra-ferri-annite”: High-pressure and high-temperature behavior of a potential nuclear waste disposal phase American Mineralogist 84 325–332 10.2138/am-1999-0315.CrossRefGoogle Scholar
Donnay, G. Takeda, H. and Donnay, J.D.H., 1964 Trioctahedral 1-layer micas. II. Prediction of structure from composition and cell dimensions Acta Crystallographica 17 1374–1381 10.1107/S0365110X64003462.CrossRefGoogle Scholar
Eggleton, R.A. and Ashley, P.M., 1989 Norrishite, a new manganese mica, , from the Hoskins Mine, New South Wales, Australia American Mineralogist 74 1360–1367.Google Scholar
Fleet, M.E., 2003 Rock-Forming Minerals Vol. 3A — Micas London The Geological Society.Google Scholar
Gnos, E. Armbruster, T. and Villa, I.M., 2003 Norrishite, , an oxymica associated with sugilite from the Wessels Mine, South Africa: Crystal chemistry and Ar-40-Ar-39 dating American Mineralogist 88 189–194 10.2138/am-2003-0122.CrossRefGoogle Scholar
Guggenheim, S. and Eggleton, R.A., 1987 Modulated 2–1 layer silicates — review, systematics, and predictions American Mineralogist 72 724–738.Google Scholar
Gunther, D. Frischknecht, R. Heinrich, C.A. and Kahlert, H.J., 1997 Capabilities of an argon fluoride 193 nm excimer laser for laser ablation inductively coupled plasma mass spectrometry microanalysis of geological materials Journal of Analytical Atomic Spectrometry 12 939–944 10.1039/A701423F.CrossRefGoogle Scholar
Hazen, R.M. and Wones, D.R., 1972 Effect of cation substitutions on physical properties of trioctahedral micas American Mineralogist 57 103–129.Google Scholar
Hazen, R.M. and Wones, D.R., 1978 Predicted and observed compositional limits of trioctahedral micas American Mineralogist 63 885–892.Google Scholar
Higashi, S. Miki, H. and Komarneni, S., 2007 Mn-smectites: Hydrothermal synthesis and characterization Applied Clay Science 38 104–112 10.1016/j.clay.2007.01.016.CrossRefGoogle Scholar
Ihara, Y. and Kitajima, K., 1997 Synthesis and properties of Co2+-substituted tetrasilicic fluorine micas Journal of the Ceramic Society of Japan 105 881–885 10.2109/jcersj.105.881.CrossRefGoogle Scholar
Ishida, K. Hawthorne, F.C. and Hirowatari, F., 2004 Shirozulite, , a new manganese-dominant trioctahedral mica: Description and crystal structure American Mineralogist 89 232–238 10.2138/am-2004-0127.CrossRefGoogle Scholar
Kitajima, K. Ihara, Y. and Takusagawa, N., 1995 Synthesis and properties of Ni2+-substituted tetrasilicic fluorine micas Journal of the Ceramic Society of Japan 103 1057–1062 10.2109/jcersj.103.1057.CrossRefGoogle Scholar
Longerich, H.P. Jackson, S.E. and Gunther, D., 1996 Laser ablation inductively coupled plasma mass spectrometric transient signal data acquisition and analyte concentration calculation Journal of Analytical Atomic Spectrometry 11 899–904 10.1039/JA9961100899.CrossRefGoogle Scholar
Mariychuk, R. Baumgartner, A. Wagner, F.E. Lerf, A. Dubbe, A. and Breu, J., 2007 Synthesis, structure, and electric conductivity of ferrous tainiolite and its oxidative conversion into coarse-grained swellable smectite Chemistry of Materials 19 5377–5387 10.1021/cm0713778.CrossRefGoogle Scholar
Mercier, P.H.J. Rancourt, D.G. Redhammer, G.J. Lalonde, A.E. Robert, J.L. Berman, R.G. and Kodama, H., 2006 Upper limit of the tetrahedral rotation angle and factors affecting octahedral flattening in synthetic and natural 1M polytype C2/m space group micas American Mineralogist 91 831–849 10.2138/am.2006.1815.CrossRefGoogle Scholar
Rancourt, D.G. Mercier, P.H.J. Cherniak, D.J. Desgreniers, S. Kodama, H. Robert, J.L. and Murad, E., 2001 Mechanisms and crystal chemistry of oxidation in annite: Resolving the hydrogen-loss and vacancy reactions Clays and Clay Minerals 49 455–491 10.1346/CCMN.2001.0490601.CrossRefGoogle Scholar
Redhammer, G.J. Amthauer, G. Lottermoser, W. Bernroider, M. Tippelt, G. and Roth, G., 2005 X-ray powder diffraction and Fe-57-Mössbauer spectroscopy of synthetic trioctahedral micas {K}[Me3](TSi3)O10(OH)2, Me = Ni2+, Mg2+, Co2+, Fe2+; T = Al3+, Fe3+ Mineralogy and Petrology 85 89–115 10.1007/s00710-005-0096-2.CrossRefGoogle Scholar
Ruscher, C.H. and Gall, S., 1995 On the polaron-mechanism in iron-bearing trioctahedral phyllosilicates — An investigation of the electrical and optical properties Physics and Chemistry of Minerals 22 468–478 10.1007/BF00200325.CrossRefGoogle Scholar
Ruscher, C.H. and Gall, S., 1997 Dielectric properties of iron-bearing trioctahedral phyllosilicates Physics and Chemistry of Minerals 24 365–373 10.1007/s002690050050.Google Scholar
Shannon, R.D., 1976 Revised effective ionic-radii and systematic studies of interatomic distances in halides and chalcogenides Acta Crystallographica Section A — Foundations of Crystallography 32 751–767 10.1107/S0567739476001551.CrossRefGoogle Scholar
Tischendorf, G. Forster, H.J. Gottesmann, B. and Rieder, M., 2007 True and brittle micas: composition and solid-solution series Mineralogical Magazine 71 285–320 10.1180/minmag.2007.071.3.285.CrossRefGoogle Scholar
Tsapatsis, M. and Maheshwari, S., 2008 Pores by pillaring: Not always a maze Angewandte Chemie — international edition 47 4262–4263 10.1002/anie.200705755.CrossRefGoogle ScholarPubMed
Tyrna, P.L. and Guggenheim, S., 1991 The crystal structure of norrishite, n oxygen-rich mica American Mineralogist 76 266–271.Google Scholar
Weiss, Z. Rieder, M. and Chmielova, M., 1992 Deformation of coordination polyhedra and their sheets in phyllosilicates European Journal of Mineralogy 4 665–682 10.1127/ejm/4/4/0665.CrossRefGoogle Scholar
Weiss, Z. Rieder, M. Chmielova, M. and Krajicek, J., 1985 Geometry of the octahedral coordination in micas — A review of refined structures American Mineralogist 70 747–757.Google Scholar