Hostname: page-component-586b7cd67f-2brh9 Total loading time: 0 Render date: 2024-11-24T08:03:13.957Z Has data issue: false hasContentIssue false
  • English
  • Français

Kaolinite Intercalation Precursors

Published online by Cambridge University Press:  01 January 2024

Yanfeng Li ,
Dewen Sun ,
Xiaobing Pan  and
Bo Zhang
Yanfeng Li*
Affiliation:
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Institute of Biochemical Engineering & Environmental Technology, Lanzhou University, Lanzhou 730000, China
Dewen Sun
Affiliation:
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Institute of Biochemical Engineering & Environmental Technology, Lanzhou University, Lanzhou 730000, China
Xiaobing Pan
Affiliation:
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Institute of Biochemical Engineering & Environmental Technology, Lanzhou University, Lanzhou 730000, China
Bo Zhang
Affiliation:
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Institute of Biochemical Engineering & Environmental Technology, Lanzhou University, Lanzhou 730000, China
*
* E-mail address of corresponding author: [email protected]
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The preparation and characterization of intercalated kaolinite is important for industries such as those using nanocomposites, but the number of compounds that can be intercalated into these clay minerals is rather limited. The purpose of this study was to expand the range of possible intercalants by developing intercalation precursors using both single and multiple (co-intercalation) precursor agents. Characterization of the resulting precursors was by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and differential thermal analysis (DTA). The results show that the most successful single intercalation agent was DMSO and, among the co-intercalation agents, the DMSO/CH3OH system was the best. The preparation and characterization of kao-DMSO-KAc showed that the displacement reaction is the most efficient way to expand the interlayer spacing of kaolinite. At the same time, the lateral-bilayer arrangement of the Ac− in the interlayers was proven by study of de-intercalation of kao-KAc under high temperature.

Keywords

ArrangementCo-intercalation AgentsDe-intercalationGuest-Displacement ReactionIntercalation PrecursorKaoliniteLateral-bilayerSingle Intercalation SystemThermal DecompositionX-ray Analyses
Type
Research Article
Information
Clays and Clay Minerals , Volume 57 , Issue 6 , December 2009 , pp. 779 - 786
Copyright
Copyright © The Clay Minerals Society 2009

References

Barrios, J. Plançon, A. Cruz, M.I. and Tchoubar, C., 1977 Qualitative and quantitative study of the stacking faults in a hydrazine-treated kaolinite-relationship with the infrared spectra Clays and Clay Minerals 25 422–429 10.1346/CCMN.1977.0250608.CrossRefGoogle Scholar
Belver, C. Muñoz, M.A. and Vincente, M.A., 2002 Chemical activation of a kaolinite under acid and alkaline conditions Chemistry of Materials 14 2033–2043 10.1021/cm0111736.CrossRefGoogle Scholar
Benco, L. Tunega, D. Hafner, J. and Lischka, H., 2001 Upper limit of the O—H⋯O hydrogen bond: Ab initio study of the kaolinite structure Journal of Physical Chemistry B 105 10812–10817 10.1021/jp0124802.CrossRefGoogle Scholar
Bundy, W.M. and Ishley, J.N., 1991 Kaolin in paper filling and coating Applied Clay Science 5 397–420 10.1016/0169-1317(91)90015-2.CrossRefGoogle Scholar
Cabedoa, L. Gimeneza, E. Lagaronb, J.M. Gavarab, R. and Saura, J.J., 2004 Development of EVOH-kaolinite nano-composites Polymer 45 5233–5238 10.1016/j.polymer.2004.05.018.CrossRefGoogle Scholar
Elboki, T.A. and Detellier, C., 2006 Aluminosilicate nanohybrid materials: Intercalation of polystyrene in kaolinite Journal of Physical and Chemistry of Solids 67 950–955 10.1016/j.jpcs.2006.01.008.CrossRefGoogle Scholar
Frost, R.L. Kristof, J. Horvath, E. and Kloprogge, J.T., 1999 Modification of kaolinite surfaces through intercalation with potassium acetate, II Journal of Colloid and Interface Science 214 109–117 10.1006/jcis.1999.6177.CrossRefGoogle ScholarPubMed
Horváth, E. Kristóf, J. Frost, R.L. Jakab, E. Makó, E. and Vágvölgyi, V., 2005 Identification of superactive centers in thermally treated formamide-intercalated kaolinite Journal of Colloid and Interface Science 289 132–138 10.1016/j.jcis.2005.03.059.CrossRefGoogle ScholarPubMed
Johnston, C.T. and Stone, D.A., 1990 Influence of hydrazine on the vibrational modes of kaolinite Clays and Clay Minerals 38 121–128 10.1346/CCMN.1990.0380202.CrossRefGoogle Scholar
Komori, Y. Sugahara, Y. and Kuroda, K., 1999 Direct intercalation of poly(vinylpyrrolidone) into kaolinite by a refined guest displacement method Chemistry of Materials 11 3–6 10.1021/cm9804721.CrossRefGoogle Scholar
Ledoux, R.L. and White, J.L.J., 1996 Infrared studies of hydrogen bonding interaction between kaolinite surfaces and intercalated potassium acetate, hydrazine, formamide, and urea Journal of Colloid and Interface Science 21 127–152 10.1016/0095-8522(66)90029-8.CrossRefGoogle Scholar
Li, B.G. Hu, Y. Zhang, R. Chen, Z.Y. and Fan, W.C., 2003 Preparation of the poly(vinyl alcohol)/layered double hydroxide nanocomposite Materials Research Bulletin 38 1567–1572 10.1016/S0025-5408(03)00203-4.CrossRefGoogle Scholar
Martens, W.N. Frost, R.L. Kristof, J. and Horvath, E., 2002 Modification of kaolinite surfaces through intercalation with deuterated dimethylsulfoxide Journal of Physical Chemistry B 106 4162–4171 10.1021/jp0130113.CrossRefGoogle Scholar
Murray, H.H., 2000 Traditional and new applications for kaolin, smectite, and palygorskite: a general overview Applied Clay Science 17 207–221 10.1016/S0169-1317(00)00016-8.CrossRefGoogle Scholar
Murray, H.H. Bundy, W. and Harvey, C., 1993 Kaolin Genesis and Utilization Boulder, CO, USA The Clay Minerals Society 43 pp.CrossRefGoogle Scholar
Olejnik, S. Aylmore, L.A.G. Posner, A.M. and Quirk, J.P., 1968 Infrared spectra of kaolin mineral-dimethyl sulfoxide complexes Journal of Physical Chemistry 72 241–249 10.1021/j100847a045.CrossRefGoogle Scholar
Olejnik, S. Posner, A.M. and Quirk, J.P., 1970 The intercalation of polar organic compounds into kaolinite Clay Minerals 8 421–434 10.1180/claymin.1970.008.4.05.CrossRefGoogle Scholar
Van der Marel, H.W. and Beutelspacher, H., 1976 Atlas of Infrared Spectroscopy of Clay Minerals and their Admixtures Amsterdam Elsevier.Google Scholar
Zhang, B. Li, Y.F. Pan, X.B. Jia, X. and Wang, X.L., 2007 Intercalation of acrylic acid and sodium acrylate into kaolinite and their in situ polymerization Journal of Physics and Chemistry of Solids 68 135–142 10.1016/j.jpcs.2006.09.020.CrossRefGoogle Scholar